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http://dx.doi.org/10.5012/bkcs.2004.25.5.629

UO22+ Ion-Selective Membrane Electrode Based on a Naphthol-Derivative Schiff's Base 2,2'-[1,2-Ethandiyl bis(nitriloethylidene)]bis(1-naphthalene)  

Shamsipur, Mojtaba (Department of Chemistry, Razi University)
Saeidi, Mahboubeh (Department of Chemistry, Razi University)
Yari, Abdullah (Department of Chemistry, Razi University)
Yaganeh-Faal, Ali (Department of Chemistry, Razi University)
Mashhadizadeh, Mohammad Hossein (Department of Chemistry, Shahid Bahonar University)
Azimi, Gholamhasan (Department of Chemistry, Arak University)
Naeimi, Hossein (Department of Chemistry, Kashan University)
Sharghi, Hashem (Department of Chemistry, Shiraz University)
Publication Information
Bulletin of the Korean Chemical Society / v.25, no.5, 2004 , pp. 629-633 More about this Journal
Abstract
A new PVC membrane electrode for $UO_2^{2+}$ ion based on 2,2'-[1,2-ethanediyl bis (nitriloethylidene)]bis(1-naphthalene) as a suitable ionophore was prepared. The electrode exhibites a Nernstian response for $UO_2^{2+}$ ion over a wide concentration range ($1.0{\times}10^{-1}-1.0{\times}10^{-7}$M) with a slope of 28.5 ${\pm}$ 0.8 mV/decade. The limit of detection is $7.0{\times}10^{-8}$M. The electrode has a response time of < 20 s and a useful working pH range of 3-4. The proposed membrane sensor shows good discriminating abilities towards $UO_2^{2+}$ ion with regard to several alkali, alkaline earth transition and heavy metal ions. It was successfully used to the recovery of uranyl ion from, tap water and, as an indicator electrode, in potentiometric titration of $UO_2^{2+}$ ion with Piroxycam.
Keywords
$UO_2^{2+}$ ion-selective electrode; PVC membrane; Schiff's base; Potentiometry;
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