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산/알칼리 촉매를 사용한 우지와 자트로파유 혼합지방의 바이오디젤화

The Conversion of Mixed Fat of Beef Tallow and Jatropha Oil into Biodiesel Using Acid / Alkali Catalysts

  • 현영진 (제주대학교 공과대학 생명화학공학과, 첨단기술연구소)
  • Hyun, Young-Jin (Department of Biological and Chemical Engineering, Institute of Advanced Technology Cheju National University)
  • 발행 : 2009.06.30

초록

The esterification of the reactants of Jatropha oil and methanol added by propyleneglycol was done using p-TSA catalyst. And then the emulsification of triglyceride and methanol was conduced by 1.0vol% GMS. The emulsified reactants were transesterified at $65^{\circ}C$ using TMAH and mixed catalyst (50wt%-TMAH+50wt%-NaOH) respectively. The esterification conversion at the 1:8 molar ratio of free fatty acid to methanol using 8.0wt% p-TSA was 94.7% within 80min. The overall conversion at the 1:8 molar ratio of mixed fat(50wt% Beef Tallow) to methanol and $65^{\circ}C$ using mixed catalyst was 95.4% The cloud point of Biodiesel decreased with the addition of petroleum diesel.

키워드

참고문헌

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