• Title/Summary/Keyword: ozone water

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Atmospheric Pressure Plasma Treatment of Aqueous Bisphenol A Solution (비스페놀 A 수용액의 대기압 플라즈마 처리)

  • Jo, Jin-Oh;Choi, Kyeong Yun;Gim, Suji;Mok, Young Sun
    • Applied Chemistry for Engineering
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    • v.26 no.3
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    • pp.311-318
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    • 2015
  • This work investigated the plasma treatment of aqueous bisphenol A (BPA) solution and mineralization pathways. For the effective contact between plasmatic gas and aqueous BPA solution, the plasma was created inside a porous ceramic tube, which was uniformly dispersed into the aqueous solution through micro-pores of the ceramic tube. Effects of the gas flow rate, applied voltage and treatment time on the decomposition of BPA were examined, and analyses using ultraviolet (UV) spectroscopy, ion chromatography and gas chromatography-mass spectrometry were also performed to elucidate mineralization mechanisms. The appropriate gas flow rate was around $1.0L\;min^{-1}$; when the gas flow rate was too high or too low, the BPA decomposition performance at a given electric power decreased. The increase in the voltage improves the BPA decomposition due to the increased electric power, but the energy required to remove BPA was similar, regardless of the voltage. Under the condition of $1.0L\;min^{-1}$ and 20.8 kV, BPA at an initial concentration of $10L\;min^{-1}$ (volume : 1 L) was successfully treated within 30 min. The intermediates produced by the attack of ozone and hydroxyl radicals on BPA were further oxidized to stable compounds such as acetate, formate and oxalate.

Removal of Bromate by Iron, Copper and Silver Impregnated Activated Carbon (철, 구리, 은 첨착활성탄을 이용한 브롬산염의 제거)

  • Choi, Seong-Woo;Park, Seung-Cho
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.2
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    • pp.178-182
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    • 2006
  • The purpose of this research is to remove the bromate that is a disinfection by-poduct of water purification by ozone. I achieved a high rate of removal with iron, copper, or silver impregnated activated carbon by using both the adsorbing power of granular activated carbon and the oxidizing power of metal ions as deoxidizing agents. In the removal test of bromate with the quantity of activated carbon input I injected each activated carbon by 0.1, 0.3, 0.1, and 1.0 g and let them react for 240 minutes. I found the quantity of removed bromate was in proportion to the amount of input. The removal rate of bromate increased about 20% when I used acid treated activated carbon. The metal impregnated activated carbon had a higher removal rate of bromate than that of general activated carbon by about $30{\sim}50%$. Iron impregnated activated carbon showed a 92% removal rate of bromate. Iron, copper, or silver impregnated activated carbon removed about $0.9{\sim}1.5mg\;{BrO_3}^-/g$ while general activated carbon removed about $0.02{\sim}0.45mg\;{BrO_3}^-/g$. In the continuous column reaction, there were breakthrough phenomena at 96, 180, and 252 hours when I tested EBCT by 1, 2 and 3 minutes while I was changing the flux rate of bromate from 15.6 to 46.8 mL/min.

A Study on the Degradation Characteristics of 1,4-dioxane at Different Initial $H_2O_2$ Concentration with Advanced Oxidation Process using Ozone and Hydrogen Peroxide ($O_3/H_2O_2$를 이용한 고급산화공정에서 초기 $H_2O_2$ 농도에 따른 1,4-dioxane의 제거 특성 연구)

  • Park, Jin-Do;Suh, Jung-Ho;Lee, Hak-Sung
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.10
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    • pp.1108-1113
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    • 2005
  • Advanced oxidation process involving $O_3/H_2O_2$ was used to eliminate 1,4-dioxane and to enhance the biodegradability of dioxane-contaminated water. Oxidation process was carried out in a bubble column reactor under different pH and $H_2O_2$ concentrations. The removal efficiencies of 1,4-dioxane were investigated at hydrogen peroxide concentration between 40 and 120 mg/L. At the same pH, removal efficiencies of 1,4-dioxane increased with increasing initial $H_2O_2$ concentration. There was a linear relationship between initial concentration of $H_2O_2$ and the amount of consumed $O_3$. It was observed that the high $H_2O_2$ concentration accelerated the generation of hydroperoxy ions(${HO_2}^-$) and hydroxyl radicals($OH{\cdot}$). Hydrogen peroxide enhanced the decomposition of 1,4-dioxane and the biodegradability of the solution.

Effect of Freezing on the Physicochemical Properties of Semi-dried Red Pepper (냉동조건에 따른 반건조 홍고추의 물리.화학적 특성 변화)

  • Kim, Bo-Yeon;Lee, Kyoung-Hae
    • Food Science and Preservation
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    • v.16 no.3
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    • pp.362-370
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    • 2009
  • Quality changes in semi-dried red pepper (SRP) treated with ozone water were observed upon storage (at $-18^{\circ}C$) after freezing at $-10^{\circ}C$, $-20^{\circ}C$, and $-40^{\circ}C$. Drip loss after treatment was greater than in control peppers, but no significant difference was evident between treatments (p<0.05). We observed that differences between samples decreased as storage time increased. Texture after treatment did not change significantly over a 3-month period. The redness (a-value) after treatment was greater than in the control, but no sample showed significant color alteration after the 3-month period. The capsaicinoid content decreasedas storage time increased, and was also affected by the freezing temperature. However, carotenoid content was not influenced by freezing or storage temperature. Ascorbic acid and free sugar contents showed decreases of 47% and 6.5%, respectively, after semi-drying. The results of sensory evaluation indicated no significant difference between samples in terms of color appearance.

Study on the Growth Environment of 'Gangwha-mugwort' Through the Climatological Characteristic Analysis of Gangwha Region (강화지역의 기후특성 분석을 통한 '강화약쑥'의 생육 환경 연구)

  • Ahn, Joong-Bae;Hur, Ji-Na;Jung, Hae-Gon;Park, Jong-Ho
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.14 no.2
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    • pp.71-78
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    • 2012
  • Eupatilin, one of representative medical components of mugwort, can be efficiently extracted from the 'Gangwha Sajabalssuk'. The Eupatilin content may depend on environmental factors such as soil and regional climate in addition to a genetic factor and Gangwha region has a profitable environmental condition for the mugwort growth. In this study, the climatological characteristics of Gangwha was analyzed in order to find the environmental condition of mugwort containing high Eupatilin in term of atmospheric, oceanographic and land variables. The climate of Gangwha is characterized by the relatively low daily temperature and large diurnal variation with plenty of solar radiation, long sunshine duration and less cloudiness. According to our correlation analysis, the long sunshine duration and the large diurnal temperature variation are highly correlated with the Eupatilin contents. The result implies that Gangwha has the favorable conditions for the cultivation and the habitat of the high-Eupatilin concentrated mugwort. Because of the sea surrounding Gangwha Island with low salinity and moderate wind, the salt contained in sea breeze is relatively low compared to other regions. Furthermore, Gangwha has clean atmospheric environment compared to other regions because the concentrations of toxic gases harmful to crop growth such as nitrogen dioxide ($NO_2$), sulfite gas ($SO_2$) and fine dust (PM-10) are lower in the air. The ozone ($O_3$) concentration is moderate and within the level of natural production. It is also found that moderately coarse texture or fine loamy soils known as good for water drainage and for the growth and cultivation of the 'Gangwha-mugwort' are distributed throughout the areas around mountainous districts in Gangwha, coinciding with those of mugwort habitat.

Study on the Methane Emissions from Pails Storing Liquid Swine Manure (Pail내 돈슬러리의 메탄 발생량에 관한 연구)

  • Choi, D.Y.;Park, K.H.;Kwag, J.H.;Cho, S.B.;Yang, S.H.;Hwang, O.H.;Kang, H.S.;Yoo, Y.H.
    • Journal of Animal Environmental Science
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    • v.16 no.3
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    • pp.175-180
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    • 2010
  • Many greenhouse gases occur naturally, such as water vapor, carbon dioxide, methane, nitrous oxide, and ozone. Others such as hydrofluorocarbons (HFCs), perfluorocarbons (PFCs), and sulfur hexafluoride ($SF_6$) result exclusively from human industrial processes. Current global warming has been linked to anthropogenic greenhouse gas concentration increases. Methods to quantify greenhouse gas emissions during animal agriculture and the possibility to apply those to circumstance in the world were studied. Various chamber methods with trace gas analyzer (TGA) were used to quantify greenhouse gas emissions from stored manure. Methane fluxes from pails storing liquid swine manure were measured. Methane emissions increased a little with time and mean was 393.2 ${\mu}g\;m^{-2}\;s{-1}$ (standard error : 4 ${\mu}g\;m^{-2}\;s{-1}$).

Simulation of TOA Visible Radiance for the Ocean Target and its Possible use for Satellite Sensor Calibration (해양 표적을 이용한 대기 상단 가시영역에서의 복사휘도 모의와 위성 센서 검보정에의 활용 가능성 연구)

  • Kim, Jung-Gun;Sohn, Byung-Ju;Chung, Eui-Seok;Chun, Hyoung-Wook;Suh, Ae-Sook;Kim, Kum-Lan;Oh, Mi-Lim
    • Korean Journal of Remote Sensing
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    • v.24 no.6
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    • pp.535-549
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    • 2008
  • Vicarious calibration for the satellite sensor relies on simulated TOA (Top-of-Atmosphere) radiances over various targets. In this study, TOA visible radiance was calculated over ocean targets which are located in five different regions over the Indian and Pacific ocean, and its possible use for the satellite sensor calibration was examined. TOA radiances are simulated with the 6S radiative transfer model for the comparison with MODIS/Terra and SeaWiFS measurements. Geometric angles and sensor characteristics of the reference satellites were taken into account for the simulation. AOT (Aerosol Optical Thickness) from MODIS/Terra, pigment concentrations from Sea WiFS, and ozone amount from OMI measurements were used as inputs to the model. Other atmospheric input parameters such as surface wind and total column water vapor were taken from NCEP/NCAR reanalysis data. The 5-day averaged radiances over all targets show that the percent differences between simulated and observed radiances are within about ${\pm}5%$ in year 2005, indicating that the calculated radiances are in good agreement with satellite measurements. It has also been shown that the algorithm can produce the SeaWiFS radiances within about ${\pm}5%$ uncertainty range. It has been suggested that the algorithm can be used as a tool for calibrating the VIS bands within about 5% uncertainty range.

정지궤도 통신해양기상위성의 기상분야 요구사항에 관하여

  • Ahn, Myung-Hwan;Kim, Kum-Lan
    • Atmosphere
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    • v.12 no.4
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    • pp.20-42
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    • 2002
  • Based on the "Mid to Long Term Plan for Space Development", a project to launch COMeS (Communication, Oceanography, and Meteorological Satellite) into the geostationary orbit is undergoing. Accordingly, KMA (Korea Meteorological Administration) has defined the meteorological missions and prepared the user requirements to fulfill the missions. To make a realistic user requirements, we prepared a first draft based on the ideal meteorological products derivable from a geostationary platform and sent the RFI (request for information) to the sensor manufacturers. Based on the responses to the RFI and other considerations, we revised the user requirement to be a realistic plan for the 2008 launch of the satellite. This manuscript introduces the revised user requirements briefly. The major mission defined in the revised user requirement is the augmentation of the detection and prediction ability of the severe weather phenomena, especially around the Korean Peninsula. The required payload is an enhanced Imager, which includes the major observation channels of the current geostationary sounder. To derive the required meteorological products from the Imager, at least 12 channels are required with the optimum of 16 channels. The minimum 12 channels are 6 wavelength bands used for current geostationary satellite, and additional channels in two visible bands, a near infrared band, two water vapor bands and one ozone absorption band. From these enhanced channel observation, we are going to derive and utilize the information of water vapor, stability index, wind field, and analysis of special weather phenomena such as the yellow sand event in addition to the standard derived products from the current geostationary Imager data. For a better temporal coverage, the Imager is required to acquire the full disk data within 15 minutes and to have the rapid scan mode for the limited area coverage. The required thresholds of spatial resolutions are 1 km and 2 km for visible and infrared channels, respectively, while the target resolutions are 0.5 km and 1 km.

Effect of Physicochemical Treatment on Growth Inhibition of Hanseniaspora uvarum Y1 from Yogurt (물리·화학적 처리에 의한 요구르트 오염균의 생육 억제효과)

  • SunWoo, Chan;Lee, So-Young;Yoon, So-Young;Jung, Ji-Yeon;Kim, Koth-Bong-Woo-Ri;Lee, Chung-Jo;Kwak, Ji-Hee;Kim, Min-Ji;Kim, Dong-Hyun;Jung, Seul-A;Kim, Hyun-Jee;Ahn, Dong-Hyun
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.40 no.12
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    • pp.1781-1786
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    • 2011
  • This study was conducted to investigate the cause of microbiological contamination in yogurt and evaluate the effect of physicochemical treatment on the growth inhibition of Hanseniaspora uvarum isolated from yogurt. The yeast strain Hanseniaspora uvarum Y1 was subjected to heat and pH treatments. H. uvarum Y1 was killed at $70^{\circ}C$ and $80^{\circ}C$ after 15 min and survived in a wide pH range from pH 2 to 9. However, it did not survive under pH 1 and over pH 10. In a disk diffusion susceptibility test on H. uvarum Y1, a clear zone (5 mm) of growth inhibition was observed upon treatment with electrolyzed water. The effect of ozone gas on the growth of H. uvarum Y1 was evaluated by viable cell count. Initial cell numbers of $10^2$ and $10^3$ CFU/mL of H. uvarum Y1 were completely killed by treatment for 10 and 30 min, respectively. H. uvarum Y1 was also sterilized by microwave treatment for 1 min. When treated with gamma-irradiation, the rate of killing of H. uvarum Y1 was proportional to the irradiation dose. and complete killing occurred at a dose of 50 kGy.

Study on characteristics of specific hazardous substances in the industrial wastewater effluent (사업장 방류수 중 특정수질유해물질 배출 특성 연구)

  • Kim, Seungho;Choi, Youngseop;Kim, Yunhee;Kim, Jongmin;Chang, Gilsik;Bae, Seokjin;Cho, Younggwan
    • Analytical Science and Technology
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    • v.29 no.3
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    • pp.114-125
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    • 2016
  • In this study, 165 wastewater discharge facilities in 10 business types were investigated with regard to 24 specific hazardous substances that included heavy metals, VOCs, CN, and phenol in the Gwangju city. Cu in the range from from 0.008 to 35.420 mg/L was detected in all business types and the detection rate was 46.8 %. Other heavy metals, such as Cd, As, Hg, Pb, and Cr+6 were detected as well. However, their detection rates ranged between 0.6 and 1.8 %. CN and phenol were detected in one and five facilities, respectively. 12 species of VOCs were detected: chloroform 80.6 % (0.42 to 81.60 μg/L), benzene 16.4 % (1.49 to 3.31 μg/L), trichloroethylene 11.5 % (1.78 to 6.02 μg/L), 1,1-dichloroethylene 10.3 % (1.23 to 5.89 μg/L), and dichloromethane 8.5 % (0.28 to 968.86 μg/L) in the detection rate order. The concentration of VOCs was detected in trace amounts, except for dichloromethane that exceeded the effluent quality standard in three business types, namely, metal manufacturing, food industry, and car washing facility. Chloroform was detected in all business types, where 24.88 μg/L were detected in the laundry business and 53.41 μg/L in the water supply business; the mean concentration of chloroform in these two business types was higher than elsewhere. Therefore, for the disposal of non-degradable specific hazardous substances in industrial wastewater, it is necessary to introduce physical and chemical processes, such as activated carbon adsorption, fenton oxidation, ozone treatment, as well as photocatalyst and the UV radiation.