• 제목/요약/키워드: partial pressure

검색결과 1,424건 처리시간 0.036초

$SrCe_{0.95}Yb_{0.05}O_3$의 결함엄개와 전기전도 특성 (Defect Structure and Electrical Conductivities of $SrCe_{0.95}Yb_{0.05}O_3$)

  • 최정식;이도권;유한일
    • 한국세라믹학회지
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    • 제37권3호
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    • pp.271-279
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    • 2000
  • 5 m/o Yb-doped SrCeO3 proton conductor was prepared by a solid state reaction method and its total electriccal conductivity measured as a function of both oxygen partial pressure and water vapor partial pressure in the temperature range of 500~100$0^{\circ}C$. From the total conductivity have been deconvoluted the partial conductivities of oxide ions, protons, and holes, respectively, on the basis of the defect model proposed. The equilibrium constant of hydrogen-dissolution reaction, proton concentration, and mobilities of oxygen vacancies and protons have subsequently been evaluated. It is verified that SrCe1-xYbxO3 is a mixed conductor of holes, protons and oxide ions and the proton conduction prevails as temperature decreases and water vapor pressure increases. The heat of water dissolution takes a representative value of $\Delta$HoH=-(140$\pm$20) kJ/mol-H2O, but tends to be less negative with increasing temperature. Migration enthalpies of proton and oxygen vacancy are extracted as 0.83$\pm$0.10 eV and 0.81$\pm$0.01 eV, respectively.

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THE DEVELOPMENT OF THE WATER LOADED PRESSURE METHOD FOR MEASURING EGGSHELL QUALITY

  • Kang, C.W.;Nam, K.T.;Olson, O.E.;Carlson, C.W.
    • Asian-Australasian Journal of Animal Sciences
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    • 제9권6호
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    • pp.723-726
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    • 1996
  • A water loaded pressure device using water as the breaking force was developed to evaluate eggshell strength and compared with a dropping ball techniques. Further, relationships of shell thickness and weight of eggs to shell strength were also studied. Values for both of the shell strength measuring methods showed a highly significant correlation (p < 0.001) with shell thickness. The water loaded pressure method had a much higher simple correlation coefficient for shell thickness (r = + 0.786) than the dropping ball method (r = + 0.577). The shell strength measured by the water loaded pressure method appeared not to be correlated to egg weight. On the other hand, the negative sign of the standard partial regression coefficient and the partial regression coefficient of egg weight in the estimated multiple regression equation implied that for a given shell thickness a larger egg tended to have less shell strength than a smaller egg.

자동차용 휠 베어링의 부분탄성유체윤활 해석 (Partial-EHL Analysis of Wheel Bearing for a Vehicle)

  • 김동원;이상돈;조용주
    • Tribology and Lubricants
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    • 제21권6호
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    • pp.289-295
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    • 2005
  • Most machine element, such as gears and bearings, are operated in the mixed lubrication region. Contact between two asperities has an effect on machine life by increasing local pressure. To estimate fatigue life exactly, asperity contact should be considered as a factor of fatigue life because this happening produce friction, abrasion and make flash temperature. In this paper, asperity contact is considered as a result of film breakdown when lubricant pressure is not enough to separate two asperities. Contact pressure is calculated to asperity overlap region and added to lubricant pressure. For this model, numerical procedure is introduced and the result on surface roughness and velocity for wheel bearing is presented. Results of EHL analysis for wheel bearing show that asperity contact is occurred at the edge ofEHL conjunction where has a insufficient lubricant pressure to separate two surface.

The Strategy to Fabricate the MTiO3(M = Sr, Ba) Thin Films by Laser Ablation

  • Im, T.M.;Park, J.Y.;Kim, H.J.;Choi, H.K.;Jung, K.W.;Jung, D.
    • Bulletin of the Korean Chemical Society
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    • 제29권2호
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    • pp.427-430
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    • 2008
  • BaTiO3 and SrTiO3 thin films were fabricated on Pt/Ti/SiO2/Si substrate by the pulsed laser deposition process. The dependence of the deposited film quality upon the partial oxygen pressure during the deposition process was importantly examined. Regardless of the oxygen pressure, the as-deposited films were not fully crystallized. However, the film deposited at low oxygen pressure became well crystallized after the annealing process. It was concluded, therefore, that the partial oxygen pressure is reduced as low as possible during the deposition process and then anneal the as-deposited samples at ambient pressure to fabricate the well crystallized SrTiO3 and BaTiO3 films by laser ablation.

휠 베어링의 부분탄성유체윤활 해석 (Partial-EHL Analysis of wheel Bearing)

  • 김동원;이상돈;조용주
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2005년도 추계학술대회 논문집
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    • pp.616-621
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    • 2005
  • Most machine element, such as gears and bearings, are operated in the mixed lubrication region. Contact between two asperities has an effect on machine life by increasing local pressure. To estimate fatigue lift exactly, asperity contact should be considered as a factor of fatigue liff because this happening produce friction, abrasion and make flash temperature. In this paper, asperity contact is considered as a result of film breakdown when lubricant pressure is not enough to separate two asperities. Contact pressure is calculated to asperity overlap region and added to lubricant pressure. For this model, numerical procedure is introduced and the result on surface roughness and velocity for wheel bearing is presented. Results of EHL analysis for wheel bearing show that asperity contact is occurred at the edge of EHL conjunction where has a insufficient lubricant pressure to separate two surface.

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열처리 산소 분압에 따른 $Bi_4Ti_3O_{12}$ 박막의 전기적 특성 변화 (Electrical Properties of $Bi_4Ti_3O_{12}$ Thin Films dependant on Oxygen Partial Pressure during Annealing)

  • 차유정;남산;정영훈;이영진;백종후
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2009년도 하계학술대회 논문집
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    • pp.191-191
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    • 2009
  • $Bi_4Ti_3O_{12}$ (BiT) thin films were well developed on the Pt/Ti/$SiO_2/Si$ substrate by a metal organic decomposition (MOD) method. Oxygen was effective on the crystallization of the BiT thin films during a rapid thermal annealing process. The electrical properties of the BiT films dependant on the oxygen partial pressure were investigated. No crystalline phase was observed for the BiT film annealed at $700^{\circ}C$ under oxygen free atmosphere. However, its crystallinity was significantly evolutionned with increasing oxygen partial pressure. In addition, its dielectric and piezoelectric properties were enhanced with increasing oxygen partial pressure to 10 torr. Especially, the BiT film, annealed at $700^{\circ}C$ and 10 torr oxygen pressure, showed good dielectric properties: dielectric constant of 51 and dielectric loss of 0.2 % at 100 kHz. Its leakage current and piezoelectric constant ($d_{33}$) was also considerably improved, being as 0.62 nA/$cm^2$ at 1 V and approximately 51 pm/V, respectively.

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Hexagonal Barium-Ferrite 박막의 미세구조와 자기적 특성에 미치는 산소분압과 열처리 시간의 영향 (Influences of Oxygen Partial Pressure and Annealing Time on Microstructure and Magnetic Properties of Hexagonal Barium-Ferrite Thin Films)

  • 김웅수;김동현;남인탁;홍양기
    • 한국자기학회지
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    • 제10권6호
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    • pp.285-290
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    • 2000
  • 본 연구에서는 Hexagonal Barium Ferrite(BaM) 박막을 RF magnetron sputtering system을 이용하여 상온에서 증착한후, 85$0^{\circ}C$에서 열처리하여 결정화하였다. XRD pattern을 통해 BaM 박막의 working pressure 10 mTorr에 대한 산소분압(Po$_2$)을 0~3 mTorr가지 변화하여 알아본 결과, 1 mTorr 이하의 산소분압(Po$_2$)에서는 spinel 상과 BaM 상이 함께 형성되었으나, 1 mTorr 이상의 높은 산소분압(Po$_2$)에서는 BaM 상만이 형성되는 것을 알 수 있었다. BaM 박막의 자기적특성을 VSM을 통하여 알아본 결과 산소분압(Po$_2$)이 증가함에 따라 수직보자력은 일정하게 감소를 하였으나 포화자화값은 1 mTorr가지 증가하다 감소하였다. 열처리 시간에 따른 결정화 정도와 특성을 알아본 결과 열처리를 시작한 뒤 10분 이내에 대부분의 특성변화가 일어났으며, 그 이상의 온도에서는 커다란 변화를 일으키지 않음을 알 수 있었다.

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병렬 연결된 다중 증발기 구조 2상 유동 순환형 열사이폰의 부분부하 및 저온운전 특성에 관한 실험적 연구 (Experimental Study on the Two Phase Thermosyphone Loop with Parallel Connected Multiple Evaporators under Partial Load and Low Temperature Operating Condition)

  • 강인석;최동규;김택영
    • 설비공학논문집
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    • 제16권11호
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    • pp.1051-1059
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    • 2004
  • Two phase thermosyphone loop for electronics cooling are designed and manufactured to test its performance under the partial load and low environment temperature conditions. The thermosyphone device has six evaporators connected parallel for the purpose of cooling six power amplifier units (PAU) independently. The heater modules for simulating PAUs are adhered with thermal pad to the evaporator plates to reduce the contact resistance. There are unbalanced distributions of liquid refrigerant in the differently heated evaporators due to the vapor pressure difference. To reduce the vapor pressure differences caused by partial heating, two evaporators are connected each other using the copper tube. The pressure regulation tube successfully reduces these unbalances and it is good candidates for a field distributed systems. Under the low environment temperature operating condition, such as $-30^{\circ}C$, there may be unexpected subcooling in condenser. It leads the very low saturation pressure, and under this condition there exists explosive boiling in evaporator. The abrupt pressure rise due to the explosive boiling inhibits the supplement of liquid refrigerant to the evaporator for continuous cooling. Finally the cooling cycle will be broken. For the normal circulation of refrigerant there may be an optimum cooling air flow rate in condenser to adjust the given heat load.

이송식 아크플라즈마 장치에 의해 제조된 실리콘 나노분말의 특성에 대한 연구 (A Study on the Characteristics of Silicon Nanopowders Produced by Transferred Type Arc Plasma Apparatus)

  • 간우섭;박상희
    • 한국산업융합학회 논문집
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    • 제24권6_2호
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    • pp.909-917
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    • 2021
  • This study was carried out experimentally on the production and properties of silicon nanopowders characteristics using a transferred type arc plasma apparatus. To investigate the properties of silicon nanopowder, the purity of argon gas(99.999%, 99.9%) and the partial pressure ratio of nitrogen gas(0~90%) were varied. The total pressure in chamber is 400Torr and the silicon chunk amount used as raw material is 300g. The power supplied to the cathode to generate arc plasma was 9~12kW/h, and the electrode was made of tungsten and graphite with a diameter of 13mm. The particle size, impurity elements and powder evaporation rate of the silicon powder were analyzed using the XRD, FE-SEM, TEM and electronic scale. According to the purity of argon gas, the silicon evaporation rate and the particle size were similar, and impurities were generated more in the case of 99.9% purity than 99.999%. When argon gas and nitrogen gas were mixed in the chamber, the silicon evaporation rate and particle size increased as the partial pressure ratio of nitrogen gas increased. In particular, when the partial pressure ratio of nitrogen gas was 80%, the silicon evaporation rate 80g/h, and the particle size was about 80~100nm.

산소분압비에 따른 ITO/PET박막의 특성변화 (Characteristic Changes of ITO/PET Thin Films with Ratio of Oxygen Partial Pressure)

  • 김현후;이무영;김광태;윤상현
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 춘계학술대회 논문집 기술교육전문연구회
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    • pp.58-61
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    • 2003
  • ITO (indium tin oxide) thin films on PET (polyethylene terephthalate) substrate have been deposited by a dc reactive magnetron sputtering without heat treatments such as substrate heater and post heat treatment. Each sputtering parameter during the sputtering deposition is an important factor for the high quality of ITO thin films deposited on polymeric substrate. Particularly, the material, electrical and optical properties of as-deposited ITO oxide films are dominated by the ratio of oxygen partial pressure. As the experimental results, the excellent ITO films are prepared on PET substrate at the operating conditions as follows: operating pressure of 5 mTorr,target-substrate distance of 45 mm, dc power of 20-30 W, and oxygen gas ratio of 10 %. The optical transmittance is above 80 % at 550 nm, and the sheet resistance and resistivity of films are $24\;{\Omega}$/square and $1.5{\times}10^{-3}\;cm$, respectively.

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