• Computers and Concrete
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• v.30 no.6
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• pp.421-432
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• 2022

Recently, the interminable ozone depletion and the global warming concerns has led to construction industries to seek for construction materials which are eco-friendly. Regarding this, Geopolymer Concrete (GPC) is getting great interest from researchers and scientists, since it can operate by-product waste to replace cement which can lead to the reduction of greenhouse gas emission through its production. Also, compared to ordinary concrete, geopolymer concrete belongs improved mechanical and durability properties. In spite of its positive properties, the practical use of geopolymer concrete is currently limited. This is primarily owing to the scarce structural, design and application knowledge. This study investigates the Mechanical and Durability of Geopolymer Concrete Containing Fibers and Recycled Aggregate. Mixtures of elastoplastic fiber reinforced geopolymer concrete with partial replacement of recycled coarse aggregate in different proportions of 10, 20, 30, and 40% with natural aggregate were fabricated. On the other hand, geopolymer concrete of 100% natural aggregate was prepared as a control specimen. To consider both strength and durability properties and to evaluate the combined effect of recycled coarse aggregate and elastoplastic fiber, an elastoplastic fiber with the ratio of 0.4% and 0.8% were incorporated. The highest compressive strength achieved was 35 MPa when the incorporation of recycled aggregates was 10% with the inclusion of 0.4% elastoplastic fiber. From the result, it was noticed that incorporation of 10% recycled aggregate with 0.8% of the elastoplastic fiber is the perfect combination that can give a GPC having enhanced tensile strength. When specimens exposed to freezing-thawing condition, the physical appearance, compressive strength, weight loss, and ultrasonic pulse velocity of the samples was investigated. In general, all specimens tested performed resistance to freezing thawing. the obtained results indicated that combination of recycled aggregate and elastoplastic fiber up to some extent could be achieved a geopolymer concrete that can replace conventional concrete.

• Advances in concrete construction
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• v.14 no.1
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• pp.1-13
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• 2022

Due to the physical-chemical characteristics of some bottom ash (BA), there are technical, economic and environmental limitations to find a destination that will add value to it. In Brazil, this residue is eventually used for filling coal extraction pits or remains in sedimentation ponds, creating a susceptible panorama to environmental issues. The geopolymers binders are one of the alternatives to the proper use high amounts of these materials. In this work, geopolymeric binder pastes were produced with BA mixed to activators with different alkali contents (expressed as %Na₂O), as well as the incorporation of soluble silicates (Ms content). The production of binary geopolymeric pastes based on the use of two industrial wastes: fluid catalytic cracking (FCC) and aluminum anodizing sludge (AAS), was also assessed. The content in mass of BA/FCC and BA/AAS ranged from 100/0, 90/10; 80/20 and 70/30. Systems with soluble silicates as activator in a molar ratio SiO₂/Na₂O of 1.0 (Ms = 1.0) and Na₂O content of 15%, showed the best results of mechanical strength (42 MPa at day 28^th). The improvement is up to 5X when compared to NaOH based systems. For systems with partial replacement of BA of 10% of AAS and 20% of FCC (80/20), the presence of soluble silicates was also effective to increase compressive strength.

• Advances in concrete construction
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• v.15 no.6
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• pp.419-430
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• 2023

In this study, the effect of two types of aggregates (fly ash aggregate and shale aggregate) on the density, strength, and durability of preplaced lightweight aggregate concrete (PLWAC) was studied. The results showed that the 7 - 28 days strength of concrete prepared with fly ash aggregates (high water absorption rate) significantly increased, which could attribute to the long-term water release of fly ash aggregates by the refined pore structure. In contrast, the strength increase of concrete prepared with shale aggregates (low water absorption rate) is not apparent. Although PLWAC prepared with fly ash aggregates has a lower density and higher strength (56.8 MPa @ 1600 kg/m³), the chloride diffusion coefficient is relatively high, which could attribute to the diffusion paths established by connected porous aggregates and the negative over-curing effect. Compared to the control group, the partial replacement of fly ash aggregates (30%) with asphalt emulsion (20% solid content) coated aggregates can reduce the chloride diffusion coefficient of concrete by 53.6% while increasing the peak load obtained in a three-point bending test by 107.3%, fracture energy by 30.3% and characteristic length by 103.5%. The improvement in concrete performance could be attributed to the reduction in the water absorption rate of aggregates and increased energy absorption by polymer during crack propagation.

• Structural Engineering and Mechanics
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• v.87 no.6
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• pp.585-599
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• 2023

Geopolymer concrete (GC) can be competently utilized as a practical replacement for cement to prevent a high carbon footprint and to give a direction toward sustainable concrete construction. Moreover, previous studies mostly focused on the axial response of glass fiber reinforced polymer (glass-FRP) concrete compressive elements without determining the effectiveness of repairing them after their partial damage. The goal of this study is to assess the structural effectiveness of partially damaged GC columns that have been restored using carbon fiber reinforced polymer (carbon-FRP). Bars made of glass-FRP and helix made of glass-FRP are used to reinforce these columns. For comparative study, six of the twelve circular specimens-each measuring 300 mm×1200 mm-are reinforced with steel bars, while the other four are axially strengthened using glass-FRP bars (referred to as GSG columns). The broken columns are repaired and strengthened using carbon-FRP sheets after the specimens have been subjected to concentric and eccentric compression until a 30% loss in axial strength is attained in the post-peak phase. The study investigates the effects of various variables on important response metrics like axial strength, axial deflection, load-deflection response, stiffness index, strength index, ductility index, and damage response. These variables include concentric and eccentric compression, helix pitch, steel bars, carbon-FRP wrapping, and glass-FRP bars. Both before and after the quick repair process, these metrics are evaluated. The results of the investigation show that the axial strengths of the reconstructed SSG and GSG columns are, respectively, 15.3% and 20.9% higher than those of their original counterparts. In addition, compared to their SSG counterparts, the repaired GSG samples exhibit an improvement in average ductility indices of 2.92% and a drop in average stiffness indices of 3.2%.

• Journal of Electrochemical Science and Technology
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• v.14 no.1
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• pp.96-104
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• 2023

Synergistically increased oxygen evolution reaction (OER) of manganese oxide (MnO₂) catalyst is introduced with surface-modified halloysite nanotube (Fe₃O₄-HNTs) structure. The flake shaped MnO₂ catalyst is attached on the nanotube template (Fe₃O₄-HNTs) by series of wet chemical and hydrothermal method. The strong interaction between MnO₂ and Fe₃O₄-HNTs maximized active surface area and inter-connectivity for festinate charge transfer reaction for OER. The synergistical effect between Fe₃O₄ layer and MnO₂ catalyst enhance the Mn³⁺/Mn⁴⁺ ratio by partial replacement of Mn ions with Fe. The relatively increased Mn³⁺/Mn⁴⁺ ratio on MnO₂@FHNTs induced 𝜎^* orbital (e_g) occupation close to single electron, improving the OER performances. The MnO₂@FHNTs catalyst exhibited the reduced overpotential of 0.42 V (E vs. RHE) at 10 mA/cm² and Tafel slope of (99 mV/dec), compared with that of MnO₂ with unmodified HNTs (0.65 V, 219 mV/dec) and pristine MnO₂ (0.53 V, 205 mV/dec). The present study provides simple and innovative method to fabricate nano fiberized OER catalyst for a broad application of energy conversion and storage systems.

• Advances in materials Research
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• v.11 no.2
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• pp.147-164
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• 2022

This study aims to investigate the influence of scoria aggregate (SA) and silica fume (SF) as a replacement of conventional aggregate and ordinary Portland cement (OPC), respectively. Three types of concrete were prepared namely normal weight concrete (NWC) using limestone aggregate (LSA) and OPC (control specimen), lightweight concrete (LWC) using SA and OPC, and LWC using SA and partial SF (SLWC). The representative workability and compressive strength properties of the developed concrete were evaluated, and the results were correlated with non-destructive ultrasonic pulse velocity and Schmidt hammer tests. The LWC and SLWC yielded compressive strength of around 30 MPa and 33 MPa (i.e., 78-86% of control specimens), respectively. The findings indicate that scoria can be beneficially utilized in the development of structural lightweight concrete. Present renewable sources of aggregate will preserve the natural resources for next generation. The newly produced eco-friendly construction material is intended to break price barriers in all markets and draw attraction of incorporating scoria based light weight construction in Saudi Arabia and GCC countries. Findings of the SWOT analysis indicate that high logistics costs for distributing the aggregates across different regions in Saudi Arabia and clients' resistant to change are among the major obstacles to the commercialized production and utilization of lightweight concrete as green construction material. The findings further revealed that huge scoria deposits in Saudi Arabia, and the potential decrease in density self-weight of structural elements are the major drivers and enablers for promoting the adoption of lightweight concrete as alternative green construction material in the construction sector.

• Structural Engineering and Mechanics
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• v.87 no.3
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• pp.221-229
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• 2023

Urbanization and industrialization have significantly increased the amount of solid waste produced in recent decades, posing considerable disposal problems and environmental burdens. The practice of waste utilization in concrete has gained popularity among construction practitioners and researchers for the efficient use of resources and the transition to the circular economy in construction. This study employed Lytag aggregate, an environmentally friendly pulverized fuel ash-based lightweight aggregate, as a substitute for natural coarse aggregate. At the same time, fly ash, an industrial by-product, was used as a partial substitute for cement. Concrete mix M20 was experimented with using fly ash and Lytag lightweight aggregate. The percentages of fly ash that make up the replacements were 5%, 10%, 15%, 20%, and 25%. The Compressive Strength (CS), Split Tensile Strength (STS), and deflection were discovered at these percentages after 56 days of testing. The concrete cube, cylinder, and beam specimens were examined in the explorations, as mentioned earlier. The results indicate that a 10% substitution of cement with fly ash and a replacement of coarse aggregate with Lytag lightweight aggregate produced concrete that performed well in terms of mechanical properties and deflection. The cementitious composites have varying characteristics as the environment changes. Therefore, understanding their mechanical properties are crucial for safety reasons. CS, STS, and deflection are the essential property of concrete. Machine learning (ML) approaches have been necessary to predict the CS of concrete. The Artificial Fish Swarm Optimization (AFSO), Particle Swarm Optimization (PSO), and Harmony Search (HS) algorithms were investigated for the prediction of outcomes. This work deftly explains the tremendous AFSO technique, which achieves the precise ideal values of the weights in the model to crown the mathematical modeling technique. This has been proved by the minimum, maximum, and sample median, and the first and third quartiles were used as the basis for a boxplot through the standardized method of showing the dataset. It graphically displays the quantitative value distribution of a field. The correlation matrix and confidence interval were represented graphically using the corrupt method.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2022.10a
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• pp.570-573
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• 2022

This paper presents the identification of void diameters for a cast-resin transformer using an artificial neural network (ANN) model. A PD signal was measured by the Rogowski coil sensor which has the planar and thin structures fabricated on a printed circuit board (PCB), and the PD electrode system was fabricated to simulate a PD defect by a void. In addition, void samples with different diameters were fabricated by injecting air in a cylindrical aluminum frame using a syringe during the epoxy curing process. To identify the diameter of void defects, PD characteristics such as the discharge magnitude, pulse count, and phase angle were extracted and back propagation algorithm (BPA) was designed using virtual instrument (VI) based on the Labview program. From the experimental results, the BPA algorithm proposed in this paper has over 90% accurate rate to identify the diameter of void defects and is expected to use reference data of maintenance and replacement of insulation for cast-resin transformers in the on-site PD measurement.

• Korean Journal of Soil Science and Fertilizer
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• v.7 no.3
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• pp.163-175
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• 1974

Effects on yields, yield components and nutrient content of potassium depression for two or three weeks at various growth stages were investigated in rice (var. Jinheung) under sand culture system.(K 40 ppm 1973) 1. Analysis of variance showed significant difference among treatments of both two-week (at p=0.01) and three-week depression (at p=0.05) in yield. 2. Most sensitive stage to potassium depression on yield appeared two weeks until heading (42% yield decrease) and sensitivity decreased the growth stage is apart from heading either before or after. During 30 days after transplanting two-week potassium depression increased yield, but three-week depression decreased yield. Until about 30 days after heading depression caused poor yield. 3. Root potassium involves in harvest index, filled grain ratio and grain weight with significant correlation and considerably in spikelet per panicle while potassium in leaf sheath+culm involves considerably in spikelet per panicle and panicle per hill. Relative total dry matter weight was significantly correlated with panicle per hill, spikelet per panicle and K or K/Ca+Mg only in leaf sheath+culm. The indications are that root potassium contributes for building sink and efficiency of structure while potassium in leaf sheat+culm primarily for building source, productive structure. 4. Relative yield was significantly correlated with potassium content in root and leaf sheath+culm and with K/Ca+Mg and its ratio before and after depression in root indicating that potassium depression occurs greatly in root and that K/Ca+Mg might have more important role than K content alone under depression. 5. Optimum level of $K_2O$ appears around 3% in leaf blade. 4% in leaf sheath+culm and 1% in root under the assumption that below these level the same content has the same role in relation to yield during growth. The K/Ca+Mg appeares to be 2.5 in root and should not decrease throughout the growth stages. 6. The increase of sodium content in plant by K depression was highest, especially in leaf sheath during the most insensitive period to K depression suggesting that insensitivity may be attributed to partial replacement of Na for K. Partial replacement seems very little in sensitive stage (later stage) and sensitive organ (root).

• Journal of agriculture & life science
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• v.45 no.5
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• pp.81-89
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• 2011

This study was carried out to investigate changes in physicochemical and sensory properties of cooked sausages replaced sodium chloride (NaCl) to potassium chloride (KCl) or magnesium chloride ($MgCl_2$) during storage for 30 days under $4^{\circ}C$. All sausages were prepared with different combination of salts as follow; CTL (1.5% NaCl), KCL (0.9% NaCl+0.6% KCl), MCL (0.9% NaCl+0.6% $MgCl_2$), KML (0.9% NaCl+0.3% KCl+0.3% $MgCl_2$) and PST (1.5% PanSalt). Among sausages moisture content in KML was the highest (p<0.05). Lightness and redness in CTL were lower than those of other treatments, but MCL and KML containing $MgCl_2$ showed higher CIE $L^*$ and $a^*$ values than CTL. The pH in CTL was the highest during storage, however, no significant difference was determined between two treatments, MCL and KML (p>0.05). Crude fat content and water holding capacity (WHC), hardness and cohesiveness of MCL sausages were higher than those of CTL. In sensory characteristics of cooked sausages, saltness in MCL was the lowest during 10 and 20 days of storage (p<0.05). Yellowness in PST was lower than other treatmeants. Gumminess and chewiness of texture property of sausages from MCL and KML were higher than CTL. The results indicate that the replacement of NaCl by KCl improved texture, but meat color was not improved as expected. In contrast, the replacement of NaCl by $MgCl_2$ enhanced color, texture and WHC, whereas partial replacement of NaCl by $MgCl_2$ must reduce bitter taste as compared to sausages manufactured with a NaCl only. Therefore, $MgCl_2$ may be a salt replacing NaCl in cooked pork sausages.