• Title/Summary/Keyword: oxide reduction

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Anti-Reflection Thin Film For Photoelectric Conversion Efficiency Enhanced of Dye-Sensitized Solar Cells (염료감응형 태양전지의 광전변환효율 향상을 위한 무반사 박막)

  • Jung, Haeng-Yun;Ki, Hyun-Chul;Hong, Kyung-Jin
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.12
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    • pp.814-818
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    • 2016
  • DSSCs (dye-sensitized solar cells) based on $TiO_2/SiO_2$ multi layer AR (anti-reflection) coating on the outer glass FTO (fluorine-doped tin oxide) substrate are investigated. We have coated an AR layer on the surface of a DSSCs device by using an IAD (ion beam-assisted deposition) system and investigated the effects of the AR layer by measuring photovoltaic performance. Compared to the pure FTO substrate, the multi layer AR coating increased the total transmittance from 67.4 to 72.9% at 530 nm of wavelength. The main enhancement of solar conversion efficiency is attributed to the reduction of light reflection at the FTO substrate surface. This leads to the increase of Jsc and the efficiency improvement of DSSCs.

Fabrication of Novel Metal Field Emitter Arrays(FEAs) Using Isotropic Silicon Etching and Oxidation

  • Oh, Chang-Woo;Lee, Chun-Gyoo;Park, Byung-Gook;Lee, Jong-Duk;Lee, Jong-Ho
    • Journal of Electrical Engineering and information Science
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    • v.2 no.6
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    • pp.212-216
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    • 1997
  • A new metal tip fabrication process for low voltage operation is reported in this paper. The key element of the fabrication process is that isotropic silicon etching and oxidation process used in silicon tip fabrication is utilized for gate hole size reduction and gate oxide layer. A metal FEA with 625 tips was fabricated in order to demonstrate the validity of the new process and submicron gate apertures were successfully obtained from originally 1.7$\mu\textrm{m}$ diameter mask. The emission current above noise level was observed at the gate bias of 50V. The required gate voltage to obtain the anode current of 0.1${\mu}\textrm{A}$/tip was 74V and the emission current was stable above 2${\mu}\textrm{A}$/tip without any disruption. The local field conversion factor and the emitting area were calculated as 7.981${\times}$10\ulcornercm\ulcorner and 3.2${\times}$10\ulcorner$\textrm{cm}^2$/tip, respectively.

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Fundamental Studies on NOx Emission Characteristics in a Dimethyl Ether/Air Nonpremixed Flame (DME/Air 비예혼합화염의 NOx 생성 특성에 관한 기초 연구)

  • Kim, Tae-Hyun;Kim, Jong-Hyun;Lee, Chang-Eon
    • Proceedings of the KSME Conference
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    • 2008.11b
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    • pp.1973-1978
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    • 2008
  • The NOx emission characteristics of DME in counterflow nonpremixed flames were investigated numerically, and brief experiments were carried out to compare the flame shapes and NOx emissions with those of $C_3H_8$ and $C_2H_6$. The DME flames were calculated using Kaiser's mechanism, while the $C_2H_6$ flames were calculated using the $C_3$ mechanism. These mechanisms were combined with the modified Miller-Bowman mechanism for the analysis of NOx. Experimental results show that DME flame has the characteristics of partial premixed flame and the flame length becomes very shorter compared with general hydrocarbon fuels and then, the NOx emission of DME is low as much as 60% of $C_3H_8$. In the calculated results of counterflow nonpremixed flames, the EINO of DME nonpremixed flame is low as much as 50% of the $C_2H_6$ nonpremixed flame. The cause of $EI_{NO}$ reduction is attributed mainly to the characteristics of partial premixed flame due to the existence of O atom in DME and partly to the O-C bond in DME, instead of C-C bond in hydrocarbon fuels.

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Effect of $18{\beta}$-Glycyrrhetinic Acid on Septic Arthritis Caused by Candida albicans ($18{\beta}$-Glycyrrhetinic Acid의 항 감염성관절염효과)

  • Han, Yong-Moon
    • YAKHAK HOEJI
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    • v.51 no.6
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    • pp.476-481
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    • 2007
  • A polymorphic fungus, Candida albicans, causes various forms of infections such as disseminated candidiasis and vaginitis. Recent reports indicate that the fungus is a main etiological agent for the arthritis. In search of new sources for treatment of the fungal arthritis, we examined $18{\beta}$-glycyrrhetinic acid ($18{\beta}$-GA) against C. albicans-caused septic arthritis. The compound is isolated from Glycyrrhizae Radix that is known to have various immunomodulating activities and is one of the most popular herbal medicines. For induction of animal model of a septic arthritis, mice were given an emulsion form of C. albicans cell wall mixed with Complete Freund's Adjuvant (CFA) via footpad-injection. To determine prophylactic and therapeutic effects, the component was given to the animals before or after the induction of the arthritis, respectively. Data showed that intraperitoneal administration of $18{\beta}$-GA resulted in reduction of the inflammation, indicating the component had both prophylactic and therapeutic activities. For investigation of mechanism of the $18{\beta}$-GA, inhibitory effects on NO (nitiric oxide) and on T-lymphocyte proliferation were determined. Results demonstrated that $18{\beta}$-GA suppressed NO production from LPS (lipopolysaccharide)-treated macrophages and also inhibited proliferation of Con A (concanavalin A)activated T-cells. Taken together, $18{\beta}$-GA, a pentacyclic triterpene, has anti-arthritic activity against C. albicans-caused septic arthritis, possibly by blocking NO production and T-cell suppression.

Corrosion and Passivation of Nickel Rotating Disk Electrode in Borate Buffer Solution (Borate 완충용액에서 니켈 회전원판전극의 부식과 부동화)

  • Kim, Younkyoo
    • Journal of the Korean Chemical Society
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    • v.57 no.5
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    • pp.533-539
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    • 2013
  • The electrochemical corrosion and passivation of Ni rotating disk electrod in borate buffer solution was studied with potentiodynamic and electrochemical impedance spectroscopy. The mechanisms of both the active dissolution and passivation of nickel and the hydrogen evolution in reduction reaction were hypothetically established while utilizing the Tafel slope, impedance data, the rotation speed of Ni-RDE and the pH dependence of corrosion potential and current. Based on the EIS data, an equivalent circuit was suggested. In addition, carefully measured were the electrochemical parameters for specific anodic dissolution regions. It can be concluded from the data collected that the $Ni(OH)_2$ oxide film, which is primarily formed by passivation, is converted to NiO by dehydration under the influence of an electrical field.

Synthesis and Mechanism of Ni-Doped Hibonite Blue Pigments (Ni-Doped Hibonite 파란색 안료의 합성과 발색기구)

  • Kim, Gumsun;Lee, Byung-Ha
    • Korean Journal of Materials Research
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    • v.24 no.1
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    • pp.43-47
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    • 2014
  • NiO-doped hibonite pigments were synthesized by the solid state method to get stabilized blue color pigment in both oxidation and reduction atmospheres. Optimum substitution condition with NiO for hibonite blue pigment was investigated. Experimental results were comparable to those of previous cobalt-minimization studies performed with other phosphate- or oxide-based cobalt-containing ceramic pigments (having olivine ($Co_2SiO_4$), spinel ($CoAl_2O_4$), or with co-doped willemite ($(Co,Zn)_2SiO_4$) structures). Composition was designed varying the NiO molar ratio increasing with $SnO_2$. The optimum substitution content is 0.93 mole NiO with 0.75mole $SnO_2$. The characteristics of the synthesized pigment were analyzed by XRD, Raman spectroscopy, SEM, and UV-vis. Synthesized pigment was applied to a lime-barium glaze with 10 wt% each and fired at an oxidation atmosphere of $1250^{\circ}C/1h$ and a reducing atmosphere $1240^{\circ}C/1h$. Blue color was obtained with $L^*a^*b^*$ values at 43.39, -6.78, -18.20 under a reducing atmosphere and 41.66, -6.36, -14.7 under and oxidation atmosphere, respectively.

Identification of 1-Furan-2-yl-3-pyridin-2-yl-propenone, an Anti-inflammatory Agent, and Its Metabolites in Rat Liver Subcellular Fractions

  • Lee, Sang-Kyu;Jeon, Tae-Won;Basnet, Arjun;Jeong, Hye-Gwang;Lee, Eung-Seok;Jeong, Tae-Cheon
    • Archives of Pharmacal Research
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    • v.29 no.11
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    • pp.984-989
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    • 2006
  • 1-Furan-2-yl-3-pyridin-2-yl-propenone (FPP-3) has been characterized to have an anti-inflammatory activity through the inhibition of the production of nitric oxide and tumor necrosis $factor-{\alpha}$. In the present studies, the phase 1 metabolism of FPP-3 was investigated in rat liver microsomes and cytosols. When FPP-3 was incubated with rat liver microsomes and cytosols in the presence of NADPH. 2 major peaks were detected on a liquid chromatography/electrospray ionization-mass spectrometry. Two metabolites (i.e., M1 and M2) were characterized as reduced forms on propenone: M1 (1-furan-2-yl-3-pyridin-2-yl-propan-1-one) was the initial metabolite and M2 (1-furan-2-yl-3-pyridin-2-yl-propan-1-ol) was a secondary alcohol believed to be formed from M1.

IDDQ Test Pattern Generation in CMOS Circuits (CMOS 조합회로의 IDDQ 테스트패턴 생성)

  • 김강철;송근호;한석붕
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.3 no.1
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    • pp.235-244
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    • 1999
  • This Paper proposes a new compaction algorithm for IDDQ testing in CMOS Circuits. A primary test pattern is generated by the primitive fault pattern which is able to detect GOS(gate-oxide short) and the bridging faults in an internal primitive gate. The new algorithm can reduce the number of the test vectors by decreasing the don't care(X) in the primary test pattern. The controllability of random number is used on processing of the backtrace together four ones of heuristics. The simulation results for the ISCAS-85 benchmark circuits show that the test vector reduction is more than 45% for the large circuits on the average compared to static compaction algorithms.

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The Fabrication of Micro-Heaters with Low-Power Consumption Using SOI and Trench Structures

  • Chung, Gwiy-Sang;Hong, Seok-Woo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.05a
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    • pp.197-201
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    • 2002
  • This paper presents optimized design, fabrication and thermal characteristics of micro-heaters for thermal MEMS (micro electro mechanical system) applications using SOI and trench structures. The micro-heaters are based on a thermal measurement principle and contains thermal isolation regions of 10 ${\mu}m$-thick Si membranes consisting of oxide-filled trenches in the SOI membrane rim. The micro-heaters were fabricated with Pt-RTD on the same substrate via MgO buff layer between Pt thin-film and $SiO_2$ layer. The thermal characteristics of micro-heater with trench-free SOI membrane structure was $280^{\circ}C$ at input power 0.9 W; in the presence of 10 trenches, it was $580^{\circ}C$ due to reduction of the external thermal loss. Therefore, a micro-heater with trenches in SOI membrane rim structure provides a powerful and versatile alternative technology for enhancing the performance of micro-thermal sensors and actuators.

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Synthesis and Characterization of CNTs/Metal/Al2O3 Nanocomposite Powders by Thermal CVD (열 CVD법에 의한 CNTs/Metal/Al2O3 나노복합분말의 합성 및 특성)

  • Choa Yong-Ho;Yoo Seung-Hwa;Yang Jae-Kyo;Oh Sung-Tag;Kang Sung-Goon
    • Journal of Powder Materials
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    • v.12 no.2 s.49
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    • pp.146-150
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    • 2005
  • An optimum route to synthesize $Al_2O_3$-based composite powders with homogeneous dispersion of carbon nanotubes (CNTs) was investigated. CNTs/Metal/$Al_2O_3$ nanocomposite powders were fabricated by thermal chemical vapor deposition of $C_2H_2$ gas over metal/$Al_2O_3$ nanocomposite catalyst prepared by selective reduction of metal oxide/$Al_2O_3$ powders. The FT-Raman spectroscopy analysis revealed that the CNTs have single- and multi-walled structure. The CNTs with the diameter of 25-43 nm were homogeneously distributed in the metal/$Al_2O_3$ powders, and their characteristics were strongly affected by a kind of metal catalyst and catalyst size. The experimental results show that the composite powder with required size and dispersion of CNTs can be realized by control of synthesis condition.