• Title/Summary/Keyword: overall conversion

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𝛽-Patchoulene: Conversion from Patchouli Alcohol by Acid Catalysts and its In silico Anti-inflammatory Study

  • Firdaus, Firdaus;Soekamto, Nunuk Hariani;Firdausiah, Syadza;Rasyid, Herlina;Rifai, Akhmad
    • Natural Product Sciences
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    • v.27 no.3
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    • pp.208-215
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    • 2021
  • 𝛽-Patchoulene (𝛽-PAE) is a tricyclic sesquiterpene which performed many potential bioactivities and can be found in patchouli oil but in very low concentration. This study aimed to obtained 𝛽-PAE in high concentration by conversion of patchouli alcohol (PA) in patchouli oil under acid catalyzed reaction. Patchouli oil was fractinated by vacuum distillation at 96 kPa to get the fraction with the highest PA content. H2SO4 and ZnCl2 were used respectively as homogeneous and heterogeneous acid catalysts in the conversion reaction of the selected fraction. Patchouli oil, the fractions and the products were analysed by using GC-MS and FTIR instruments. Moreover, the interaction of 𝛽-PAE to COX-2 protein was studied to understand the antiinflammation activity of 𝛽-PAE. The results showed that patchouli oil contains 25.3% of PA. The selected fraction which has the highest PA content (70.3%) was distilled at 151 - 152 ℃. The application of ZnCl2 catalyst in conversion reaction did not succeed. In contrast, H2SO4 as a catalyst in acetic acid solvent succeeded in converting the overall fraction of PA to 𝛽-PAE. Furthermore, the molecular docking study of 𝛽-PAE against COX-2 enzyme showed van der Waals and alkyl-alkyl stacking interactions on ten amino acid residues.

Design of W-band Cascode Mixer with High Conversion Gain using 0.1-μm GaAs pHEMT Process (0.1-μm GaAs pHEMT 공정을 이용한 높은 변환이득을 가지는 W-대역 캐스코드 혼합기 설계)

  • Choe, Wonseok;Kim, HyeongJin;Kim, Wansik;Kim, Jongpil;Jeong, Jinho
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.18 no.6
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    • pp.127-132
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    • 2018
  • In this paper, a high conversion gain cascode mixer was designed in W-band and verified by the fabrication and measurements. In the high frequency band such as a W-band, the conversion loss of a mixer is increased because of the poor performance of transistors. This high conversion loss of the mixer requires additional circuits which can give an extra gain such as an RF buffer amplifier, and this can affects the linearity and stability of the overall systems. Therefore, it is necessary to maximize the conversion gain of the mixer. To maximize the conversion gain of the mixer, biases of the transistor were optimized, and output load impedance was optimized by the load-pull simulations. The designed mixer was fabricated in $0.1-{\mu}m$ GaAs pHEMT technology and verified by the measurements. The measurement results shows a maximum conversion gain of -4.7 dB at W-band and an input 1-dB compression point of 2.5 dBm.

The Conversion of Mixed Fat of Beef Tallow and Jatropha Oil into Biodiesel Using Acid / Alkali Catalysts (산/알칼리 촉매를 사용한 우지와 자트로파유 혼합지방의 바이오디젤화)

  • Hyun, Young-Jin
    • Journal of the Korean Applied Science and Technology
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    • v.26 no.2
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    • pp.179-185
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    • 2009
  • The esterification of the reactants of Jatropha oil and methanol added by propyleneglycol was done using p-TSA catalyst. And then the emulsification of triglyceride and methanol was conduced by 1.0vol% GMS. The emulsified reactants were transesterified at $65^{\circ}C$ using TMAH and mixed catalyst (50wt%-TMAH+50wt%-NaOH) respectively. The esterification conversion at the 1:8 molar ratio of free fatty acid to methanol using 8.0wt% p-TSA was 94.7% within 80min. The overall conversion at the 1:8 molar ratio of mixed fat(50wt% Beef Tallow) to methanol and $65^{\circ}C$ using mixed catalyst was 95.4% The cloud point of Biodiesel decreased with the addition of petroleum diesel.

The Conversion of Jatropha Oil into Biodiesel Using Acid / Alkali Catalysts (산 / 알칼리 촉매를 사용한 자트로파유의 바이오디젤화)

  • Hyun, Young-Jin;Kim, Hae-Sung
    • Journal of the Korean Applied Science and Technology
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    • v.25 no.3
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    • pp.275-281
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    • 2008
  • The esterification of free fatty acid in Jatropha oil added by propylene glycol using p-TSA catalyst was done, and then the transesterification of Jatropha oil added by 1.0vol% GMS as an emulsifier using TMAH, and mixed catalyst(60wt%-TMAH+ 40wt%-KOH) respectively was followed at $60^{\circ}C$. The esterification conversion at the 1:8 molar ratio of free fatty acid to methanol using 8.0wt% p-TSA was 94.7% within 60min. The overall conversion at the 1:8 molar ratio of Jatropha oil to methanol and $60^{\circ}C$ using mixed catalyst was 95.4%. The kinematic viscosity of Biodiesel using TMAH and mixed catalyst in 24h met the ASTM D-6751 above $30^{\circ}C$, and showed a little more than its criterion.

Present State of Self-Rectifying Air Turbines for Wave Energy Conversion

  • Setoguchi, Toshiaki;Takao, Manabu
    • 유체기계공업학회:학술대회논문집
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    • 2003.12a
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    • pp.3-12
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    • 2003
  • This paper reviews the present state of the art on the self-rectifying air turbines, which could be used for wave energy conversion. The overall performances of the turbines under irregular wave conditions, which typically occur in the sea, have been evaluated numerically and compared from the viewpoints of the starting and running characteristics. The types of turbine included in the paper are as follows: (a) Wells turbine with guide vanes (WTGV); (b) turbine with self-pitch-controlled blades (TSCB); (c) biplane Wells turbine with guide vanes (BWGV); (d) impulse turbine with self-pitch-controlled guide vanes (ISGV) and (e) impulse turbine with fixed guide vanes (IFGV). As a result, under irregular wave conditions it is found that the running and starting characteristics of the impulse type turbines could be superior to those of the Wells turbine. Moreover, the authors have explained the mechanism of hysteretic behavior of the Wells turbine and the necessity of links for improvement of the performance of ISGV.

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Design of a Rceiver MMIC for the CDMA Terminal (CDMA 단말기용 수신단 MMIC 설계)

  • 권태운;최재하
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.12 no.1
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    • pp.65-70
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    • 2001
  • This paper presents a Receiver MMIC for the CDMA terminal. The complete circuit is composed of Low Noise Amplifier, Down Conversion Mixer, Intermediate Frequency Amplifier and Bias circuit. The Bias circuit implementation, which allows for compensation for threshold voltage and power supply voltage variation are provided. The proposed topology has high linearity and low noise characteristics. Results of the designed circuit are as follows: Overall conversion gain is 28.5 dB, input IP3 of LNA is 8 dBm, input IP3 of down conversion mixer is 0 dBm and total DC current consumption is 22.1 mA.

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Evaluation of the Effect of Sipjeondaebo-Tang By-Product Powder on Broiler Production (십전대보탕부산물을 활용한 육계생산성 향상 평가)

  • Yeon-Woo Jeong
    • Journal of Environmental Science International
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    • v.31 no.12
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    • pp.1135-1138
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    • 2022
  • This study was conducted to evaluate the effects of sipjeondaebo-tang by-product powder on the growth performance of broilers. A total of 120 broiler chicks (Arbor acres) at 0 days old were assigned to one of two treatments with three replications: control and 1% sipjeondaebo-tang by-product powder. Weight gain at 3 weeks and feed intake at 5 weeks were significantly (p<0.05) influenced by the sipjeondaebo-tang by-product powder treatments. However, there were no significant differences in the feed conversion ratio between treatments as a function of treatment time (p>0.05). Overall, weight gain and the feed conversion ratio were slightly greater for the sipjeondaebo-tang by-product powder treatment than the control treatment. It was concluded that sipjeondaebo-tang by-product powder may be an appropriate source of feed additive, without any negative effects on the growth performance of the broilers.

Production of Biodiesel from High Acid Value Oils using Amberlyst-15 (Amberlyst-15를 이용한 산가가 높은 유지로부터 바이오디젤의 생산)

  • Sim, Yeon-Ju;Kim, Eui-Yong
    • KSBB Journal
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    • v.25 no.5
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    • pp.483-489
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    • 2010
  • Biodiesel has attracted great attention as an alternative renewable energy source for the replacement of petroleumbased diesel fuel, yet its high production cost due to expensive oil feedstock remainsas the major economical obstacle. In this study, we investigated catalysts and reaction conditions for the acid catalyzed pre-conversion of free fatty acid (FFA) to fatty acid methyl ester (FAME) in cheap low-grade oils of high acid value. The NaOH base catalyzed reaction of vegetable oil of the initial acid value of 2 mg KOH/g led to a high FAME conversion above 95.4%, but the conversion abruptly decreased at higher initial acid values. This base catalyzed reaction was practically ineffective displaying the FAME conversion below 15% even at the initial acid value of 10 mg KOH/g by the severe saponification side reaction. Among the various catalysts studied for the pre-conversion of FFA to FAME, Amberlyst-15 was the most effective in reducing the acid value, and the optimum reaction condition identified was $65^{\circ}C$ with oil to methanol ratio of 1:3 and catalyst concentration of 15% (w/w). As the results, great enhancements in the overall biodiesel conversion were achievable via a consecutive reaction of the acid catalyzed FFA pre-conversion to FAME under the optimal condition obtained with Amberlyst-15 followed by the NaOH base catalyzed reaction, far above the extent which was obtainable by the single NaOH catalyzed reaction.

Analysis of Land Cover Change from Paddy to Upland for the Reservoir Irrigation Districts (토지피복지도를 이용한 저수지 수혜구역 농경지 면적 및 변화 추이 분석)

  • Kwon, Chaelyn;Park, Jinseok;Jang, Seongju;Shin, Hyungjin;Song, Inhong
    • Journal of The Korean Society of Agricultural Engineers
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    • v.63 no.6
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    • pp.27-37
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    • 2021
  • Conversion of rice paddy field to upland has been accelerated as the central government incentivizes more profitable upland crop cultivation. The objective of this study was to investigate the current status and conversion trend from paddy to upland for the reservoir irrigation districts. Total 605 of reservoir irrigation districts whose beneficiary area is greater than 200 ha were selected for paddy-to-upland conversion analysis using the land cover maps provided by the EGIS of the Ministry of Environment. The land cover data of 2019 was used to analyze up-to-date upland conversion status and its correlation with city proximity, while land cover change between 2007 and 2019 was used for paddy-to-upland conversion trend analysis. Overall 14.8% of the entire study reservoir irrigation area was converted to upland cultivation including greenhouse and orchard areas. Approximately the portion of paddy area was reduced by 17.8% on average, while upland area was increased by 4.9% over the 12 years from 2007 to 2019. This conversion from paddy to upland cultivation was more pronounced in the Gyoenggi and Gyeongsang regions compared to other the Jeolla and Chungcheong provinces. The increase of upland area was also more notable in proximity of the major city. This study findings may assist to identify some hot reservoir districts of the rapid conversion to upland cultivation and thus plan to transition toward upland irrigation system.

Methods and Applications to estimate the Conversion Factor of Resource-based Relative Value Scale for Nurse-Midwife's Delivery Service in the National Health Insurance (조산원(助産院)의 분만간호서비스에 대한 건강보험수가 산출방법과 적용방안)

  • Kim, Jin-Hyun;Jung, Yoo-Mi
    • Journal of Korean Academy of Nursing
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    • v.39 no.4
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    • pp.574-583
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    • 2009
  • Purpose: This paper analyzed alternative methods of calculating the conversion factor for nurse-midwife's delivery services in the national health insurance and estimated the optimal reimbursement level for the services. Methods: A cost accounting model and Sustainable Growth Rate (SGR) model were developed to estimate the conversion factor of Resource-Based Relative Value Scale (RBRVS) for nurse-midwife's services, depending on the scope of revenue considered in financial analysis. The data and sources from the government and the financial statements from nurse-midwife clinics were used in analysis. Results: The cost accounting model and SGR model showed a 17.6-37.9% increase and 19.0-23.6% increase, respectively, in nurse-midwife fee for delivery services in the national health insurance. The SGR model measured an overall trend of medical expenditures rather than an individual financial status of nurse-midwife clinics, and the cost analysis properly estimated the level of reimbursement for nurse-midwife's services. Conclusion: Normal vaginal delivery in nurse-midwife clinics is considered cost-effective in terms of insurance financing. Upon a declining share of health expenditures on midwife clinics, designing a reimbursement strategy for midwife's services could be an opportunity as well as a challenge when it comes to efficient resource allocation.