• Title/Summary/Keyword: pN2

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Self-Assembly of Vanadium Borophosphate Cluster Anions: Synthesis and Structures of (NH4)(C2H10N2)5.5[Cu(C2H8N2)2]3[V2P2BO12]6·17H2O and (NH4)(C2H10N2)3.5[Cu(C2H8N2)2]5[V2P2BO12]6·18H2O

  • Jung, Kyung-Na;Cho, Yoon-Suk;Yun, Ho-Seop;Do, Jung-Hwan
    • Bulletin of the Korean Chemical Society
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    • v.26 no.8
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    • pp.1185-1189
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    • 2005
  • Two new copper vanadium borophosphate compounds, $(NH_4)(C_2H_{10}N_2)_{5.5}[Cu(C_2H_8N_2)_2]_3[V_2P_2BO_{12}]_6{\cdot}17H_2O,\;Cu-VBPO1\;and\;(NH_4)(C_2H_{10}N_2)_{3.5}[Cu(C_2H_8N_2)_2]_5[V_2P_2BO_{12}]_6{\cdot}18H_2O$, Cu-VBPO2 have been hydrothermally synthesized and characterized by single crystal X-ray diffraction, thermogravimetric analysis, IR spectroscopy, and elemental analysis. The structure of Cu-VBPO1 contains a layer anion, {$[Cu(C_2H_8N_2)_2]_3[V_2P_2BO_{12}]_6$}$^{12-}$, whereas Cu-VBPO2 has an open framework anion, {$[Cu(C_2H_8N_2)_2]_5[V_2P_2BO_{12}]_6$}$^{8-}$. Crystal Data: $(NH_4)(C_2H_{10}N_2)_{5.5}[Cu(C_2H_8N_2)_2]_3[V_2P_2BO_{12}]_6{\cdot}17H_2O$, monoclinic, space group I2/m (no. 12), $\alpha$ = 15.809(1) $\AA$, b = 31.107(2) $\AA$, c = 12.9343(8) $\AA$, $\beta$ = 104.325(1)$^{\circ}$, Z = 2; $(NH_4)(C_2H_{10}N_2)_{3.5}[Cu(C_2H_8N_2)_2]_5[V_2P_2BO_{12}]_6{\cdot}18H_2O$, tetragonal, space group $P4_2$/mnm (no.136), $\alpha$ = 26.832(1) $\AA$, c = 18.021(1) $\AA$, Z = 4.

A Study on the Diffusion Barrier at the p/n Junctions of $Bi_{0.5}Sb_{1.5}Te_3/Bi_2Te_{2.4}Se_{0.6} p/n$ Thermoelectric Thin Films (열전 박막 $Bi_{0.5}Sb_{1.5}Te_3/Bi_2Te_{2.4}Se_{0.6} p/n$ 접합에서의 확산 장벽에 관한 연구)

  • Kim, Il-Ho;Lee, Dong-Hui
    • Korean Journal of Materials Research
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    • v.6 no.7
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    • pp.678-683
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    • 1996
  • In the fabrication processes of thin film thermoelectrics, a subsequent annealing treatment is inevitable to reduce the defects and residual stresses introduced during the film growth, and to make the uniform carrier concentration of the film. However, the diffusion-induced atomic redistribution and the broadening of p/n junction region are expected to affect the thermoelectric properties of thin film modules. The present study intends to investigate the diffusion at the p/n junctions of thermoelectric thin films and to relate it to the property changes. The film junctions of p-type(Bi0.5Sb1.5Te3)and n-type(Bi2Te2.4Se0.6)were prepared by the flash evaporation method. Aluminum thin layer was employed as a diffusion barrier between p-and n-type films of the junction. This was found to be an effective barrier by showing a negligible diffusion into both type films. After annealing treatment, the thermoelectric properties of p/n couples with aluminum barrier layer were accordingly retained their properties without any deterioration.

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Effects of n-6/n-3 and P/S Ratio of Dietary Lipid on Thromboxane B2 and 6-Keto prostaglandin F1$\alpha$ Production in Rat (P/S 비율과 n-6/n-3 비율을 달리한 식이지방이 흰쥐의 Thromboxane B2 와 6-Keto prostaglandin F1$\alpha$ 합성에 미치는 영향 연구)

  • 김우경
    • Journal of Nutrition and Health
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    • v.27 no.6
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    • pp.574-582
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    • 1994
  • The effects of age and dietary fatty acid composition on prostagladin production was investigated in Sprague-Dawley strain male rats. Animals weighing 88.6$\pm$2.2g were fed 10% dietary fat(W/W, 20% of total energy). The P/S ratios of dietary lipid were three levels(0.5, 1, 2) and there were three different levels of n-6/n-3 fatty acid ratio(2, 4, 8) in each P/S ratio. The experimental period were 1 month and 12 months, respectively. The results of this study were as follows. As the age of rats increased, the plasma thromboxane B2 production increased, but aorta 6-keto prostaglandin F1$\alpha$ decreased. When a higher amount of n-3 fatty acid was fed in each P/S ratio, the relative percentage of linolenic acid and EPA in platelet increased.

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SOME Lq INEQUALITIES FOR POLYNOMIAL

  • Chanam, Barchand;Reingachan, N.;Devi, Khangembam Babina;Devi, Maisnam Triveni;Krishnadas, Kshetrimayum
    • Nonlinear Functional Analysis and Applications
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    • v.26 no.2
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    • pp.331-345
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    • 2021
  • Let p(z)be a polynomial of degree n. Then Bernstein's inequality [12,18] is $${\max\limits_{{\mid}z{\mid}=1}}\;{\mid}p^{\prime}(z){\mid}\;{\leq}\;n\;{\max_{{\mid}z{\mid}=1}{\mid}(z){\mid}}$$. For q > 0, we denote $${\parallel}p{\parallel}_q=\{{\frac{1}{2{\pi}}}{\normalsize\displaystyle\smashmargin{2}{\int\nolimits_{0}}^{2{\pi}}}\;{\mid}p(e^{i{\theta}}){\mid}^qd{\theta}\}^{\frac{1}{q}}$$, and a well-known fact from analysis [17] gives $${{\lim_{q{\rightarrow}{{\infty}}}}\{{\frac{1}{2{\pi}}}{\normalsize\displaystyle\smashmargin{2}{\int\nolimits_{0}}^{2{\pi}}}\;{\mid}p(e^{i{\theta}}){\mid}^qd{\theta}\}^{\frac{1}{q}}={\max\limits_{{\mid}z{\mid}=1}}\;{\mid}p(z){\mid}$$. Above Bernstein's inequality was extended by Zygmund [19] into Lq norm by proving ║p'║q ≤ n║p║q, q ≥ 1. Let p(z) = a0 + ∑n𝜈=𝜇 a𝜈z𝜈, 1 ≤ 𝜇 ≤ n, be a polynomial of degree n having no zero in |z| < k, k ≥ 1. Then for 0 < r ≤ R ≤ k, Aziz and Zargar [4] proved $${\max\limits_{{\mid}z{\mid}=R}}\;{\mid}p^{\prime}(z){\mid}\;{\leq}\;{\frac{nR^{{\mu}-1}(R^{\mu}+k^{\mu})^{{\frac{n}{\mu}}-1}}{(r^{\mu}+k^{\mu})^{\frac{n}{\mu}}}\;{\max\limits_{{\mid}z{\mid}=r}}\;{\mid}p(z){\mid}}$$. In this paper, we obtain the Lq version of the above inequality for q > 0. Further, we extend a result of Aziz and Shah [3] into Lq analogue for q > 0. Our results not only extend some known polynomial inequalities, but also reduce to some interesting results as particular cases.

ON A COMPUTATION OF PLURIGENUS OF A CANONICAL THREEFOLD

  • Shin, Dong-Kwan
    • Bulletin of the Korean Mathematical Society
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    • v.53 no.1
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    • pp.303-323
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    • 2016
  • For a canonical threefold X, it is known that $p_n$ does not vanish for a sufficiently large n, where $p_n=h^0(X,\mathcal{O}_X(nK_X))$. We have shown that $p_n$ does not vanish for at least one n in {6, 8, 10}. Assuming an additional condition $p_2{\geq}1$ or $p_3{\geq}1$, we have shown that $p_{12}{\geq}2$ and $p_n{\geq}2$ for $n{\geq}14$ with one possible exceptional case. We have also found some inequalities between ${\chi}(\mathcal{O}_X)$ and $K^3_X$.

Long Term Survival of Patients with Unsuspected N2 Disease in Non-Small Cell Lung Cancer

  • Lee, Deok Heon;Kim, Jae Bum;Keum, Dong Yoon;Hwang, Ilseon;Park, Chang Kwon
    • Journal of Chest Surgery
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    • v.46 no.1
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    • pp.49-55
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    • 2013
  • Background: The aim of this study was to determine the survival rate of patients with non-small cell lung cancer (NSCLC) who were preoperatively diagnosed with a negative N2 lymph node, but postoperatively confirmed as a positive N2 node based on a pathological evaluation. Materials and Methods: The hospital records of 248 patients from 1994 to 2009 with resected primary NSCLC who were preoperatively diagnosed with negative N2 lymph node, were retrospectively reviewed. Of these, after surgery, there were 148 (59.7%) patients with pathological N0, 54 (21.8%) with pathological N1 and 46 (18.5%) with pathological N2. Results: The median follow-up period was 24 months (range, 1 to 132 months). The 5-year disease free survival rates were 60% in pN0, 44% in pN1, and 29% in pN2. The 5-year overall survival rates were 63.1% in pN0, 51.9% in pN1, and 33.5% in pN2. There were no statistically significant differences between pN1 and pN2 (p=0.326 and p=0.106, respectively). Thirty-three (71.7%) of the 46 pN2 patients had single-zone metastasis, and 13 patients (28.3%) had multiple-zone metastases over the two nodal zone metastasis. There were no statistical differences in the 5-year disease free survival rate and the 5-year overall survival rates between the two groups. Conclusion: The 5-year disease free survival and the overall survival rate of the patients with unsuspected N2 disease were statistically similar with that of the patients with pathological N1 disease. There was no statistically significant difference between the patients with a single-zone metastasis and a multiple zone metastasis.

Infinite Families of Congruences for Partition Functions ${\bar{\mathfrak{EO}}}$(n) and ${\mathfrak{EO}}_e$(n)

  • Riyajur Rahman;Nipen Saikia
    • Kyungpook Mathematical Journal
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    • v.63 no.2
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    • pp.155-166
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    • 2023
  • In 2018, Andrews introduced the partition functions ${\mathfrak{EO}}$(n) and ${\bar{\mathfrak{EO}}}$(n). The first of these denotes the number of partitions of n in which every even part is less than each odd part, and the second counts the number of partitions enumerated by the first in which only the largest even part appears an odd number of times. In 2021, Pore and Fathima introduced a new partition function ${\mathfrak{EO}}_e$(n) which counts the number of partitions of n which are enumerated by ${\bar{\mathfrak{EO}}}$(n) together with the partitions enumerated by ${\bar{\mathfrak{EO}}}$(n) where all parts are odd and the number of parts is even. They also proved some particular congruences for ${\bar{\mathfrak{EO}}}$(n) and ${\mathfrak{EO}}_e$(n). In this paper, we establish infinitely many families of congruences modulo 2, 4, 5 and 8 for ${\bar{\mathfrak{EO}}}$(n) and modulo 4 for ${\mathfrak{EO}}_e$(n). For example, if p ≥ 5 is a prime with Legendre symbol $({\frac{-3}{p}})=-1$, then for all integers n ≥ 0 and α ≥ 0, we have ${\bar{\mathfrak{EO}}}(8{\cdot}p^{2{\alpha}+1}(pn+j)+{\frac{19{\cdot}p^{2{\alpha}+2}-1}{3}}){\equiv}0$ (mod 8); 1 ≤ j ≤ (p - 1).

Soil Chemistry Changes after N, P, and K Fertilization in a Willow(Salix spp.) Bioenergy Plantation (버드나무(Salix spp.) bioenergy 조림지내(造林地內) N, P, K 시비(施肥)가 토양화학성(土壤化學性) 변화(變化)에 미치는 영향(影響))

  • Park, Gwansoo
    • Journal of Korean Society of Forest Science
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    • v.86 no.3
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    • pp.311-318
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    • 1997
  • Chemical properties of soil(N, P, K, Ca, Na, Mg, CEC, and pH) were studied after annual additions of $NH_4NO_3$(336kg/ha N), treble superphosphate(112kg/ha P), and KCl(224kg/ha K) fertilizers in a willow(Salix spp.) bioenergy plantation. Soil samples were collected from November through December 1992 from previously established the fertilized and non-fertilized willow plantation at Tully, New York, U.S.A. in 1987. Total fertilizer additions from 1987 through 1991 were 1,680kg/ha N and 560kg/ha P and 1.120kg/ha K. Fertilization with N, P, and K resulted in no difference in total soil N content between the fertilized and non-fertilized plots, increased soil P and K, decreased base cations ($Ca^{2+}$ and $Mg^{2+}$) and soil pH, and increased soil pH with soil depth. Strong positive correlations of soil carbon to soil N, Ca, Mg, and CEC were noted. Soil C/N ratio in the study plots ranged from 9.6 to 11.2 for all treatment combinations. Significant differences in soil P, K, Ca, and pH between the fertilized and non-fertilized plots indicate that fertilization had changed chemical properties of soil in this fertilizer trial.

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Preparation of $N-TiO_2$ Photocatalysts and Activity Test ($N-TiO_2$ 광촉매의 제조와 광촉매 활성 검토)

  • Kang, Young-Gu;Shin, Ki-Seok;Ahn, Sung-Hwan;Hahm, Hyun-Sik
    • Journal of the Korean Applied Science and Technology
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    • v.29 no.3
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    • pp.466-472
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    • 2012
  • Visible-light-responding photocatalysts, $N-TiO_2$, were prepared by nitrogen doping onto $TiO_2$. The crystalline structure and morphology, doping state of the prepared photocatalysts were characterized by XRD, FE-SEM, and XPS. The activity of the prepared photocatalysts was examined by the decomposition of methyleneblue. The prepared catalysts were anatase type and the crystallinity was increased with pH. The particle sizes of the prepared catalysts were 5.42, 5.99, 7.58 nm at pH 2.2, 4.7, 9.0, respectively. The particle sizes of the prepared catalysts were slightly increased with pH. The activity of the photocatalysts was directly proportional to the crystallinity of the catalysts. $N-TiO_2$ prepared by nitrogen doping onto $TiO_2$ showed activity under visible light. The doped nitrogen was located not in the lattice but on the surface.

Synthesis, Characterization, and Catalytic Properties of Gp 6 Metal Complexes of 1-N,N-dimethylaminomethyl-$1^{\prime}$,2-bis(diphenylphosphino)ferrocene (FcNPP). X-ray Crystal Structure of W$(CO)_4({\eta}^2-FcNPP(O)-P,N)$

  • Kim, Tae-Jeong;Kim, Yong-Hoon;Kim, Eun-Jin;Oh, Sang-Ho;Kim, Hong-Seok;Jeong, Jong-Hwa
    • Bulletin of the Korean Chemical Society
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    • v.15 no.5
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    • pp.379-386
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    • 1994
  • Reactions of 1',2-bis(diphenylphosphino)-l-(N,N-dimethylaminomethyl)ferrocene (FcNPP) with $M(CO)_6$ (M=Cr, Mo, W) in the presence of TMNO (Trimethylamine oxide) in a stoichiometric ratio of 1 : 1.5 : 3.5 produced a series of Gp 6 metal carbonyl derivatives with a variety of coordination modes: M(CO)$_4({\eta}^2$-FcNPP-P,P) (M=Cr, Mo, W), $M(CO)_5({\eta}^1-FcNPP-P) (M=Mo, W)\;,\; M_2(CO)_9({\eta}^1\;,\;{\eta}^2-FcNPP-P,P,N) (M=Cr, Mo)\;,\;M_2(CO)_{10}({\eta}^1\;,\;{\eta}^1-FcNPP-P,P) (M=Cr, Mo, W)\;, and\;W(CO)_4({\eta}^2-FcNPP(O)-P,N)$. All these complexes were characterized by microanalytical and spectroscopic techniques. In one case, the structure of W(CO)$_4({\eta}^2$-FcNPP(O)-P,N) was determined by X-ray crystallography. Crystals are monocinic, space group P$2_{1/C}$, with a=10.147(2), b=19.902(3), c=19.821(4) ${\AA},\;{\beta}=96.88(2)^{\circ},\;V=3974(l){\AA}^3$, Z=4, and $D_{calc}=1.64 g cm^{-3}$. The geometry around the central tungsten metal is a distorted octahedron, with the nitrogen and phosphorus atoms being cis to each other. Some of these complexes exhibited catalytic activities in the allylic oxidation and epoxidation of cholesterly acetate. Other oxidation products were also formed with the different chemical yields and product distribution depending upon the ligand and the central metal.