• Journal of Electrochemical Science and Technology
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• 제14권1호
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• pp.66-74
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• 2023

In this study, a new potentiometric sensor selective to copper(II) ions was developed and characterized. The developed sensor has a polymeric membrane and contains 4.0% electroactive material (ionophore), 33.0% poly(vinyl chloride) (PVC), 63.0% bis(2-ethylhexyl)sebacate (BEHS) and 1.0% potassium tetrakis(p-chlorophenyl)borate (KTpClPB). This novel copper(II)-selective sensor exhibits a Nernstian response over a wide concentration range from 1.0×10^-6 to 1.0×10^-1 mol L^-1 with a slope of 29.6 (±1.2) mV decade^-1, and a lower detection limit of 8.75×10-7 mol L^-1. The sensor, which was produced economically by synthesizing the ionophore in the laboratory, has a good selectivity and repeatability, fast response time and stable potentiometric behaviour. The potential response of the sensor remains unaffected of pH in the range of 5.0-10.0. Based on the analytical applications of the sensor, we showed that it can be used as an indicator electrode in the quantification of Cu²⁺ ions by potentiometric titration against EDTA, and can also be successfully utilized for the determination of copper(II) ions in different real samples.

• 공업화학
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• 제1권2호
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• pp.154-160
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• 1990

glucose의 농도에 따라 인슐린의 방출을 조절하기 위하여 3급 아민을 함유하는 Hydroxypropyl methacrylate 고분자막을 합성하였다. 이 막의 함수율은 수용액의 pH가 감소함에 따라 증가하였다. 인슐린의 투과도 역시 수용액의 pH가 감소함에 따라 증가하였다. 이 막에 당산화효소를 고정화시킨 acryl amine 막을 부착하여 복합막을 제조하였다. 이 막의 인슐린 투과도는 glucose의 농도가 증가함에 따라 증가하였다.

• 분석과학
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• 제14권3호
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• pp.286-289
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• 2001

The effect of pH and the substrate concentration on the sensing ability of the chicken peroxidase enzyme electrode was examined quanititatively. Using the new Michaelis-Menten equation, to which pH concept was introduced, enabled to calculate all kinds of dissociation constant related to chicken peroxidase and subsequently to determine the optimum pH of the sensor.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2004년도 하계학술대회 논문집 C
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• pp.1762-1765
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• 2004

This paper suggest the field test method of PD UHF sensor's sensitivity for a high voltage GIS and prove a reliability of the field test method through the test results of UHF sensor.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1999년도 추계학술대회 논문집 학회본부 C
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• pp.956-958
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• 1999

We designed and fabricated p-type MOSFETs with floating gate in n-type well lesion and examined their photo characteristics. The fabricated MOBFETs showed a high photo-respsonse characteristics, indicating a possibility as a photo sensor. The structures of MOSFETs were changed as to the number of gate and channel. As the number of channel increased, the induced current by light source s increased. However, the effect of the number of gate was negligble on the photo-response characteristics of the device.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2004년도 춘계학술대회 논문집 전기설비전문위원
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• pp.121-124
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• 2004

This paper suggest the field test method of PD UHF sensor's sensitivity for a high voltage GIS and prove a reliability of the field test method through the test results of UHF sensor.

• Bulletin of the Korean Chemical Society
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• 제30권12호
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• pp.2979-2983
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• 2009

Nanowires of polytetrakis(o-aminophenyl)porphyrin (PTAPPNW) were fabricated by electrochemical polymerization with the cyclic voltammetric method in anodic aluminum oxide (AAO) membranes. The glassy carbon electrode (GCE) modified by PTAPPNW, single-walled carbon nanotubes (SWNT) and Nafion as a binder was investigated with voltammetric methods in a phosphate buffer saline (PBS) solution at pH 7.4. The PTAPPNW + SWNT + Nafion/GCE exhibited strongly enhanced voltammetric and amperometric sensitivity towards hydrogen peroxide ($H_2O_2$), which shortened the response time and enhanced the sensitivity for $H_2O_2$ determination at an applied potential of 0.0 V by amperometric method. The PTAPPNW + SWNT + Nafion/GCE can be used to monitor $H_2O_2$ at very low concentrations in biological pH as an efficient electrochemical $H_2O_2$ sensor.

• 센서학회지
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• 제10권4호
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• pp.266-272
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• 2001

자동차 엔진오일의 열화상태를 직접 in situ로 측정할 수 있는 코일형 전기용량 센서를 개발하였다. 엔진 오일팬의 드레인 홀의 제한된 공간 속에서 10 pF 이상을 얻기 위하여 코일형으로 설계 제작되었다. 코일의 직경 및 권선 조건, 포머의 재질 및 구조, 차폐조건 등 안정된 전기용량 측정을 위한 설계 요구 조건을 컴퓨터 시뮬레이션과 실험적인 방법에 의해서 찾아내었다. 제작된 여러 개의 센서를 이용하여 동일한 조건의 사용오일 특성을 분석한 결과 0.25% 이내에서 일치하였다. 차량에 직접 장착하여 장기간 측정한 결과, 심한 진동과 온도 및 습도변화와 전자기적 잡음 등 열악한 차량의 조건에서도 매우 우수한 측정결과를 나타내었다.

• 한국전기전자재료학회논문지
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• 제26권4호
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• pp.325-329
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• 2013

Carbon nanotubes(CNT) have excellent electrical, chemical stability and mechanical properties. These can be used in a variety of fields. MWCNT are extremely sensitive for minute changes in the ambient gas, namely, their sensing properties varies greatly with the absorption of gas such as NOx and $H_2$. We investigate the electrical properties of CNTs and make a NOx gas sensor based on Multi-walled carbon nanotubes (MWCNT) materials. We obtained the NOx gas sensor of MWCNT based on P-type Si wafer that has the resistivity of $1.667{\times}10^{-1}[{\Omega}{\cdot}cm]$. We knew that the sensitivity of sensor decreased with increasing of NOx gas concentration. And the sensitivity of sensor shows the largest value at $20^{\circ}C$. The sensitivity of sensor decrease with increasing the temperature. Also absorption energy of NOx gas molecule on the MWCNT surface decreases with increasing concentration of NOx gas.

• 전기학회논문지P
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• 제55권1호
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• pp.31-34
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• 2006

A infrared rays sensor or ultrasonic sensor can detect the object at the narrow area, however a pressure sensor can detect man and animal at the wide area. It is necessary to manufacture the sensor by using Pb-free ceramics in the respect of environmental protection. Piezoelectric properties of ceramics added 0.2wt% $La_2O_3\;into\;0.96Bi_{0.5}(Na_{0.84}K_{0.16})_{0.5}+0.04SrTiO_3$ were 0.4 of kp, $31{\times}$10^{-3}Vm/N\;of\;g_{33}$. The output voltage of the pressure sensor is 0.48 V at 20 in$H_2O$. The output voltage of the pressure sensor with driving circuit is 9.8 V, 37 ms width.