• Title/Summary/Keyword: pH-sensitivity

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Sensitivity and Self-purification Function of Forest Ecosystem to Acid Precipitation (II) - Ion Balance in Vegetation and Soil Leachate - (산성우(酸性雨)에 대한 산림생태계(山林生態系)의 민감도(敏感度) 및 자정기능(自淨機能)(II) - 식생층(植生層)과 토양층(土壤層) 용탈(溶脫)이온 분석(分析)을 중심으로 -)

  • Chang, Kwan Soon;Lee, Soo Wook
    • Journal of Korean Society of Forest Science
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    • v.84 no.1
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    • pp.103-113
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    • 1995
  • To estimate buffer capacity and sensitivity of forest ecosystem to acid rain in Taejon, ionic components of throughfall, stemflow, soil leachate, and open rain in Pinus rigida and Quercus variabilis forest were analysed. The spatial sensitivity based on parent rock and forest type was given by IDRISI of GIS which created imagery conversion from soil and vegetation map. Parent rocks and soils were classified into acidic, sedimentary, metamorphic rock and then subdivided based on $SiO_2$ content. Average pH of vegetation leachate was higher in throughfall but lower in stemflow than open rain and higher in Quercus variabilis forest than in Pinus rigida forest. The flow of $SO{_4}^{2-}$, $NO_3{^-}$ and $Cl^-$ through vegetation leaching(throughfall plus stemflow) into soil were 7.2, 4.3, and 2.5 times, respectively, higher in Pinus rigida forest and 4.4, 2, and 2.5 times, respectively, higher in Quercus variabilis forest than in open field. But the concentration of exchangeable cations was 4.1 times higher in Pinus rigida forest and 4.6 times higher in Quercus variabilis forest than in open field. Average pH of soil leachate was lower than that of throughfall, but higher than that of stemflow. The concentration of exchangeable canons and $Al^{3+}$ in soil leachate were more in Pinus rigida forest than in Quercus variabilis forest and increase signficantly with the increase of acidic deposits. Pinus forest had more deposition and canopy interception of acidic pollutants and more nutrient loss than Quercus forest, and Quercus forest had more cation exchange and proton consumption and than consequently had less nutrient loss and better buffer capacity than Pinus forest. The 69% of forest soils was distributed on acidic rock, 25% of it on metamorphic rock, and 6% of it on intermediate and basic rock. Acidic rock residuals which had low very canon exchange capacity and high sensitivity to acid rain occupied a half of total forest land in Taejon area. Therefore forests in Taejon showed high vulnerability to acid rain and will receive much more stress with the increase of acid rain precursors.

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Polarization Characteristics of Polymers: Poly(vinylchloride), Poly(ethyleneterephthalate), Poly(propylene), and Poly(carbonate) (고분자물질들의 분극 특성: Poly(vinylchloride), Poly(ethyleneterephthalate), Poly(propylene), Poly(carbonate))

  • Choi, Chil-Nam;Yang, Hyo-Kyung
    • Journal of the Korean Chemical Society
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    • v.46 no.1
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    • pp.19-25
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    • 2002
  • We measured the variations of potentials and current densities for several polymers. The results were carefully examined to identify various factors such as temperature and pH to influence the potential and rate. The Tafel slope for anodic dissolution was determined by the polarization effect under these conditions. The optimum conditions were established for each case. The second anodic current density peak and maximum current density were designated as the relative polarization sensitivity $(I_r/I_f)$. The mass-transfer coefficient value $({\alpha})$ was determined by the Tafel slope for anodic dissolution on the basis of the polarization effect under optimum conditions.

Study on the Modelling of Algal Dynamics in Lake Paldang Using Artificial Neural Networks (인공신경망을 이용한 팔당호의 조류발생 모델 연구)

  • Park, Hae-Kyung;Kim, Eun-Kyoung
    • Journal of Korean Society on Water Environment
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    • v.29 no.1
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    • pp.19-28
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    • 2013
  • Artificial neural networks were used for time series modelling of algal dynamics of whole year and by season at the Paldang dam station (confluence area). The modelling was based on comprehensive weekly water quality data from 1997 to 2004 at the Paldang dam station. The results of validation of seasonal models showed that the timing and magnitude of the observed chlorophyll a concentration was predicted better, compared with the ANN model for whole year. Internal weightings of the inputs in trained neural networks were obtained by sensitivity analysis for identification of the primary driving mechanisms in the system dynamics. pH, COD, TP determined most the dynamics of chlorophyll a, although these inputs were not the real driving variable for algal growth. Short-term prediction models that perform one or two weeks ahead predictions of chlorophyll a concentration were designed for the application of Harmful Algal Alert System in Lake Paldang. Short-term-ahead ANN models showed the possibilities of application of Harmful Algal Alert System after increasing ANN model's performance.

Yeast Loading BOD Biosensor (효모균을 이용한 BOD Biosensor)

  • Kim, Mal-Nam
    • The Korean Journal of Mycology
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    • v.23 no.4 s.75
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    • pp.354-358
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    • 1995
  • A yeast loading biochemical oxygen demand (BOD) sensor was designed and constructed to quickly measure the concentration of biologically assimilable organic substances dissolved in water as BOD values to feed back to the waste water treating processes. The sensitivity of the BOD sensor reached maximum at around pH 7.0 and $30^{\circ}C$ where yeast showed the highest assimilation activity. Biomass also affected the sensor output, and biomass of $ 0.14\;mg/cm^2$ on the dialysis membrane appeared to be the optimum cell mass level. The sensitivity of the sensor depended on the kinds of pollutants and increased considerably when the yeast was preincubated in the solution of respective pollutants before loading on the sensor.

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THE SENSITIVITY OF STRUCTURAL RESPONSE USING FINITE ELEMENTS IN TIME

  • Park, Sungho;Kim, Seung-Jo
    • Journal of Theoretical and Applied Mechanics
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    • v.3 no.1
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    • pp.66-80
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    • 2002
  • The bilinear formulation proposed earlier by Peters and Izadpanah to develop finite elements in time to solve undamped linear systems, Is extended (and found to be readily amenable) to develop time finite elements to obtain transient responses of both linear and nonlinear, and damped and undamped systems. The formulation Is used in the h-, p- and hp-versions. The resulting linear and nonlinear algebraic equations are differentiated to obtain the first- and second-order sensitivities of the transient response with respect to various system parameters. The present developments were tested on a series of linear and nonlinear examples and were found to yield, when compared with results obtained using other methods, excellent results for both the transient response and Its sensitivity to system parameters. Mostly. the results were obtained using the Legendre polynomials as basis functions, though. in some cases other orthogonal polynomials namely. the Hermite. the Chebyshev, and integrated Legendre polynomials were also employed (but to no great advantage). A key advantage of the time finite element method, and the one often overlooked in its past applications, is the ease In which the sensitivity of the transient response with respect to various system parameters can be obtained. The results of sensitivity analysis can be used for approximate schemes for efficient solution of design optimization problems. Also. the results can be applied to gradient-based parameter identification schemes.

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Shape Design Sensitivity Analysis using Isogeometric Approach (CAD 형상을 활용한 설계 민감도 해석)

  • Ha, Seung-Hyun;Cho, Seon-Ho
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 2007.04a
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    • pp.577-582
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    • 2007
  • A variational formulation for plane elasticity problems is derived based on an isogeometric approach. The isogeometric analysis is an emerging methodology such that the basis functions in analysis domain arc generated directly from NURBS (Non-Uniform Rational B-Splines) geometry. Thus. the solution space can be represented in terms of the same functions to represent the geometry. The coefficients of basis functions or the control variables play the role of degrees-of-freedom. Furthermore, due to h-. p-, and k-refinement schemes, the high order geometric features can be described exactly and easily without tedious re-meshing process. The isogeometric sensitivity analysis method enables us to analyze arbitrarily shaped structures without re-meshing. Also, it provides a precise construction method of finite element model to exactly represent geometry using B-spline base functions in CAD geometric modeling. To obtain precise shape sensitivity, the normal and curvature of boundary should be taken into account in the shape sensitivity expressions. However, in conventional finite element methods, the normal information is inaccurate and the curvature is generally missing due to the use of linear interpolation functions. A continuum-based adjoint sensitivity analysis method using the isogeometric approach is derived for the plane elasticity problems. The conventional shape optimization using the finite element method has some difficulties in the parameterization of boundary. In isogeometric analysis, however, the geometric properties arc already embedded in the B-spline shape functions and control points. The perturbation of control points in isogeometric analysis automatically results in shape changes. Using the conventional finite clement method, the inter-element continuity of the design space is not guaranteed so that the normal vector and curvature arc not accurate enough. On tile other hand, in isogeometric analysis, these values arc continuous over the whole design space so that accurate shape sensitivity can be obtained. Through numerical examples, the developed isogeometric sensitivity analysis method is verified to show excellent agreement with finite difference sensitivity.

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α1-adrenoceptor stimulation increases intracellular pH and Na+ via Na+-H+ exchange in guinea pig papillary muscle (기니픽 유두근에서 α1-adrenoceptor 자극에 의한 세포내 pH와 Na+ 증가는 Na+-H+ 교환기를 경유)

  • Kim, Jin-sang
    • Korean Journal of Veterinary Research
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    • v.35 no.2
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    • pp.229-236
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    • 1995
  • The effect of ${\alpha}_1$-adrenoceptor(${\alpha}_1$-AR) stimulation on intracellular pH($pH_i$), $Na^+$ activity($a_{Na}{^i}$) and contractility were investigated in isolated papillary muscles of euthyroid or hyperthyroid guinea pig with conventional microelectrode, $Na^+$ or $H^+$-selective microelectrodes, and tension transducer. Stimulation of the ${\alpha}_1$-AR by phenylephrine produced a decrease in $a_{Na}{^i}$ in euthyroid preparations. This decrease in $a_{Na}{^i}$ was abolished in presence of PKC activator, phorbol dibutyrate, and increased contrary to decrease. Phenylephrine also increased $a_{Na}{^i}$ in hyperthyroid ones. However, phenylrephtine produced an increase in $pH_i$ in both euthyroid and hyperthyroid ones. These changes were blocked by prazosin, an antagonist of ${\alpha}_1$-AR. These findings suggest that the changes in $a_{Na}{^i}$ and $pH_i$ are mediated by a stimulation of $Na^+-H^+$ exchange via ${\alpha}_1$-AR stimulation. This study focused on the increase in $a_{Na}{^i}$, $pH_i$ and contractility. The increase in $pH_i$ was blocked by amiloride or EIPA, $Na^+-H^+$ exchange inhibitors. Therefore, the increase in $a_{Na}{^i}$ and $pH_i$ mediated by ${\alpha}_1$-AR appeared to be due to an influx of $Na^+$ and a reduction of $H^+$ through $Na^+-H^+$ exchange. This study also revealed that the increase in $pH_i$ and $a_{Na}{^i}$ might be related to the sustained positive inotropic response. The $a_{Na}{^i}$ increase may contribute to the intracellular $Ca^{2+}$ through the $Na^+-Ca^{2+}$ exchange, and the $pH_i$ increase could cause an increase in the $Ca^{2+}$ sensitivity of myofilaments and may augment the ${\alpha}_1$-AR-mediated positive inotropic response.

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Opimization of HDD Suspension Shape Using Sensitivity Analysis and Sequential Linear Programing (감도해석 및 순차적 선형계획법을 이용한 HDD 서스펜션의 형상 최적화)

  • Hwang, C.H.;Kim, D.W.;Lee, J.S.;Park, Y.P.;Park, N.C.
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2002.11b
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    • pp.128-133
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    • 2002
  • The main obstacle to high track density in HDD is the structural resonances of the suspension. The most critical mode is sway mode and second torsion mode, when a data is read and written. It is common fact that the effect of two modes is smaller when a thickness is bulky. But the stiffness of suspension is smaller, the slider can follow a disk better. Because these two fact are reciprocal, a compromise is needed. So we investigated another method to improve band width without changing of the thickness of suspension but with changing of the shape. In this paper, we use two method - Sensitivity analysis and SIP using ADS. And we obtained the optimized value close to target value.

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The Comparison of Skin Physical Parameters in Asian Women (아시아 여성의 피부 물리적 변수들의 비교)

  • Lee, Jung Ah;Song, Eun Jeung;Park, Jung Jun;Kim, Hyun Ju;Kim, Sin Hae;Kim, Nam Soo;Moon, Tae Kee
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.43 no.4
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    • pp.297-307
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    • 2017
  • Skin properties are influenced by a variety of internal or external factors. This study was conducted to investigate and compare the skin characteristics in Asian women. We evaluated values of skin physical parameters, and then assessed the correlations among the parameters, and regional differences in 1,500 Asian subjects in seven countries (Malaysia, Indonesia, Vietnam, Thailand, India, China, and South Korea). The values of transepidermal water loss (TEWL), pH, skin hydration, sebum content, skin sensitivity, elasticity, crow's feet wrinkles, and skin brightness were measured. New Delhi's women were observed to have a lower level of hydration in stratum corneum, sebum content, stinging scores, and darker skin color than others. Furthermore, their skin surface pH on all sites is the highest among seven countries. Vietnamese had the lowest pH values in skin surface. Korean and Chinese had generally higher elasticity and fewer wrinkles. Both the skin hydration and TEWL had positive correlations with the stinging test, and there was a negative correlation between wrinkles and stinging test. These results represent that there was no clear trend related to the area or region. Skin physical parameters should be studied along with understanding of regional differences and various factors (skin care habits, lifestyle and personal sensitivity).

Structural and Electrical Properties of an Electrolyte-insulator-metal Device with Variations in the Surface Area of the Anodic Aluminum Oxide Template for pH Sensors

  • Kim, Yong-Jun;Lee, Sung-Gap;Yeo, Jin-Ho;Jo, Ye-Won
    • Journal of Electrical Engineering and Technology
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    • v.10 no.6
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    • pp.2364-2367
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    • 2015
  • In this study, we fabricated an electrolyte-insulator-metal (EIM) device incorporating a high-k Al2O3 sensing membrane using a porous anodic aluminum oxide (AAO) through a two-step anodizing process for pH detection. The structural properties were observed by field-emission scanning electron microscopy (FE-SEM) and X-ray diffraction patterns (XRD). Electrochemical measurements taken consisted of capacitance-voltage (C-V), hysteresis voltage and drift rates. The average pore diameter and depth of the AAO membrane with a pore-widening time of 20 min were 123nm and 273.5nm, respectively. At a pore-widening time of 20 min, the EIM device using anodic aluminum oxide exhibited a high sensitivity (56mV/pH), hysteresis voltage (6.2mV) and drift rate (0.25mV/pH).