• Title/Summary/Keyword: osmotic concentration

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Mass Transfer Characteristics in the Osmotic Dehydration Process of Carrots (당근의 삼투건조시 물질이동 특성)

  • Youn, Kwang-Sup;Choi, Yong-Hee
    • Korean Journal of Food Science and Technology
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    • v.27 no.3
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    • pp.387-393
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    • 1995
  • Diffusion coefficients of moisture and solid, reaction rate constants of carotene destruction, and the fitness of drying models for moisture transfer were determined to study the characteristics of mass transfer during osmotic dehydration. Moisture loss and solid gain were increased with increase of temperature and concentration; temperature had higher osmotic effect than concentration. Diffusion coefficient showed similar trend with osmotic effect. Diffusion coefficients of solids were larger than those of moisture because the movement of solid was faster than that of moisture at the high temperature. Reaction rate constants were affected to the greater extent by concentration changes than by temperature changes. Arrhenius equation was applied to determine the effect of temperature on diffusion coefficients and reaction rate constants. Moisture diffusion required high activation energy in $20^{\circ}Brix$, while relatively low in $60^{\circ}Brix$. To predict the diffusion coefficients and reaction rate constants, a model was established by using the optimum functions of temperature and concentration. The model had high $R^2$ value when applied to diffusion coefficients, but low when applied to reaction rate constants. Quadratic drying model was most fittable to express moisture transfer during drying. In conclusion, moisture content of carrots could be predictable during the osmotic dehydration process, and thereby mass transfer characteristics could be determined by predicted moisture content and diffusion coefficient.

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Quality Characteristics of Hot-Air and Freeze Dried Apples Slices after Osmotic Dehydration (사과의 삼투압처리 후 열풍 및 동결건조에 따른 품질 특성)

  • Kim, Gi-Chang;Lee, Sun-Young;Kim, Kyung-Mi;Kim, Young;Kim, Jin-Sook;Kim, Haeng-Ran
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.40 no.6
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    • pp.848-852
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    • 2011
  • The aim of our study was to develop drying process of apple slice. Quality characteristics of apple slices dried by hot-air and freeze drying after osmotic dehydration was investigated in different sucrose solution (20, 40, $60^{\circ}Brix$) and steeping time (2, 4, 8 hours). The weight of apple slice before and after osmotic dehydration was measured for characteristic of mass transfer. Consequently, osmotic dehydration increases weight reduction, water loss and solid gain of apple slice as the concentration of the sucrose solution and steeping time increased. Moisture contents of apples slices dried hot-air and freeze were about 3 to 7%. Hunter color L, a, b value was lower than non-treatment to osmotic dehydration of apple slice. In hot-air drying, L value decreased as the concentration of the sucrose solution and steeping time increased. The hardness increased as the concentration of the sucrose solution and steeping time increased. Contents of monosaccharide (glucose, fructose) decrease by osmotic dehydration but sucrose increased. In comparison with hot-air drying, freeze drying was high in contents of free sugar.

Mass transfer Characteristic during Osmotic Dehydration of Ginger and Its Effect on Quality (생강 삼투압 건조 시 물질이동 특성과 품질에 미치는 효과)

  • Kim, Myung-Hwan
    • Applied Biological Chemistry
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    • v.41 no.5
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    • pp.372-376
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    • 1998
  • Internal mass transfer during osmotic dehydration of gingers in sugar solution was examined as a function of concentration, temperature and immersion time of those solutions using moisture loss, sugar gain, molality and rate parameter. Influence of osmotic dehydration on browning reaction and texture properties of air dried rehydrated was also evaluated. Increasing the concentration and temperature of sugar solutions increased moisture loss, sugar gain, molality and rate parameter. Water loss and sugar gain were rapid in the first 3 min and then changed gentle slope. Moisture loss during osmotic dehydration using a sugar solution $(60\;Brix,\;80^{\circ}C)$ with 18 min immersion time was 40.05 g moisture/100 g wet ginger which was 52% reduction of initial moisture content in ginger (83.02%, wet basis). The changes of rate parameter were more affected by temperature than by concentration of sugar solution. Minimum browning degree (O.D.=0.027) was carried out by osmotic dehydration in sugar solution $(40\;or\;50\;Brix,\;80^{\circ}C)$ with 15 min immersion time compared to control (O.D.=0.132). Influence of osmotic dehydration on puncture forces of 3 min rehydrated ginger in boiling water were $22{\sim}34%$ of reduction, while blanching treatment had not affected compared to those of control.

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Microstructure and shear modulus in concentrated dispersions of bidisperse charged spherical colloids

  • Chun, Myung-Suk;Lee, Sangwoo;Lee, Tae-Seok;Cho, Jae-Seol
    • Korea-Australia Rheology Journal
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    • v.16 no.1
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    • pp.17-26
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    • 2004
  • We examine rigorous computations on microstructural as well as rheological properties of concentrated dispersions of bidisperse colloids. The NVT Monte Carlo simulation is applied to obtain the radial distribution function for the concentrated system. The long-range electrostatic interactions between dissimilar spherical colloids are determined using the singularity method, which provides explicit solutions to the linearized electrostatic field. The increasing trend of osmotic pressure with increasing total particle concentration is reduced as the concentration ratio between large and small particles is increased. From the estimation of total structure factor, we observe the strong correlations developed between dissimilar spheres. As the particle concentration increases at a given ionic strength, the magnitude of the first peak in structure factors increases and also moves to higher wave number values. The increase of electrostatic interaction between same charged particles caused by the Debye screening effect provides an increase in both the osmotic pressure and the shear modulus. The higher volume fraction ratio providing larger interparticle spacing yields decreasing high frequency limit of the shear modulus, due to decreasing the particle interaction energy.

Separation of Colloidal Particles by Osmotic Sink Field Flow Fractionation Using UF Hollow Fiber Membranes

  • Shin, Se-Jong;Min, Byoung-Ryul;Park, Jin-Won;Ahh, Ik-Sung;Lee, Kang-Taek;Lee, Jae-Hoon
    • Korean Membrane Journal
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    • v.3 no.1
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    • pp.59-68
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    • 2001
  • Unlike existent field flow fractionation, new method, osmotic sink field flow fractionation is introduced and used ultrafiltration hollow fiber membranes as separation channel. This hollow fiber osmotic sink field flow fractionation is called HF-OSFFF. A theory that describes the retention, relaxation, resolution, plate number for the system, has been developed and experimentally verified by separation model of po1ystyrene latex beads. At external field, it is measured that radial flow rates change according to various concentrations of PEG solutions. Concentration of PEG solution vs. radial flow rate is a linear relation. For diameter distribution of unknown polymer sample, HF-OSFFF compared with the commercial capillary hydrodynamic flow fractionation (CHDF).

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Change in Photosynthesis, Proline Content, and Osmotic Potential of Corn Seedling under High-Saline Condition

  • Yoon Byeong Sung;Jin Chengwn;Park Sang Un;Cho Dong Ha
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.50 no.1
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    • pp.28-31
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    • 2005
  • To identify salt-tolerance characteristics of corn seedling was treated in solution of 0, 50 and 100 mM NaCl of hydroponic cultivation. In photosynthesis of corn seedling, there was no large difference between 50mM and 0 mM NaCl solution, however, in 100 mM NaCl solution, the tolerance gradually decreased to $76\%,\;49\%,\;and\;31\%$ after one day, four days, and seven days, respectively, in comparison to 0 mM NaCl solution. Osmotic potential of corn in seedling period was significantly decreased with increasing saline level, however, free proline content in the plant on the ground was significantly increased with increasing saline level and with the lapse of time. In terms of correlation among major characteristics, there was a highly significant positive difference between osmotic pressure potential and photosynthesis, However, highly negative correlation was found between osmotic pressure potential and free proline content. In addition, it was expected that young seedling of corn with saline tolerance may be utilized in the transplantation in salt-accumulated land. Based on above-shown result, in terms of saline tolerance of Chalok-2 variety, growth suppression was serious with 100mM NaCl solution. However, growth was expected that seedling growth would be favorable under 50 mM NaCl solution.

Effects of Ginseng Saponins on Cholesterol Solubility (인삼(人蔘) Saponin류(類)가 Cholesterol 용해도(溶解度)에 미치는 영향(影響))

  • Ha, Choon-Ja;Kim, Sung-Ho
    • Korean Journal of Pharmacognosy
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    • v.15 no.3
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    • pp.134-138
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    • 1984
  • In this study the solubility of cholesterol was examined with ginseng saponin and chemical saponin used in the preparation of reaction mixture of 0.15M NaCl solution. It was shown that the solubility of cholesterol varied in the concentration of ginseng saponins and in the temperature and that the osmotic pressure and the surface tension was amenable to changes in the concentration of ginseng saponins and the incubation period of the reaction mixture. From the results, it was revealed that the solubility of cholesterol was dependent upon the incubated times and the concentration of ginseng saponins in 0.15mM NaCl solution and that ginseng saponins have the cholesterol solubilizing effect as evidenced in the physicochemical properties of mixed micelle formation and surface-activity.

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A COMPUTATIONAL MODEL FOR OSMOSIS PHENOMENA OF CELLS THROUGH SEMI-PERMEABLE MEMBRANES

  • Kim, Im-Bunm;Ha, Tae-Young;Sheen, Dong-Woo
    • Journal of the Korean Society for Industrial and Applied Mathematics
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    • v.13 no.2
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    • pp.123-140
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    • 2009
  • The effect of a solute concentration difference on the osmotic transport of water through the semi-permeable membrane of a simple cell model is investigated. So far, most studies on osmotic phenomena are described by simple diffusion-type equations ignoring all fluid motion or described by Stokes flow. In our work, as the governing equations, we consider the coupled full Navier-Stokes equations which describe the fluid motion and the full transport equation that takes into account of convection and diffusion effects. A two dimensional finite difference model has been developed to simulate the velocity field, concentration field, and semi-permeable membrane movement. It is shown that the cell swells to regions of lower solute concentration due to the uneven water flux through the semi-permeable membrane. The simulation is applied on a red blood cell geometry and the relevant results are presented.

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Phosphorylation of AQP4 Water Channel Regulates Water Permeability (Aquaporin 4 water channel 인산화에 의한 수분 투과도의 조절)

  • 박권희;정동근;정진섭;이재숙;예운해;서덕준;배혜란
    • Journal of Life Science
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    • v.10 no.5
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    • pp.456-466
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    • 2000
  • Aquaperin 4 (AQP4) is the mercurial water channel expressed abundantly in brain, especially the region related with cerebrospinal fluid reabsorption and osmoregulation. The primary structure of AQP4 water channel was elucidated but the molecular mechanism of AQP4 channel regulation is still unknown. To investigate the possible regulation of AQP4 water channel by phosphorylation via various protein kinases, osmotic water permeability of AQP4 expressed in Xenopus oocytes was measured by videomicroscopy technique. Forskolin (10 $\mu$M) did not affect osmotic water permeability of oocytes injected with AQP4 cRNA, excluding the regulation of AQP4 water cnannel by protein kinase A. Osmotic water permeability (P아래첨자) of AQP4-expressed oocytes was ingibited by the pretreatmeat of BAPTA/AM (up to 500$\mu$M), an intracellular Ca윗첨자 chelator, and calmidazolium (100$\mu$M), a specific Ca윗첨자/calmodulin antagonist, in a dose-dependent manner. The inhibition of osmotic water permeability (P아래첨자) by the calmidazolium treatment was completely reversed by the addition of calyculin A (0.1$\mu$M), a nonspecific phosphatase inhibitor. Phorbol 12-myristate 13-acetate (PMA), a protein kinase C activator, had biphasic effects on osmotic water permeability in AQP4 cRNA injected oocytes depending on its concentration; 21% increase by 100 nM PMA, 35% decrease by 1$\mu$M PMA. These effects were reversed with 2$\mu$M staurosporine, a nonspecific PKC inhibitor. These results suggest that phosphorylation of AQP4 water channel by Ca윗첨자/calmodulin kinase and protein kinase C might regulate the osmotic water permeability.

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A Study on Relationship between Corrosion Characteristics and Salt Concentration of Anti-corrosive Paint (방청도료의 부식특성과 염분농도의 상관관계에 관한 연구)

  • Moon, Kyung-Man;Lee, Myeong-Woo;Lee, Myeong-Hoon;Kim, Hye-Min;Baek, Tae-Sil
    • Journal of the Korean institute of surface engineering
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    • v.51 no.2
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    • pp.95-103
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    • 2018
  • Recently, many types of constructional steels have been often exposed to under severe corrosive environments due to acid rain with increasing environmental contamination. In order to inhibit their corrosion in severe corrosive environments, a painting method has been widely applied to numerous constructional steels of land as well as marine. Therefore, development of paint having a good quality of corrosion resistance is considered to be very important. In this study, four types of anti-corrosive paints (AP: Phenol epoxy, AC: Ceramic epoxy, AT: Coal tar epoxy, AH: High solid epoxy) were coated to the specimens, and then, were immerged in various salt solutions (0.1, 0.3, 3, 6, 9 and 15% NaCl solutions) for 11 days. And, the corrosion resistance of these samples by effect of osmotic pressure with salt concentration was investigated with electrochemical methods such as measurement of corrosion potential, impedance and corrosion current density. The corrosion current densities of all samples (AC, AT and AH) submerged in 3% NaCl solution exhibited the smallest values compared to other salt solutions. However, in the case of lower values of salt solutions than 3% NaCl solution, the corrosion current density increased again because it makes easier for water, dissolved oxygen and chloride ion etc. to invade toward inner side of coating film due to increasing of the osmotic pressure than 3% NaCl solution, but in the case of higher values of salt solutions than 3% NaCl solution, the coating film is easily deteriorated due to high concentration of chloride ion rather than the osmotic pressure, which resulted in increasing the corrosion current density. In particular, the AC sample indicated the best corrosion resistance in 6% NaCl solution compared to other samples. Consequently, it is considered that the corrosion mechanism of the coated steel plate is completely different from bare steel plate, and the corrosion resistance of coating film by osmotic pressure and chloride ion depend on various types of epoxy of paint in NaCl solution.