• 제목/요약/키워드: oxide removal

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Bioelectrochemical Denitrification Using Permeabilized Ochrobactrum anthropi SY509

  • Choi Kyung-Oh;Song Seung-Hoon;Kim Yang-Hee;Park Doo-Hyun;Yoo Young-Je
    • Journal of Microbiology and Biotechnology
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    • v.16 no.5
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    • pp.678-682
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    • 2006
  • To remove nitrate from wastewater, a novel bioelectrochemical denitrification system is introduced. In this proposed system, biological reactions are coupled with reactions on the electrode, whereby the electrons are transferred to the bacterial enzymes via a mediator as an electron carrier. The denitrification reaction was achieved with permeabilized Ochrobactrum anthropi SY509 containing denitrifying enzymes, such as nitrate reductase, nitrite reductase, and nitrous oxide reductase, and methyl viologen was used as the mediator. The electron transfer from the electrode to the enzymes in the bacterial cells was confirmed using cyclic voltammetry. A high removal efficiency of nitrate was achieved when the bioelectrochemical system was used with the permeabilized cells. Furthermore, when the permeabilized cells were immobilized to a graphite felt electrode using a calcium alginate matrix containing graphite powder, a high removal efficiency was achieved (4.38 nmol/min mg cell) that was comparable to the result when using the free permeabilized cells.

Effect of Pad Thickness on Removal Rate and Within Wafer Non-Uniformity in Oxide CMP (산화막 CMP에서 패드 두께가 연마율과 연마 불균일도에 미치는 영향)

  • Bae, Jae-Hyun;Lee, Hyun-Seop;Park, Jae-Hong;Nishizawa, Hideaki;Kinoshita, Masaharu;Jeong, Hae-Do
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.23 no.5
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    • pp.358-363
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    • 2010
  • The polishing pad is important element for polishing characteristic such as material removal rate(MRR) and within wafer non-uniformity(WIWNU) in the chemical mechanical planarization(CMP). The result of the viscoelasticity measurement shows that 1st elastic modulus is increased and 2nd elastic modulus is decreased when the top pad is thickened. The finite element analysis(FEA) was conducted to predict characteristic of polishing behavior according to the pad thickness. The result of polishing experiment was similar with the FEA, and it shows that the 1st elastic modulus affects instantaneous deformation of pad related to MRR. And the 2nd elastic modulus has an effect on WIWNU due to the viscoelasticity deformation of pad.

Removal of BP-3 Endocrine Disrupting Chemical (EDC) using cellulose acetate and ZnOnano particles mixed matrix membranes

  • Rajesha, B.J.;Chandan, H.R.;Sunil, K.;Padaki, Mahesh;Balakrishna, Geetha R.
    • Membrane and Water Treatment
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    • v.7 no.6
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    • pp.507-520
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    • 2016
  • The effect of ZnO on cellulose acetate in the removal of benzophenone-3 (BP-3) was investigated. The benzophenone-3 (BP-3) which is an endocrine disrupting chemical (EDC) was completely removed (100%) from the drinking water using Cellulose Acetate (CA) and zinc oxide (ZnO) composite membranes. The membranes were prepared by DIPS method and the filtration experiments were conducted by dead end filtration unit. The macrostructure of the membrane were studied by ATR-IR and XRD Spectra's. Atomic force microscopy (AFM) and Scanning electron microscopy (SEM) were used to study the micro properties of the membranes. The laboratory experiments such as water uptake study and pure water flux performed to confirm the increasing hydrophilicity. The enhancing hydrophilicity was confirmed with respect to higher the concentration of nanoparticles. Evaluation of BP-3 removal was carried in different experimental conditions, such as, different Trans membrane pressure and different concentration of feed. The membrane with low pressure showed better performance by rejecting 100% of BP-3. However, 1 ppm, 3 ppm and 6 ppm of feed solution was used and among them 3 ppm of feed solution gives 100% rejection. The ZnO nanoparticales enhances the performance of CA membrane by showing maximum rejection.

Effect of Oxidizer on the Polishing in Cadmium Telluride CMP (카드뮴 텔룰라이드 CMP 공정에서 산화제가 연마에 미치는 영향)

  • Shin, Byeong Cheol;Lee, Chang Suk;Jeong, Hae Do
    • Journal of the Korean Society for Precision Engineering
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    • v.32 no.1
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    • pp.69-74
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    • 2015
  • Cadmium telluride (CdTe) is being developed for thin film of the X-Ray detector recently. But a rough surface of the CdTe should be improved for resolution and signal speed. This paper shows the study on the improvement of surface roughness and removal rate by applying Chemical Mechanical Polishing. The conventional potassium hydroxide (KOH) based colloidal silica slurry could not realize a mirror surface without physical defects, resulting in low material removal rate and many scratches on surface. In order to enhance chemical reaction such as form oxidized layer on the surface of cadmium telluride, we used hydrogen peroxide ($H_2O_2$) as an oxidizer. Consequently, in case of 3 wt% concentration of hydrogen peroxide, the highest MRR (938 nm/min) and the lowest surface roughness ($R_{p-v}=10.69nm$, $R_a=0.8nm$) could be obtained. EDS was also used to confirm the generated oxide of cadmium telluride surface.

Selective Removal of Odorants in Natural Gas by Adsorption on Metal-containing Beta Zeolite Adsorbents (금속함유 베타 제올라이트 흡착제 상에서 LNG가스 내에 부취된 황화합물의 선택적 흡착제거)

  • Oh, Sang-Seung;Kim, Geon-Joong
    • Applied Chemistry for Engineering
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    • v.18 no.5
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    • pp.459-466
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    • 2007
  • In this study, H-type beta zeolites (BEA) having various metals were used as the adsorbent for the removal of sulfur containing odorants. The different adsorbents containing single or bimetals were utilized to investigate the performance in the individual adsorption of TBM and THT odorants or in the competitive adsorption between them by using a continuous adsorptive bed system. The result shows that the pure H-type BEA zeolite exhibited the highest adsorption capacity for TBM compound, but the higher amount of THT was removed and adsorbed on a HBEA adsorbent having Fe, Pd metal and ZnO oxide. In the case of bimetal containing adsorbents, Cu-Zn/HBEA and Fe-Mo/HBEA showed a higher adsorption capacity for TBM.

Behavior of Indoor Organic Pollutants Dissolved into the Ringer's Solution (수액제에 유입되는 실내 유기오염물질의 거동)

  • 김만구;정영림
    • Journal of Korean Society for Atmospheric Environment
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    • v.12 no.3
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    • pp.315-322
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    • 1996
  • Recently, hospital acquired infections have an increase interest as a public problems, which are caused of indoor pollutants in hospital. Microorganisms, ethylene oxide, formaldehyde, and anesthetic gases are main hazardous pollutants in hospital. The possible pathways of the infection are a respiratory channel as well as a blood channel. The blood channel is concerned since these pollutants might be dissolved into the Ringer's solution. The objective of this research was to evaluate the removal efficiencies of adsorption trap for formaldehyde and microorganisms as indoor pollutants which permeated into the Ringer's solution. Dissolved formaldehyde in the solution was increased with the injection dose time. The amount of dissolved formaldehyde was 67.5 $\pm$ 9.5% in Ringer's solution when injection dose time was controlled about 7hrs. An adsorption trap was designed for preventing formaldehyde and microorganisms to be permeated into Ringer's solution. The adsorption trap was packed with 0.4g of active carbon (60/80 mesh) in a sterilized plastic tube (7.79 cm length, 0.46 cm i.d.) and both ends were packed with glass wool. Devised infusion set equipped with the adsorption trap showed 99.9% of removal efficiency for formaldehyde. Microorganism numbers detected on sterilized water for injection and 5% dextrose infusion used in the hospital were 2,695 $\times 10^3$ cells/l and 4,190 $\times 10^3$ cells/l, respectively. Removal efficiency by the adsorption trap was 92.3 $\pm$ 8.5% as for microorgnisms.

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Preparation of ZnO Nanorod Grown on the PAN Surface and Its Sulfur Removal Characteristics (PAN 섬유 표면에서 성장하는 ZnO 나노로드의 제조 및 이를 이용한 황화합물 제거 특성)

  • LEE, JAEYOUNG;HAN, KYEONGSIK;JEONG, INSOO;LEE, HONGKI
    • Journal of Hydrogen and New Energy
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    • v.29 no.3
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    • pp.243-250
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    • 2018
  • Zinc oxide (ZnO) nanorods were grown on a palladium (Pd) activated polyacrylonitrile (PAN) fiber where Pd activation was carried out in advance by the following dry process: palladium(II) bis(acetylacetonate), $Pd(acac)_2$ was sublimed, penetrated into the surface of PAN fiber and spontaneously reduced to Pd nanoparticles at $180^{\circ}C$ for various times under a nitrogen atmosphere. ZnO nanorod morphology was observed by a scanning electron microscopy (SEM) and the elemental composition was confirmed by energy-dispersive X-ray spectroscopy (EDS). The crystalline structure of ZnO nanorods was analyzed by X-ray diffraction (XRD) analysis showing Wurtzite structure consisting of hexagonal lattice. Sulfur removal characteristics were evaluated.

Development of Tungsten CMP (Chemical Mechanical Planarization) Slurry using New Abrasive Particle (새로운 연마입자를 이용한 텅스텐 슬러리 개발)

  • Yu, Young-Sam;Kang, Young-Jae;Kim, In-Kwon;Hong, Yi-Koan;Park, Jin-Goo;Jung, Seok-Jo;Byun, Jung-Hwan;Kim, Moon-Sung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.571-572
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    • 2006
  • Tungsten CMP needs interconnect of semiconductor device ULSI chip and metal plug formation, CMP technology is essential indispensable method for local planarization. This Slurry development also for tungsten CMP is important, slurry of metal wiring material that is used present is depending real condition abroad. It is target that this research makes slurry of efficiency that overmatch slurry that is such than existing because focus and use colloidal silica by abrasive particle to internal production technology development. Compared selectivity of slurry that is developed with competitor slurry using 8" tungsten wafer and 8" oxide wafer in this experiment. And removal rate measures about density change of $H_2O_2$ and Fe particle. Also, corrosion potential and current density measure about Fe ion and Fe particle. As a result, selectivity find 83:1, and expressed similar removal rate and corrosion potential and current density value comparing with competitor slurry.

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Vasorelaxant effect of fluoxetine in isolated rat aorta (흰쥐 대동맥에서 fluoxetine의 혈관 이완 효과)

  • Kim, Shang-Jin;Kang, Hyung-sub;Kim, Jin-shang
    • Korean Journal of Veterinary Research
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    • v.44 no.4
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    • pp.515-522
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    • 2004
  • The vasorelaxant effect of serotonin reuptake inhibitor fluoxetine was investigated in rat isolated thoracic aorta. Fluoxetine induced a concentration-dependent relaxation in aorta precontracted with phenylephrine (PE) and KCl. These relaxations were suppressed by removal of the endothelium (-E) or pretreatment of nitric oxide synthase inhibitors, N(G)-nitro-L-arginine (L-NNA) and N(omega)-nitro-Larginine methyl ester (L-NAME), guanylate cyclase inhibitors, methylene blue (MB) and 1H-[1,2,4]oxadiazolo [4,3-a]quinoxalin-1-one (ODQ), and $Ca^{2+}$ channel blockers, nifedipine and verapamil, in PE-precontracted +E rings. However, fluoxetine-induced relaxations were not suppressed by pretreatment of $K^{+}$ channel blockers, tetrabutylammonium and glibenclamide, in PE-precontracted endothelium intact (+E) rings. The fluoxetine-induced relaxations were not suppressed by removal of the endothelium or pretreatment of LNNA and MB in KCl-precontracted +E rings. Also, fluoxetine inhibited PE-induced sustained contraction in +E rings. These inhibitory effects of fluoxetine on contractions could be reversed by removal of the endothelium or pretreatment of L-NNA, L-NAME, MB, ODQ, nifedipine and verapamil, but not by pretreatment of etrabutylammonium and glibenclamide. These findings suggest that the vasorelaxant effect of fluoxetine is modulated by intracellular $Ca^{2+}$ with an involvement of endothelial NO-cGMP pathway and also may be related to the inhibition of $Ca^{2+}$ entry through voltage-gated channel.

Adsorption Characteristics of Lithium Ions from Aqueous Solution using a Novel Adsorbent SAN-LMO Beads (수중의 리튬 이온 회수를 위한 새로운 흡착제인 SAN-LMO 비드의 제조)

  • Kam, Sang-Kyu;Park, Jeong-Min;Lee, Min-Gyu
    • Journal of Environmental Science International
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    • v.24 no.5
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    • pp.641-646
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    • 2015
  • In order to recover lithium ions from aqueous solution, a novel SAN-LMO beads were prepared by immobilizing lithium manganese oxide (LMO) with styrene acrylonitrile copolymers (SAN). The optimum condition for synthesis of SAN-LMO beads was 5 g of LMO and 3 g of SAN content. The characterization of the prepared SAN-LMO beads by SEM and XRD were confirmed that LMO was immobilized in SAN-LMO beads. The removal and the distribution coefficient of lithium ions decreased with increasing lithium ion concentration and solution pH. Even when the prepared SAN-LMO beads were reused 5 times, the leakage of LMO and the damage of SAN-LMO beads was not observed.