• Title/Summary/Keyword: pH sensing

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Ferricyanide-Sensing Electrodes

  • Ihn, Gwon-Shik
    • Bulletin of the Korean Chemical Society
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    • v.7 no.1
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    • pp.36-38
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    • 1986
  • The Ferricyanide-sensing electrodes were prepared with $Ag_2S\;and\;Ag_3Fe(CN)_6$ (mole ratio 3:1-7:1). The 5:1 $(Ag_2S:Ag_3Fe(CN)_6)$ composition is superior to others in terms of potentiometric response, rapidity of response and reproducibility. Testing was done over the concentration range $10^{-1}M{\sim}10^{-6}M\; Fe(CN)_6^{3-}$ at pH 6.8 with constant ionic strength. The concentration-potential curve was linear and coincided with the Nernstian slope (19.7 mV/decade). Interfering ions were $I^-,\;Br^-,\; SCN^-\;and\;Fe(CN)_6^{4-}$ and the life time of this electrode was 3 weeks. This electrode could be used as the indicator electrode for measuring the ferricyanide and ferrocyanide.

Trends in Disaster Environment Multimodal Sensing Platforms (재난환경 멀티모달 센싱 플랫폼 기술 동향)

  • S.M. Park;P.J. Park;K.H. Park;B.T. Koo
    • Electronics and Telecommunications Trends
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    • v.39 no.5
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    • pp.31-39
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    • 2024
  • For a quick and accurate response at a disaster site, technological solutions are essential to overcome limited visual information, secure environmental information, and identify victim locations. Research on artificial-intelligence-based semiconductors is being actively conducted to address existing challenges. In fact, new technologies combining various sensor signals are required to provide accurate and timely information at disaster sites. We examine existing disaster environment multimodal sensing technologies and discuss the status of disaster risk detection and monitoring technologies. Additionally, we present current problems and future directions of development.

Electrochemical properties of the mugwort-embedded biosensor for the determination of hydrogen peroxide (쑥을 이용한 과산화수소 정량 바이오센서의 전기화학적 성질)

  • Lee, Beom-Gyu;Park, Sung-Woo;Yoon, Kil-Joong
    • Analytical Science and Technology
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    • v.19 no.1
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    • pp.58-64
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    • 2006
  • A mugwort-tissue-based modified carbon paste electrode was constructed for the amperometric detection of hydrogen peroxide and its electrochemical properties are described. Especially the amperometric signal was very stable and bigger than any other enzyme electrode studied in this lab. The effect of tissue composition on the response was linear within the wide range of experiment and the linearity of Lineweaver-Burk plot showed that the sensing process of the biosensor is by enzymatic catalysis. And pH dependent current profile connoted that two isozymes are active in this system.

Characteristics and Application of the Highly-Durable and Highly-Sensitive Super Hydrophobic Acid-gas Sensing Dye (고내구성 고감도 강산감지기능 초소수성 색소의 특성 및 응용)

  • Kim, Taekyeong;Lee, Seonae
    • Textile Coloration and Finishing
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    • v.27 no.2
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    • pp.105-112
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    • 2015
  • In order to detect gas phase strong acid on fabrics, a hexyl-substituted monoazo yellow dye, which was the modified form of a conventional pH-indicating dye, Methyl Yellow, was studied in view of acid-gas sensing properties and its fastness. The dye was printed on polypropylene non-wovens for protective coveralls and examined under various conditions of strong acid such as hydrochloric acid. The dye showed color change from yellow to red on exposure to gas phase hydrochloric acid as low concentration as 1~3 ppm very instantly. Considering reuse of the dye-printed non-wovens, the repeatability of color change was tested on the same sample for 50 repeats and 100 days. The acid-gas sensing function was maintained almost the same level of initial performance. The color fastness of the dye on polypropylene non-wovens was very good showing higher than ratings 4 except for 3~4 to rubbing under wet condition.

Real-time structural damage detection using wireless sensing and monitoring system

  • Lu, Kung-Chun;Loh, Chin-Hsiung;Yang, Yuan-Sen;Lynch, Jerome P.;Law, K.H.
    • Smart Structures and Systems
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    • v.4 no.6
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    • pp.759-777
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    • 2008
  • A wireless sensing system is designed for application to structural monitoring and damage detection applications. Embedded in the wireless monitoring module is a two-tier prediction model, the auto-regressive (AR) and the autoregressive model with exogenous inputs (ARX), used to obtain damage sensitive features of a structure. To validate the performance of the proposed wireless monitoring and damage detection system, two near full scale single-story RC-frames, with and without brick wall system, are instrumented with the wireless monitoring system for real time damage detection during shaking table tests. White noise and seismic ground motion records are applied to the base of the structure using a shaking table. Pattern classification methods are then adopted to classify the structure as damaged or undamaged using time series coefficients as entities of a damage-sensitive feature vector. The demonstration of the damage detection methodology is shown to be capable of identifying damage using a wireless structural monitoring system. The accuracy and sensitivity of the MEMS-based wireless sensors employed are also verified through comparison to data recorded using a traditional wired monitoring system.

Teaching a Known Molecule New Tricks: Optical Cyanide Recognition by 2-[(9-Ethyl-9H-carbazol-3-yl)methylene]propanedinitrile in Aqueous Solution

  • Tang, Lijun;Zhao, Guoyou;Wang, Nannan
    • Bulletin of the Korean Chemical Society
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    • v.33 no.11
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    • pp.3696-3700
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    • 2012
  • The colorimetric and fluorescent cyanide recognition properties of 2-[(9-ethyl-9H-carbazol-3-yl)methylene]-propanedinitrile (1) in $CH_3CN-H_2O$ (2/1, v/v, HEPES 10 mM, pH = 7.0) solution were evaluated. The optical recognition process of probe 1 exhibited high sensitivity and selectivity to cyanide ion with the detection limit of $2.04{\times}10^{-6}$ M and barely interfered by other coexisting anions. The sensing mechanism of probe 1 is speculated to undergo a nucleophilic addition of cyanide to dicyanovinyl group present in compound 1. The colorimetric and fluorescent dual-modal response to cyanide makes probe 1 has a potential utility in cyanide detection.

Sensing Nitrate and Potassium Ions in Soil Extracts Using Ion-Selective Electrodes (이온선택성 전극을 이용한 토양추출물의 질산 및 칼륨이온 측정)

  • Kim, H.J.;Sudduth Kenneth A.;Hummel John W.
    • Journal of Biosystems Engineering
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    • v.31 no.6 s.119
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    • pp.463-473
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    • 2006
  • Automated sensing of soil macronutrients would allow more efficient mapping of soil nutrient spatial variability for variable-rate nutrient management. The capabilities of ion-selective electrodes for sensing macronutrients in soil extracts can be affected by the presence of other ions in the soil itself as well as by high concentrations of ions in soil extractants. Adoption of automated, on-the-go sensing of soil nutrients would be enhanced if a single extracting solution could be used for the concurrent extraction of multiple soil macronutrients. This paper reports on the ability of the Kelowna extractant to extract macronutrients (N, P, and K) from US Corn Belt soils and whether previously developed PVC-based nitrate and potassium ion-selective electrodes could determine the nitrate and potassium concentrations in soil extracts obtained using the Kelowna extractant. The extraction efficiencies of nitrate-N and phosphorus obtained with the Kelowna solution for seven US Corn Belt soils were comparable to those obtained with IM KCI and Mehlich III solutions when measured with automated ion and ICP analyzers, respectively. However, the potassium levels extracted with the Kelowna extractant were, on average, 42% less than those obtained with the Mehlich III solution. Nevertheless, it was expected that Kelowna could extract proportional amounts of potassium ion due to a strong linear relationship ($r^2$ = 0.96). Use of the PVC-based nitrate and potassium ion-selective electrodes proved to be feasible in measuring nitrate-N and potassium ions in Kelowna - soil extracts with almost 1 : 1 relationships and high coefficients of determination ($r^2$ > 0.9) between the levels of nitrate-N and potassium obtained with the ion-selective electrodes and standard analytical instruments.

The Fabrication of FET-Type NOx Gas Sensing System Using the MWCNT (다중벽 카본 나노튜브를 이용한 FET식 NOx 가스 센싱 시스템 제작)

  • Kim, Hyun-Soo;Jang, Kyung-Uk
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.4
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    • pp.325-329
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    • 2013
  • Carbon nanotubes(CNT) have excellent electrical, chemical stability and mechanical properties. These can be used in a variety of fields. MWCNT are extremely sensitive for minute changes in the ambient gas, namely, their sensing properties varies greatly with the absorption of gas such as NOx and $H_2$. We investigate the electrical properties of CNTs and make a NOx gas sensor based on Multi-walled carbon nanotubes (MWCNT) materials. We obtained the NOx gas sensor of MWCNT based on P-type Si wafer that has the resistivity of $1.667{\times}10^{-1}[{\Omega}{\cdot}cm]$. We knew that the sensitivity of sensor decreased with increasing of NOx gas concentration. And the sensitivity of sensor shows the largest value at $20^{\circ}C$. The sensitivity of sensor decrease with increasing the temperature. Also absorption energy of NOx gas molecule on the MWCNT surface decreases with increasing concentration of NOx gas.

Acetone Sensing Characteristics of ZnO Nanoparticles Prepared from Zeolitic Imidazolate Framework-7 (Zeolitic Imidazolate Framework-7로 합성한 ZnO 나노입자의 Acetone 가스 감응 특성)

  • Yoon, Ji Won;Wang, Rui;Park, Joon-Shik;Lee, Jong-Heun
    • Journal of Sensor Science and Technology
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    • v.26 no.3
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    • pp.204-208
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    • 2017
  • Highly uniform and well-dispersed Zeolitic Imidazolate Framework-7 (ZIF-7) particles were prepared by the precipitation of $Zn^{2+}$ using benzimidazole, which were converted into ZnO nanoparticles by heat treatment at $500^{\circ}C$ for 24 h. The ZIF-7 derived ZnO nanoparticles showed abundant mesopores, high surface area, and good dispersion. The gas sensing characteristics toward 5 ppm acetone, ethanol, trimethylamine, ammonia, p-xylene, toluene, benzene, and carbon monoxide and carbon dioxide were investigated at $350-450^{\circ}C$. ZIF-7 derived ZnO nanoparticles exhibited high response to 5 ppm acetone ($R_a/R_g=57.6$; $R_a$: resistance under exposure to the air, Rg: resistance under exposure to the gas) at $450^{\circ}C$ and negligible cross-responses to other interference gases (trimethylamine, ammonia, p-xylene, toluene, benzene, carbon monoxide, carbon dioxide) and relatively low responses to ethanol. ZIF derived synthesis of metal oxide nanoparticles can be used to design high performance acetone sensors.

Embedded Micro Fluxgate Sensor in Printed Circuit Board (PCB) (PCB 기판에 내장된 마이크로 플럭스게이트 센서)

  • 최원열;황준식;강명삼;최상언
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.8
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    • pp.702-707
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    • 2002
  • This paper presents a micro fluxgate sensor in printed circuit board (PCB). The fluxgate sensor consists of five PCB stack layers including one layer magnetic core and four layers of excitation and pick-up coils. The center layer as a magnetic core is made of a micro patterned amorphous magnetic ribbon and the core has a rectangular-ring shape. The amorphous magnetic core is easily saturated due to the low coercive field and closed magnetic path for the excitation field. Four outer layers as an excitation and pick-up coils have a planar solenoid structure. The chip size of the fabricated sensing element is 7.3$\times$5.7$\textrm{mm}^2$. Excellent linear response over the range of -100$\mu$T to +100$\mu$T is obtained with 540V/T sensitivity at excitation square wave of 3 $V_{p-p}$ and 360kHz. The very low power consumption of ~8mW was measured. This magnetic sensing element, which measures the lower fields than 50$\mu$T, is very useful for various applications such as: portable navigation systems, military research, medical research, and space research.h.