• Proceedings of the Korean Society of Rheology Conference
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• 2001.09a
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• pp.162.3-162
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• 2001

• International Journal of Concrete Structures and Materials
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• v.10 no.sup3
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• pp.65-74
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• 2016

During concrete pumping, the migration and redistribution of particles occur in a pipe and the lubrication layer that forms between the bulk concrete and the pipe wall is the governing factor determining the flow behavior. In order to identify flow behavior of pumping, in this study, the viscoelastic properties related to the microstructural behavior of a flocculated suspension were examined by using dynamic oscillatory measurements. Cement paste is assumed to be a constituent material of the lubrication layer and ten cases of mixing design are employed by changing the proportions of mineral admixtures. The relationship between the yield stress obtained from the steady shear test and the dynamic modulus resulted from the oscillatory shear measurement was derived and the implications of the correlation are discussed. Moreover, based on the investigation of the viscoelastic properties with oscillatory measurements, the initial behavior of pumped concrete was analyzed systematically.

• Journal of Pharmaceutical Investigation
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• v.39 no.3
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• pp.185-199
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• 2009

Using a strain-controlled rheometer [Advanced Rheometric Expansion System (ARES)], the steady shear flow properties and the dynamic viscoelastic properties of $Antiphlamine-S^{(R)}$ lotion have been measured at $20^{\circ}C$ (storage temperature) and $37^{\circ}C$ (body temperature). In this article, the temperature dependence of the linear viscoelastic behavior was firstly reported from the experimental data obtained from a temperature-sweep test. The steady shear flow behavior was secondly reported and then the effect of shear rate on this behavior was discussed in detail. In addition, several inelastic-viscoplastic flow models including a yield stress parameter were employed to make a quantitative evaluation of the steady shear flow behavior, and then the applicability of these models was examined by calculating the various material parameters. The angular frequency dependence of the linear viscoelastic behavior was nextly explained and quantitatively predicted using a fractional derivative model. Finally, the strain amplitude dependence of the dynamic viscoelastic behavior was discussed in full to elucidate a nonlinear rheological behavior in large amplitude oscillatory shear flow fields. Main findings obtained from this study can be summarized as follows : (1) The linear viscoelastic behavior is almostly independent of temperature over a temperature range of $15{\sim}40^{circ}C$. (2) The steady shear viscosity is sharply decreased as an increase in shear rate, demonstrating a pronounced Non-Newtonian shear-thinning flow behavior. (3) The shear stress tends to approach a limiting constant value as a decrease in shear rate, exhibiting an existence of a yield stress. (4) The Herschel-Bulkley, Mizrahi-Berk and Heinz-Casson models are all applicable and have an equivalent validity to quantitatively describe the steady shear flow behavior of $Antiphlamine-S^{(R)}$ lotion whereas both the Bingham and Casson models do not give a good applicability. (5) In small amplitude oscillatory shear flow fields, the storage modulus is always greater than the loss modulus over an entire range of angular frequencies tested and both moduli show a slight dependence on angular frequency. This means that the linear viscoelastic behavior of $Antiphlamine-S^{(R)}$ lotion is dominated by an elastic nature rather than a viscous feature and that a gel-like structure is present in this system. (6) In large amplitude oscillatory shear flow fields, the storage modulus shows a nonlinear strain-thinning behavior at strain amplitude range larger than 10 % while the loss modulus exhibits a weak strain-overshoot behavior up to a strain amplitude of 50 % beyond which followed by a decrease in loss modulus with an increase in strain amplitude. (7) At sufficiently large strain amplitude range (${\gamma}_0$>100 %), the loss modulus is found to be greater than the storage modulus, indicating that a viscous property becomes superior to an elastic character in large shear deformations.

• Korea-Australia Rheology Journal
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• v.14 no.2
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• pp.49-55
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• 2002

To understand the large amplitude oscillatory shear (LAOS) behavior of complex fluids, we have investigated the flow behavior of a network model in the LAOS environment. We applied the LAOS flow to the model proposed by Vaccaro and Marrucci (2000), which was originally developed to describe the system of associating telechelic polymers. The model was found to predict at least three different types of LAOS behavior; strain thinning (G' and G" decreasing), strong strain overshoot (G' and G" increasing followed by decreasing), and weak strain overshoot (G' decreasing, G" increasing followed by decreasing). The overshoot behavior in the strain sweep test, which il often observed in some complex fluid systems with little explanation, could be explained in terms of the model parameters, or in terms of the overall balance between the creation and loss rates of the network junctions, which are continually created and destroyed due to thermal and flow energy. This model does not predict strain hardening behavior because of the finitely extensible nonlinear elastic (FENE) type nonlinear effect of loss rate. However, the model predicts the LAOS behavior of most of the complex fluids observed in the experiments.he experiments.

• Polymer Science and Technology
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• v.24 no.2
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• pp.183-190
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• 2013

• Food Science and Preservation
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• v.30 no.5
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• pp.785-796
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• 2023

The aim of this study was to elucidate chemical structures and rheological properties of arabinogalactans (AGs) isolated from three legumes including black gram (BG), great northern bean (GNB), and California small white bean (CSWB). The ratio of galactose to arabinose (G/A) in three legumes increased in the order of BG > GNB > CSWB. The rheological measurements of 1-5% (w/v) AG solutions revealed Newtonian and non-Newtonian flow behaviors. BG exhibited yield stress, indicating plastic behavior. Small-amplitude oscillatory tests indicated viscoelastic properties of BG, GNB, and CSWB ranging from solid-like, paste-like, and liquid-like behaviors, respectively. Small-strain oscillatory tests were conducted to assess the structure recovery of the AGs after pre-shearing. G" values of BG and GNB increased, but those of CSWB remained constant after shearing. These results suggest that the chemical structures of the AGs, particularly their G/A ratios, influence their rheological properties.

• Magazine of the Korean Society of Agricultural Engineers
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• v.38 no.1
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• pp.79-89
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• 1996

It is expected that the soil hehaviours in the seahed subjected to cyclic wave loads are much different from that on the ground Cyclic shear stresses developed below the ocean bed as a result of a passing wave train may progressively build up pore pressure in certain soils. Such build-up pore pressure may be developed dynamic behaviour such as liquefaction and significant deformation of the seabed. Currently available analytical and testing methods for the seabed subjected to cyclic wave loads are not general. The purpose of the study are to provide a test method in laboratory and to analyse the mechanism of wave-induced stresses and liquefactions potentials of the unsaturated silty marine sand. It is showed that the test set-up made especially for this study delivers exactly oscillatory wave pressures of the form of sine function. Laboratory test results defining the cyclic shear strength of the unsaturated porous medium that is homogenously sedimented. It is understood that the pore water pressure due to induced-waves is not accumulated as the wave number increases but reveals periodical change on the still water surface. The magnitude of the pore water pressure tends to be attenuated radically with a certain time lag under the action of both high and low waves as depth increases.

• Composites Research
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• v.35 no.3
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• pp.153-160
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• 2022

Cellulose nanofibrils (CNF) based on wood pulp fibers are gained much attention as part of biocompatible hydrogels for biomedical applications such as tissue engineering scaffolds, biomedicine, and drug carrier. However, CNF hydrogels have relatively poor mechanical properties, impeding their applications requiring high mechanical integrity. In this work, we prepare 2,2,6,6-tetramethylipiperidin-oxyl (TEMPO) oxidated cellulose nanofibrils hydrogels mediated with metal cations, which form the metal-carboxylate coordination bonds for enhanced mechanical strength and toughness. We conduct the large amplitude oscillatory shear (LAOS) test and Live/dead cell assay for obtaining nonlinear viscoelastic parameters and cell viability, respectively. In particular, the cell proliferation and viability change depending on the type of metal salt, which also affected the rheological properties of the hydrogels.

• International Journal of Highway Engineering
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• v.7 no.4 s.26
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• pp.203-210
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• 2005

The penetration and viscosity tests have been used for the evaluation of the aged asphalt binder performance change. The improved test method has been required because the conventional tests could not evaluate the viscoelastic characteristics and the real behaviour of the aged asphalt binder. The conventional test methods using a different short term aged asphalt binder were tested and the test results were expressed as the penetration index and the residual penetration. The oscillatory and rotational mode tests were performed to find out the rheological characteristics of the short term aged asphalt binder in this study. The test results showed that the change of testing frequency, the speed of the vehicle effects the complex modules and phase angles. The creep compliance and shear viscosity also showed the different test results when the short term aged asphalt binders were tested. The rheological behavior should consider when the pavement design is conducted.

• Restorative Dentistry and Endodontics
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• v.29 no.6
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• pp.520-531
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• 2004

The aim of this study was to investigate the effect of monomer and filler compositions on the rheological properties related to the handling characteristics of resin composites. Methods. Resin matrices that Bis-GMA as base monomer was blended with TEGDMA as diluent at various ratio were mixed with the Barium glass (0.7 um and 1.0 um), 0.04 um fumed silica and 0.5 um round silica. All used fillers were silane treated. In order to vary the viscosity of experimental composites, the type and content of incorporated fillers were changed, Using a rheometer, a steady shear test and a dynamic oscillatory shear test were used to evaluate the viscosity ($\eta$) of resin matrix, and the storage shear modulus (G'), the loss shear modulus (G"), the loss tangent ($tan{\delta}$) and the complex viscosity (${\eta}^*$) ofthe composites as a function of frequency ${\omega}{\;}={\;}0.1-100{\;}rad/s$. To investigate the effect of temperature on the viscosity of composites, a temperature sweep test was also undertaken. Results. Resin matrices were Newtonian fluid regardless of diluent concentration and all experimental composites exhibited pseudoplastic behavior with increasing shear rate. The viscosity of composites was exponentially increased with increasing filler volume%. In the same filler volume, the smaller the fillers were used, the higher the viscosities were. The effect of filler size on the viscosity was increased with increasing filler content. Increasing filler content reduced $tan{\delta}$ by increasing the G' further than the G". The viscosity of composites was decreased exponentially with increasing temperature.