• 폴리머
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• 제24권1호
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• pp.124-127
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• 2000

Poly(isobutylene oxide)의 물리적 성질을 개선하기 위하여 isobutylene oxide와 cyclohexene oxide의 공중합체가 triisobutylaluminum을 촉매로 하여 합성되었다. 분자량은 diethylzinc를 촉매로 하여 만든 poly(isobutylene oxide)보다 낮았다. 유리전이온도는 두 개의 단일중합체 사이에 일정하게 분포되었다. Vinyl cyclohexene oxide와의 공중합체는 현저한 열안정성을 보여주었다. 폴리올이나 윤활제로 응용 가능한 올리고머가 제조되었다. 산촉매하에서는 복잡한 생성물 분포를 보여 주었으나 염기 촉매하에서는 오량체 및 육량체가 주인 생성물 분포를 보여주었다.

• Journal of Electrochemical Science and Technology
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• 제9권2호
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• pp.93-98
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• 2018

$MnO_2$, a metal oxide used as an electrode material in electrochemical capacitors (EDLCs), has been applied in binary oxide and conducting polymer hybrid electrodes to increase their stability and capacitance. We developed a method for electrodepositing Mn-Ni oxide/PANI, Mn-Ni oxide/PEDOT, and Mn-Ni-Ru oxide/PEDOT films on carbon paper in a single step using a mixed bath. Mn-Ni oxide/PEDOT and Mn-Ni-Ru oxide/PEDOT electrodes used in an electro-osmotic pump (EOP) have shown better efficiency compared to Mn-Ni oxide and Mn-Ni oxide/PANI electrodes through testing in water as a pumping solution. EOP using a Mn-Ni-Ru oxide/PEDOT electrode was also tested in a 0.5 mM $Li_2SO_4$ solution as a pumping solution to confirm the effect of the $Li^+$ insertion/de-insertion reaction of Ruthenium oxide on the EOP. Experimental results show that the flow rate increases with the increase in current in a 0.5 mM $Li_2SO_4$ solution compared to that obtained when water was used as a pumping solution.

• Elastomers and Composites
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• 제39권2호
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• pp.153-160
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• 2004

풀러렌($C_{70}$)을 3-picoline N-oxide, pyridine N-oxide hydrate, quinoline N-oxide, isoquinolne N-oxide의 여러가지 아민 N-옥시드를 사용하여 $25{\sim}43^{\circ}C$, 초음파 조건에서 반응시켜 풀러렌 산화물을 합성 하였다. 동일한 초음파 조건에서 여러가지 아민 N-옥시드에 대한 풀러렌 ($C_{70}$)의 반응성은 3-picoline N-oxide : pyridine N-oxide hydrate : quinoline N-oxide : isoquinoline N-oxide 처럼 동일하게 나타났다. MALDI -TOF MS, UV-vis 그리고 HPLC를 사용하여 생성된 풀러렌 산화물을 분석한 결과 [$C_{70}(O)n$] (n=1) 임을 알 수 있었다.

• 한국소음진동공학회:학술대회논문집
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• 한국소음진동공학회 2014년도 춘계학술대회 논문집
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• pp.81-82
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• 2014

Recently it is often reported about toxic nanomaterials to organisms. In other words, it is called nanotoxicity, toxic nanomaterials have extremely toxic properties. Zinc oxide is widely used as a promising nanomaterials, but some researchers are warning that nanotype zinc oxide has nanotoxicity. One of typical zinc oxide materials is a zinc oxide nanowire, especially, there is no technique which is detecting a zinc oxide nanowire because of its geometric. In here, we use reduced graphene oxide in order to detect zinc oxide nanowire and use DNA immobilized cantilever sensor, we detect graphene wrapped zinc oxide nanowire. Detection of a zinc oxide nanowire is measured by shifting of cantilever's resonance frequency based on vibration theory. It is proved that cantilever sensor is valid for nanomaterial detection. We showed that detection of a zinc oxide nanowire is successful.

• Applied Biological Chemistry
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• 제34권4호
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• pp.386-392
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• 1991

Propene으로부터 propylene oxide를 생산하기 위하여, methane 자화성 세균인 Methylosinus trichosporium OB3b를 이용하였다. 이 균주는 methane을 methanol로 전환시키는 methane monooxygenase를 가지고 있는데, 이 효소는 또한 propene을 propylene oxide로 전환시킬 수 있다. 이 균주의 휴지세포를 이용하여 propene으로부터 propylene oxide 생산의 최적조건을 검토하였다. 최적 pH는 7.0이었으며, 최적온도는 $35^{\circ}C$이었다. 최종산물인 propylene oxide는 propylene oxide의 생산반응을 저해하지 않았으며, 더 이상 대사되지도 않았다. Methane 대사중간물질들(methanol, formaldehyde, formic acid)의 첨가는 propylene oxide의 생산을 $3{\sim}4$배 증가시켰으며, 특히 methanol 첨가의 경우에 가장 좋은 효과를 보였다. 상기의 최적조건하에서, 1시간 반응시 propylene oxide의 최대 생산량은 14.2 mM이었으며, 이 때 공급한 propene으로부터 propylene oxide로의 전환율은 약 8.0%이었다.

• 한국세라믹학회지
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• 제11권1호
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• pp.3-9
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• 1974

The role of added metal oxide in the adherence mechanism of low melting glass to several metal plates such as oxygen free high conducting copper, low carbon steel, chrominum galvanized on copper, and stainless steel was investigated. The metal oxide which added to glass were cupric oxide, ferric oxide, chromic oxide, and stainless steel oxide. The glass to that various metla oxide were added, sealed with several metal plates in the electric furnace at $650^{\circ}C$ for 5 minutes. The results as follows; 1) The interfacial reaction was promoted and strong chemical bonding with glass and metals by which the surface energy was decreased showed excellent sealing by addition of metal oxide. 2) When the interfacial reaction of glass and metals was promoted by addition of metal oxide found out that various adhernece mechanism were related to the sealing. 3) When the amount of metal oxide addition was 3-5% the excellent sealing was achieved.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1996년도 추계학술대회 논문집
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• pp.13-17
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• 1996

Superthin ONO ( oxide -nitride - oxide ) structures were fabricated for the MONOS nonvolatile memory device with a 20$\AA$ tunneling oxide, 40$\AA$ nitride and 40$\AA$ blocking oxide. The compositions of each layer in a superthin ONO structure were investigated. Also, the characteristics of trap related to the memory quality were examined.

• 대한전자공학회논문지SD
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• 제41권9호
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• pp.31-37
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• 2004

oxide 층의 위치와 두께 조절을 통하여 oxide-VCSEL이 단일모드로 동작하는 활성영역의 반경을 확장하는 방법을 Self-consistent effective-index 방법을 이용하여 제시하였다. 이렇게 활성영역이 넓어지면 고속, 고신뢰도, 고출력 동작에 유리한 단일모드 VCSEL을 만들 수 있게 된다. 고출력을 위하여 단일모드로 동작하는 활성영역을 확대하는 방법을 하면 다음과 같다. 첫째 oxide 층은 활성층에서 멀리 떨어진 곳에 위치시켜야 한다 둘째, oxide 층은 얇게 만들어야 한다. 셋째, oxide층을 node에 위치시켜야 한다. 그리고 고출력을 위하여 p-DBR 쌍의 수를 줄이는 것은 단일모드 동작조건을 변화시키지 않는다. 이 방법을 사용하면 단일모드로 동작하는 oxide-aperture 크기를 3m% 이상 키울 수 있다.

• 한국재료학회지
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• 제24권7호
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• pp.363-369
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• 2014

This is the study on diffusion of ceramic body oxide compounds to glaze. For ceramic bodies, no ferrous oxides contain white ware, celadon, and 3 wt% iron oxides contained white ware was used in this experiment. These ceramic bodies were glazed by transparency glaze, iron oxides contained glaze, and glaze made by pine tree ash that treated in 1240 degree, under reduction condition for an hour. An electron probe microanalyzer(EPMA) was used to study diffusion of oxides and to calculate distance of ceramics bodies. As a result, only iron oxide and magnesium oxide from the body diffused to glaze, and also made a band which shown very thin layer of iron oxide and magnesium oxide between the body and glaze. The densest band of iron oxide formed 100 to $150{\mu}m$ in the glaze, and the densest band of magnesium oxide was found 50 to $100{\mu}m$ in the glaze. Therefore, it could be concluded that iron oxide in the body is diffused to the glaze and it affects the color of glaze, even though iron oxide exists in the glaze. Furthermore, the thickness of the glaze has an effect on the color of celadon.

• Nuclear Engineering and Technology
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• 제56권8호
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• pp.3307-3314
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• 2024

For traditional spent fuel shielding materials, due to physical and chemical defects and cost constraints, they have been unable to meet the needs. Therefore, this paper carries out the first discussion on the application and performance of bismuth in neutron shielding by establishing Monte Carlo simulation on the neutron flux model of shielded spent fuel. Firstly, functional fillers such as bismuth oxide, lead oxide, boron oxide, gadolinium oxide and tungsten oxide are added to the matrices to compare the shielding rates of aluminum alloy matrix and silicone rubber matrix. The shielding rate of silicone rubber mixture is higher than aluminum alloy mixture, reaching more than 56%. The optimal addition proportion of bismuth oxide and lead oxide is 30%, and the neutron radiation protection efficiency reaches 60%. Then, the mass attenuation coefficients of bismuth oxide, lead oxide, boron oxide, gadolinium oxide and tungsten oxide in silicone rubber matrix are simulated with the change of functional fillers proportion and neutron energy. This simulation result shows that the mixture with functional fillers has good shielding performance for low energy neutrons, but poor shielding effect for high energy neutrons. Finally, in order to further evaluate the possibility of replacing lead oxide with bismuth oxide as shielding material, the half-value layers and various properties of bismuth oxide and lead oxide are compared. The results show that the shielding properties of bismuth oxide and lead oxide are basically the same, and the mechanical properties, heat resistance, radiation resistance and environmental protection of bismuth oxide are better than that of lead oxide. Therefore, in the case of neutron source strengths in the range of 0.01-6 MeV and secondary gamma rays produced below 2.5 MeV, bismuth can replace lead in neutron shielding applications.