• Title/Summary/Keyword: pH Sensor

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Query Processing of Sensor Network using Sensing View (센싱 뷰를 이용한 센서 네트워크에서의 질의 처리)

  • Kim, Hae-Jung;Hong, J.P.;Hong, S.B.;Kim, C.H.;Kim, S.K.;Park, C.J.
    • Proceedings of the Korean Information Science Society Conference
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    • 2006.10c
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    • pp.93-97
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    • 2006
  • 센서 네트워크에서 질의 처리 기술은 통신 비용을 절감하고 신뢰성을 향상하고 에너지 효율성을 향상시키는데 목적을 두고 있다. 현재 에너지의 효율성을 위해서 센서 노드가 수행하는 질의를 최적화하여 전력 손실을 줄이고자 하는 연구가 활발하게 수행 중이다. 본 논문에서는 실체 뷰와 인덱싱 뷰를 이용하여 센서 네트워크에 맞는 효율적인 새로운 센싱 뷰라는 기법을 제안한다. 제안하는 질의 처리 알고리즘은 실체 뷰와 인덱싱 뷰의 개념을 바탕으로 기존의 분산 데이터베이스의 질의 처리 방법을 센서 네트워크에 적용하였다. 제안된 센싱 뷰 알고리즘은 센싱 뷰를 싱크 노드에 위치시킴으로서 센서 노드와의 통신 횟수를 최대한 줄임으로서 통신 비용과 에너지의 소모량을 줄일 수 있었다. 성능은 시뮬레이션을 통해서 평균적으로 약 30%정도의 성능 향상 효과를 보였다.

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Detection of Organic Vapors Using Change of Fabry-Perot Fringe Pattern of Surface Functionalized Porous Silicon (표면 기능성을 가진 다공성 실리콘의 Fabry-Perot fringe pattern의 변화를 이용한 유기 화합물의 감지)

  • Hwang, Minwoo;Cho, Sungdong
    • Journal of Integrative Natural Science
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    • v.3 no.3
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    • pp.168-173
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    • 2010
  • Novel porous silicon chip exhibiting dual optical properties, both Frbry-Perot fringe (optical reflectivity) and photoluminescence had been developed and used as chemical sensors. Porous silicon samples were prepared by an electrochemical etch of p-type sillicon wafer (boron-doped, <100> orientation, resistivity 1 - 10 ${\Omega}$). The ething solution was prepared by adding an equal volume of pure ethanol to an aqueous solution of HF (48% by weight). The porous silicon was illuminated with a 300 W tungsten lamp for the duration of etch. Ething was carried out as a two-electrode Kithley 2420 preocedure at an anodic current. The surface of porous silicon was characterized by FT-IR instrument. The porosity of samples was about 80%. Three different types of porous silicon, fresh porous silicon (Si-H termianated), oxidized porous silicon (Si-OH terminated), and surface-derivatized porous silicon (Si-R terminated), were prepared by the thermal oxidation and hydrosilylation. Then the samples were exposed to the wapor of various organics vapors. such as chloroform, hexane, methanol, benzene, isopropanol, and toluene. Both reflectivity and photoluminescence were simultaneously measured under the exposure of organic wapors.

UO22+ Ion-Selective Membrane Electrode Based on a Naphthol-Derivative Schiff's Base 2,2'-[1,2-Ethandiyl bis(nitriloethylidene)]bis(1-naphthalene)

  • Shamsipur, Mojtaba;Saeidi, Mahboubeh;Yari, Abdullah;Yaganeh-Faal, Ali;Mashhadizadeh, Mohammad Hossein;Azimi, Gholamhasan;Naeimi, Hossein;Sharghi, Hashem
    • Bulletin of the Korean Chemical Society
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    • v.25 no.5
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    • pp.629-633
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    • 2004
  • A new PVC membrane electrode for $UO_2^{2+}$ ion based on 2,2'-[1,2-ethanediyl bis (nitriloethylidene)]bis(1-naphthalene) as a suitable ionophore was prepared. The electrode exhibites a Nernstian response for $UO_2^{2+}$ ion over a wide concentration range ($1.0{\times}10^{-1}-1.0{\times}10^{-7}$M) with a slope of 28.5 ${\pm}$ 0.8 mV/decade. The limit of detection is $7.0{\times}10^{-8}$M. The electrode has a response time of < 20 s and a useful working pH range of 3-4. The proposed membrane sensor shows good discriminating abilities towards $UO_2^{2+}$ ion with regard to several alkali, alkaline earth transition and heavy metal ions. It was successfully used to the recovery of uranyl ion from, tap water and, as an indicator electrode, in potentiometric titration of $UO_2^{2+}$ ion with Piroxycam.

Experimental Evaluation of Superconductor Flywheel Energy Storage System with Hybrid Type Active Magnetic Bearing (하이브리드 AMB를 포함한 초전도 플라이휠 에너지 저장장치의 실험평가)

  • Lee, J.P.;Kim, H.G.;Han, S.C.
    • Progress in Superconductivity
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    • v.13 no.3
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    • pp.195-202
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    • 2012
  • In this paper, we designed Active Magnetic Bearing (AMB) for large scale Superconductor Flywheel Energy Storage System (SFESS) and PD controller for AMB. And we experimentally evaluated SFESS including hybrid type AMB. The radial AMB was designed to provide force slew rate that was sufficient for the unbalance disturbances at the maximum operating speed. The thrust AMB is a hybrid type where a permanent magnet carries the weight of the flywheel and an electromagnetic actuator generates the dynamic control force. We evaluated the design performance of the manufactured AMB through comparison of FEM analysis and the results of experimental force measurement. In order to obtain gains of PD controller and design a notch filter, the system identification was performed through measuring frequency response including dynamics for the AMBs, a power amp and a sensor using a sine swept test method after levitating the flywheel. Through measuring the current input of the AMBs and the orbit of a flywheel according to rotational speed, we verified excellent control performance of the AMBs with small amount current for the large scale SFESS.

Chitosan-Cu-salen/Carbon Nano-Composite Based Electrode for the Enzyme-less Electrochemical Sensing of Hydrogen Peroxide

  • Jirimali, Harishchandra Digambar;Saravanakumar, Duraisamy;Shin, Woonsup
    • Journal of Electrochemical Science and Technology
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    • v.9 no.3
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    • pp.169-175
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    • 2018
  • Cu-Salen complex was prepared and attached into chitosan (Cs) polymer backbone. Nanocomposite of the synthesized polymer was prepared with functionalized carbon nano-particles (Cs-Cu-sal/C) to modify the electrode surface. The surface morphology of (Cs-Cu-sal/C) nanocomposite film showed a homogeneous distribution of carbon nanoparticles within the polymeric matrix. The cyclic voltammogram of the modified electrode exhibited a redox behavior at -0.1 V vs. Ag/AgCl (3 M KCl) in 0.1 M PB (pH 7) and showed an excellent hydrogen peroxide reduction activity. The Cs-Cu-sal/C electrode displays a linear response from $5{\times}10^{-6}$ to $5{\times}10^{-4}M$, with a correlation coefficient of 0.993 and detection limit of $0.9{\mu}M$ (at S/N = 3). The sensitivity of the electrode was found to be $0.356{\mu}A\;{\mu}M^{-1}\;cm^{-2}$.

The Potentiometric Performance of Mercury (II) Ion-Selective Electrode Based on Tetracycline Antibiotics

  • Baek, Jong-Gyu;Rhee Paeng, In-Sook
    • Journal of the Korean Electrochemical Society
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    • v.11 no.1
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    • pp.59-63
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    • 2008
  • Poly (vinylchloride) (PVC) membrane electrodes based on neutral carrier, tetracycline was prepared as an active sensor for Hg(II) ion, and tested in different contents of the potassium tetrakis (4-chlorophenyl) borate (KTpClPB) as lipophilic salt. Bis (2-ethylhexyl) sebacate (DOS), bis(l-butylpentyl) adipate (BBPA), 2-nitrophenyl octyl ether (NPOE) and dibutyl phthalate (DBP) were used as diverse plasticizing solvent mediators. This electrode shows excellent potentiometric response characteristics and display good linearity with log $[Hg^{+2}]$ versus EMF response, over a range of concentrations between $10^{-7}$ and $10^{-3}M$. With 30.8mV/decade Nernstian slope, the detection limit was $6.9{\times}10^{-9}M$ and the response time was less than 20s. The proposed electrode yields very good selectivity for mercury (II) ion over many cations such as alkali, alkaline earth, transition and heavy metal ions. And it shows a very stable potential values in a wide pH range. This reliable electrode prepared was kept at least a month without considerable alteration in their response to Hg (II) ion.

Formation of porous 3C-SiC thin film by anodization with UV-LED (양극산화법과 UV-LED를 이용한 다공성 3C-SiC 박막 형성)

  • Kim, Kang-San;Chung, Gwiy-Sang
    • Journal of Sensor Science and Technology
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    • v.18 no.4
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    • pp.307-310
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    • 2009
  • This paper describes the formation of porous 3C-SiC by anodization. 3C-SiC thin films were deposited on p-type Si(100) substrates by APCVD using HMDS(Hexamethyildisilane: $Si_2(CH_3)_6$). UV-LED(380 nm) was used as a light source. The surface morphology was observed by SEM and the pore size was increased with increase of current density. Pore diameter of 70 $\sim$ 90 nm was achieved at 7.1 mA/cm$^2$ current density and 90 sec anodization time. FT-IR was conducted for chemical bonding of thin film and porous 3C-SiC. The Si-H bonding was observed in porous 3C-SiC around wavenumber 2100 cm$^{-1}$. PL shows the band gap enegry of thin film(2.5 eV) and porous 3C-SiC(2.7 eV).

1-D photonic crystals of free-standing DBR PSi for sensing and drug delivery applications (비고정화 된 일차원 광결정의 DBR 다공성 실리콘을 이용한 센서와 Drug Delivery로의 응용)

  • Koh, Young-Dae;Kim, Ji-Hoon;Park, Jong-Sun;Kim, Sung-Gi;Kim, Dong-Su;Cho, Sung-Dong;Sohn, Hong-Lae
    • Journal of Sensor Science and Technology
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    • v.15 no.6
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    • pp.391-396
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    • 2006
  • Free-standing multilayer distributed Bragg reflectors (DBR) porous silicon dielectric mirrors, prepared by electrochemical etching of crystalline silicon using square wave currents are treated with polystyrene to produce flexible, stable composite materials in which the porous silicon matrix is covered with caffeine-impregnated polystyrene. Optically encoded DBR PSi/polystyrene composite films retain the optical reflectivity. Optical characteristics of DBR PSi/polystyrene composite films are stable and robust for 2 hrs in a pH=7 aqueous buffer solution. The appearance of caffeine and change of DBR peak were simultaneously measured by UV-vis spectrometer and Ocean optics 2000 spectrometer, respectively.

Polymeric Membrane Silver-ion Selective Electrodes Based on Schiff Base N,N'-Bis(pyridin-2-ylmethylene)benzene-1,2-diamine

  • Seo, Hyung-Ran;Jeong, Eun-Seon;Ahmed, Mohammad Shamsuddin;Lee, Hyo-Kyoung;Jeon, Seung-Won
    • Bulletin of the Korean Chemical Society
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    • v.31 no.6
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    • pp.1699-1703
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    • 2010
  • The Schiff base N,N'-bis(pyridin-2-ylmethylene)benzene-1,2-diamine [BPBD] has been synthesized and explored as ionophore for preparing PVC-based membrane sensors selective to the silver ($Ag^+$) ion. Potentiometric investigations indicate high affinity of this receptor for silver ion. The best performance was shown by the membrane of composition (w/w) of ionophore: 1 mg, PVC: 33 mg, o-NPOE: 66 mg and additive were added 50 mol % relative to the ionophore in 1 mL THF. The sensor works well over a wide concentration range $1{\times}10^{-3}$ to $1.0{\times}10^{-7}$ M by pH 6 at room temperature (slope 58.6 mV/dec.) with a response time of 10 seconds and showed good selectivity to silver ion over a number of cations. It could be used successfully for the determination of silver ion content in environmental and waste water samples.

Lead-Selective Poly(vinyl chloride) Membrane Electrode Based on 1-Phenyl-2-(2-quinolyl)-1,2-dioxo-2-(4-bromo) phenylhydrazone

  • Zare, Hamid Reza;Ardakani, Mahammad Mazloum;Nasirizadeh, Navid;Safari, Javad
    • Bulletin of the Korean Chemical Society
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    • v.26 no.1
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    • pp.51-56
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    • 2005
  • A PVC membrane electrode for lead ion based on 1-phenyl-2-(2-quinolyl)-1,2-dioxo-2-(4-bromo) phenylhydrazone (PQDBP) as ionophore was demonstrated. The optimum composition of the membrane was 30 wt% poly(vinyl chloride), 60 wt% dibutyl phthalate as a plasticizer, 4 wt% ionophore and 6 wt% sodium tetraphenylborate as additive. The electrode exhibits a Nernstian response (28.7 mV decade$^{-1}$) for Pb$^{2+}$ over a wide concentration range (1.0 ${\times}$ 10$^{-1}$ to 1 ${\times}$ 10$^{-6}$ M) with a detection limit of 6.0 ${\times}$ 10$^{-7}$ M. This sensor has a short response time and can be used for at least 2 months without any divergence in potentials. The proposed electrode could be used in a pH range of 3.0-6.0 and revealed good selectivities for Pb$^{+2}$ over a wide variety of other metal ions. It was successfully applied as an indicator electrode for the potentiometric titration of lead ion with potassium chromate and for the direct determination of lead in mine.