• Title/Summary/Keyword: osmosis membrane

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Rotating Reverse Osmosis Membrane Filtration (회전 역삼투 분리막 여과)

  • Sangho Lee;Richard M. Lueptow
    • Membrane Journal
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    • v.13 no.3
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    • pp.131-142
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    • 2003
  • Cylindrical rotating reverse osmosis (RO) is a means of dynamic filtration that incorporates both high shear and flow instabilities to reduce membrane fouling. This article summarizes recent works on rotating RO including the physics of rotating filtration; mass - transfer and concentration polarization; theoretical and experimental analysis; and some case studies.

Study of Surface Properties on Fouling Resistance of Reverse Osmosis Membranes (역삼투 분리막 표면 특성의 내오염성 상관 관계 연구)

  • 김노원
    • Membrane Journal
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    • v.12 no.1
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    • pp.28-40
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    • 2002
  • The primary objective of this study is to elucidate the contribution of the electrostatic and molecula structural properties of an active layer of the thin film compsite (TFC) membranes to fouling tendency. The studies of surface morphology and surface charge were very effective in understanding fouling behaviors of the reverse osmosis (RO) membranes which were the thin film composite type of ployamide. Results of microscopic morphology analyzed by atomic force microscopy (AFM) and surface charge analyzed by electrokinetic analyzer (EKA) showed important factors affecting the fouling of RO membranes. The active layer of the composite membrane possessing realtively neutral streaming charge and less roughness provided a RO membrane with slowly decreasing flux.

Removal of cesium(137Cs) and iodide(127I) by microfiltration·nanofiltration·reverese osmosis membranes (정밀여과·나노여과·역삼투 막에 의한 세슘과 요오드의 제거)

  • Chae, Seon-Ha;Kim, Chung-Hwan
    • Journal of Korean Society of Water and Wastewater
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    • v.28 no.5
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    • pp.549-554
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    • 2014
  • This study was evaluated the applicability of the membrane filtration process (Micro Filtration (MF), nanofiltration membranes (NF), reverse osmosis (RO)) on the major radioactive substances, iodine ($I^-$) and cesium ($Cs^+$) using membranes produced in Korea and domestic raw water. Iodine ($I^-$) or cesium ($Cs^+$) in the microfiltration membrane (MF) process could not be expected removal efficiency by eliminating marginally at the combined state with colloidal and turbidity material. At the domestic raw water (lake water, turbidity 1.2 NTU, DOC 1.3 mg/L) conditions, nanofiltration membrane (NF) and reverse osmosis (RO) showed a high removal rate of about 88 ~ 99% for iodine ($I^-$) and cesium ($Cs^+$) and likely to be an alternative process for the removal of radioactive material.

Structure Parameter Change Estimation of a Forward Osmosis Membrane Under Pressurized Conditions in Pressure-assisted Forward Osmosis (PAFO) (가압형 정삼투 시 압력에 따른 정삼투막의 Structure Parameter 변화양상 예측)

  • Kook, Seungho;Kim, Sung-Jo;Lee, Jinwoo;Hwang, Moonhyun;Kim, In S.
    • Membrane Journal
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    • v.26 no.3
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    • pp.187-196
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    • 2016
  • Pressure-assisted forward osmosis (PAFO) process has recently been under spotlight for its potential to improve forward osmosis (FO) process performance by applying low hydraulic pressure on the feed side. Structure parameter, one of the governing factors in estimating water flux and solute flux across FO membranes in the solution-diffusion model (S-D model), determines solute resistivity in FO and PAFO processes. This study aims to estimate the trend of structure parameter change with respect to varying additional hydraulic pressure condition in PAFO.

Pilot-Scale Simulation of Desalination Process Using Water Integrated Forward Osmosis System (물통합형 정삼투 시스템을 이용한 파일럿 스케일 담수 공정 모사)

  • Kim, Bongchul;Hong, Seungkwan;Choi, Juneseok
    • Journal of Korean Society on Water Environment
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    • v.33 no.4
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    • pp.403-408
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    • 2017
  • In these days, wastewater reclamation and seawater desalination play essential role in addressing the challenge of worldwide water scarcity. Particularly, reverse osmosis (RO) for seawater desalination process is commonly used due to less energy consumption than conventional thermodynamic systems. However, membrane fouling and electrical energy consumption during operation of RO system for seawater desalination haver continued to be a obstruction to its application. In this study, therefore, wastewater secondary effluent is used for osmotic dilution of seawater. Firstly, fouling behaviour of RO by simulating wastewater effluent in osmotic dilution process was measured and we calculated energy consumption of overall desalination process by theoretical equations and commercial program. Our results reveal that RO membrane fouling can be efficiently controlled by pre-treatment systems such as nano filtration (NF) or forward osmosis (FO) process. Especially FO system for osmotic dilution process is a non-pressurized membrane system and, therefore, the operating energy consumption of overall desalination system was the lowest. Moreover, fouling layer on FO membrane is comparatively weak and reversible enough to be disrupted by physical cleaning. Thus, RO system with low salinity feed water through FO process is possible as a less energy consuming desalination system with efficient membrane fouling control.

Hypochlorite treatment of polyamide membrane for improved reverse osmosis performance

  • Shao, P.;Kurth, C.J.
    • Membrane and Water Treatment
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    • v.4 no.1
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    • pp.69-81
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    • 2013
  • The pH-dependent inter-conversion of the three free chlorine species ($Cl_2$, HOCl, OCl-) present in the aqueous hypochlorite solution was theoretically investigated. Each species was found overwhelmingly present in a characteristic pH range. Hypochlorite treatment of the polyamide membrane was carried out over these pH ranges and various membrane responses were observed. As pH is less than 8, membrane tends to be N-chlorinated by $Cl_2$ and HOCl, and N-chlorinated membrane showed reduced water permeance and salt rejection. As pH rises to 10-12, $OCl^-$ appears to be the dominating chlorine species. Membrane hydrolysis was found to well interpret the improved water permeance and salt rejection. When the pH is between 8-10, both N-chlorination and hydrolysis contribute to the response of the membrane, and the treated membrane showed improved salt rejection but reduced water permeation. Excessive hydrolysis occurred while the membrane was treated at pH 13 for the much stronger alkalinity.

Evaluation of Cleaning Efficiency of Reverse Osmosis Module Using Micro-bubble (미세기포를 이용한 역삼투 모듈 세정 효율 평가)

  • Kim, Dongjin;Kang, Shingyung;Cho, Hayoung;Lee, Jeawoo;Moon, Ilshik
    • Membrane Journal
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    • v.27 no.1
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    • pp.104-107
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    • 2017
  • Among many methods in solving the organic contamination in the reverse osmosis operation, caustic soda (NaOH) wash method is efficient and commercially affordable. In continuation of our many organic pollution removal works, this study focused mainly on caustic soda wash with micro-bubble to removal the organic contamination of the spent membrane from reverse osmosis process. First, the membrane was forced the pollute using known organic pollutants such as Humic acid, Bovine serum albumin, Sodium alginate drug. The organic contamination on the membrane was monitored flux. The decontamination of organic contaminants was derived flux variation at individual caustic soda was injected micro-bubble methods and combined method as well. the found results explain removal of organic contaminants effective only by combined caustic soda wash with micro-bubble methods.

NUCLIDE SEPARATION MODELING THROUGH REVERSE OSMOSIS MEMBRANES IN RADIOACTIVE LIQUID WASTE

  • LEE, BYUNG-SIK
    • Nuclear Engineering and Technology
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    • v.47 no.7
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    • pp.859-866
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    • 2015
  • The aim of this work is to investigate the transport mechanism of radioactive nuclides through the reverse osmosis (RO) membrane and to estimate its effectiveness for nuclide separation from radioactive liquid waste. An analytical model is developed to simulate the RO separation, and a series of experiments are set up to confirm its estimated separation behavior. The model is based on the extended Nernst-Plank equation, which handles the convective flux, diffusive flux, and electromigration flux under electroneutrality and zero electric current conditions. The distribution coefficient which arises due to ion interactions with the membrane material and the electric potential jump at the membrane interface are included as boundary conditions in solving the equation. A high Peclet approximation is adopted to simplify the calculation, but the effect of concentration polarization is included for a more accurate prediction of separation. Cobalt and cesium are specifically selected for the experiments in order to check the separation mechanism from liquid waste composed of various radioactive nuclides and nonradioactive substances, and the results are compared with the estimated cobalt and cesium rejections of the RO membrane using the model. Experimental and calculated results are shown to be in excellent agreement. The proposed model will be very useful for the prediction of separation behavior of various radioactive nuclides by the RO membrane.

Effect of intermittent operation modes on performance of reverse osmosis (RO) membrane in desalination and water treatment

  • Yang, Heungsik;Choi, Jihyeok;Choi, Yongjun;Lee, Sangho
    • Membrane and Water Treatment
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    • v.13 no.1
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    • pp.39-49
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    • 2022
  • Seawater desalination is doubtlessly a viable option to supply fresh drinking water. Nevertheless, RO (reverse osmosis) desalination plants in specific areas may be intermittently operated to match the imbalance between water demand and supply. Although a handful of works have been done on other membrane systems, few studies have attempted to mitigate fouling in intermittent RO systems. Accordingly, the objectives of this paper were to examine the effect of the intermittent operation on RO fouling; and to compare four intermittent operation modes including feed solution recirculation, membrane storage in the feed solution, deionized water (DI) recirculation, and membrane storage in DI water. Results showed that intermittent operation reduced RO fouling under several conditions. However, the extents of fouling mitigation were different depending on the feed conditions, foulant types, and membrane lay-up methods. When the feed solution was recirculated during the lay-up, the restoration of the flux was less significant than that by the feed solution feed-up. The use of deionized water during the lay-up was effective to restore flux, especially when the feed solution contains scale-forming salts (CaSO4) and/or colloidal silica.