• Bulletin of the Korean Chemical Society
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• 제15권1호
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• pp.33-36
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• 1994

The x values of nonstoichiometric chemical formula, $Tb_4O_{7-{\delta}}\;or\;TbO_{1.5+x}$, have been determined in temperature range from 600$^{\circ}$C to 1000$^{\circ}$C under oxygen partial pressure of 2 ${\times}$ 10$^{-1}$ to 1 ${\times}$ 10$^{-5}$ atm by using quartz microbalance. The x values varied from 0.0478 to 0.1964 in the above conditions. The enthalpy of formation for x' in TbO$_{1.5+(0.25-xo-x')}$, ${\delta}H_f$, was 4.93-3.40 kcal mol$^{-1}$ and the oxygen partial pressure dependence was -1/8.80∼-1/11.8 under these conditions. The electrical conductivity of the $TbO_{1.5+x}$ was measured under the same conditions and the values varied from about 10$^{-3}$ to 10$^{-6}\;{\Omega}^{-1}cm^{-1}$ within semiconductor range. The activation energies for the conduction increase with oxygen partial pressure from 0.83 to 0.89 eV under the above conditions. The l/n values obtained from the oxygen pressure dependence of the conductivity are 1/4.4-1/5.2. The conduction mechanism, defect structure, and other physical properties of the oxides are dicussed with the x values, the electrical conductivity values, and the thermodynamic data.

• 한국초전도학회:학술대회논문집
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• 한국초전도학회 2008년도 High Temperature Superconductivity Vol.XVIII
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• pp.84-84
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• 2008

• International Journal of Naval Architecture and Ocean Engineering
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• 제10권5호
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• pp.609-616
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• 2018

The cargo handling system, which is composed of a fuel gas supply unit and cargo tank pressure control unit, is the second largest power consumer in a Liquefied Natural Gas (LNG) carrier. Because of recent enhancements in ship efficiency, the surplus boil-off gas that remains after supplying fuel gas for ship propulsion must be reliquefied or burned to regulate the cargo tank pressure. A full or partial liquefaction process can be applied to return the surplus gas to the cargo tank. The purpose of this study is to review the current partial liquefaction process for LNG carriers and develop new processes for reducing power consumption using exergy analysis. The developed partial liquefaction process was also compared with the full liquefaction process applicable to a LNG carrier with a varying boil-off gas composition and varying liquefaction amounts. An exergy analysis showed that the Joule-Thomson valve is the key component needed for improvements to the system, and that the proposed system showed an 8% enhancement relative to the current prevailing system. A comparison of the study results with a partial/full liquefaction process showed that power consumption is strongly affected by the returned liquefied amount.

• 유체기계공업학회:학술대회논문집
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• 유체기계공업학회 2006년 제4회 한국유체공학학술대회 논문집
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• pp.275-278
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• 2006

A steam turbine is one of propulsion systems of a LNG carrier, which consists of high pressure (HP) and low pressure (LP) turbines. In order to obtain high power, each one has the form of a multi-stage turbine. Especially, the first stage of a HP turbine is Curtis stage and uses partial admission considering the turbine efficiency. The performance of a HP turbine can be predicted by a mean-line analysis method, because the relatively large value of hub-tip ratio makes the three-dimensional losses small. In this study, a performance analysis method is developed for a multi-stage HP turbine using Chen's loss model developed for the transonic steam turbines. To consider the feature of partial admission, different partial admission models are reviewed, This analysis method can be used in partial load conditions as well as full load condition. The calculation results are also compared with the CFD results about some simple cases to check the accuracy of the program. Performance of two HP turbine models are calculated, and the calculation results are compared with the designed data. The comparison shows the qualitative performance analysis result.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1999년도 하계학술대회 논문집 D
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• pp.1523-1525
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• 1999

ZnO is a wide-bandgap II-VI semiconductor and has a variety of potential application. ZnO exhibits good piezoelectric, photoelectric and optic properties, and is good for a electroluminescence device. ZnO films have been deposited at (0001) shappire by PLD technique. Chamber was evacuated by turbomolecular pump to a base pressure of $1{\times}10^{-6}$ Torr Nd:YAG pulsed laser was operated at ${\lambda}=355nm$. The ZnO films were deposited at oxygen pressures from base to 500 mTorr. The substrate temperatures was increased from $200^{\circ}C$ to $700^{\circ}C$. At aleady works, UV emission and green-yellow PL was observed. In this work, ZnO films showed UV, violet, green and yellow emissions. UV emission was enhanced by increasing partial oxygen pressure. We investigated relationship between partial oxygen pressure and UV emission.

• E2M - 전기 전자와 첨단 소재
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• 제8권4호
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• pp.400-405
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• 1995

ZnO films have been grown easily with the conventional thermal evaporation method on SiO$\_$2/ coated Si wafers. Anhydrous zinc acetate has been used as evaporation source. Zinc-acetate was directly heated in the laboratory-made brass boat. Zinc-acetate was sublimed at the boat temperature of about 220.deg. C. The substrates were heated to 600.deg. C with home made tantalium heater. Oxygen has been flowed into the deposition chamber to change the partial pressure of oxygen. X-ray diffraction patterns showed all the films to be amorphous. The films deposited at high oxygen pressure exhibit higher resistivity than films at low pressure. Energy dispersive spectroscopy(EDS) and rutherford backscattering spectrometry(RBS) were conducted on the films to reveal the composition of the ZnO films.

• Journal of Advanced Marine Engineering and Technology
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• 제28권7호
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• pp.1082-1091
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• 2004

Analyzed Parametrically was an internal combustion engine combined with gas turbine the cycle of which is splitted into compression side cylinder and expansion side one, and heat adding of which is during constant volume pressure, temperature process. The advantages of each measures were analyzed by means of thermal cycle diagram. The thermal efficiency of partial load cutting off firstly isothermal heat adding and secondly isobaric heat adding also was analyzed The authors suggested some potentials about the performance as for thermal efficiency, mean effective pressure and reducing emissions and noise supposed were the operating parameter of the engine set to some values and were some problems solved.

• Journal of Welding and Joining
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• 제17권6호
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• pp.70-77
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• 1999

Surface depression in the arc welding is calculated numerically to analyze its influence on pool convection and oscillation. The magnitude of surface depression due to arc pressure on the stationary GTA pool surface is relatively small, and fluctuations of the surface and velocity are caused mainly by arc pressure. The inward flow on the surface due to the electromagnetic force and positive surface tension gradient acts to decrease surface depression. Surface depression appears to have minor effects on average flow velocity and thus pool geometry. Pool oscillation occurs due to surface vibration, and oscillation frequencies are affected mainly by the surface tension and pool width. The input parameters such as arc pressure and current have negligible effects on the oscillation frequency, and the surface tension gradient has limited effects. Since the oscillation frequency varies slightly according to penetration, pool oscillation for the partial penetration weld pool is applicable to monitor the pool width.

• 한국재료학회지
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• 제11권9호
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• pp.751-758
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• 2001

Anatase $TiO_2$ thin films as a photocatalyst were prepared by the D.C reactive magnetron sputtering process. The $TiO_2$ thin films were deposited on Si(100) substrates under the various conditions : oxygen partial pressure, working pressure, substrate temperature, D.C power, and deposition time. The morphology of the TiO$_2$ thin films showed an island structure. At early stages of film growth, amorphous phase formed. However, during the further growth, columnar crystalline $TiO_2$grains evolved. The crystallinity of the thin films depended on the oxygen partial pressure, the working pressure and the D.C. powers.

• 한국초전도ㆍ저온공학회논문지
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• 제9권3호
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• pp.72-82
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• 2007

This paper relates to reducing the temperature of a cryogenic liquid by contacting it with gas bubbles, which can be characterized by diffusion-driven evaporative cooling, The characteristic of diffusion-driven evaporative cooling is thoroughly examined by theoretical. analytical and experimental methods specifically for the case of helium injection into liquid oxygen. The results reveal that if the gaseous oxygen partial pressure in helium bubbles is lower than the liquid oxygen vapor pressure, cooling occurs autonomously due to diffusion mass transfer. The method of lowering the injected helium temperature turns out to be very effective for cooling purpose.