• 한국환경과학회지
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• 제5권5호
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• pp.561-567
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• 1996

31 종류의 유기 염소계 잔류 농약을 동시에 분석하는 기체 크로마토그래피 방법을 개발하기 위하여 본 연구를 수행하였다. 준비된 분석 시료를 ECD (electron capture detector)로 Ultra-2 column의 GC (gas chromatography)에 주입하였다. Column 충진 물질을 florisil과 alumina N으로 변화시키면서 잔류 용액을 column에 loading하고 용출 용매로는 ether . benzene(2 : 8) solution, hexane . benzene(1 . 1) solution, dichloromethane, acetone 및 methanol을 사용하였다. 분석 결과 column 충진 물질로 florisil을 사용하였을때 (첫째 조건) 6종류의 유기 염소(dichlorfluanid, captan, chlorofenvinfos, folpet, captafol과 dicofol)가 검출되지 않았다. 이 조건에서 dichloromethane과 methanol을 용출 용매로 첨가하였을때는 (둘째 조건) 첫째 분석 조건하에서 검출되지 않았던 6종류의 유기 염소가 검출되었고 thrin계 pesticides, 특히 captan과 captafol의 recovery가 증가하였다(첫째 조건에서와 마찬가지로 충진 물질로 florisil을 사용). 그러나 BHC(benzene hexachloride) 화합물의 recovery는 감 소하였다. 한편 alumina N을 column 충진 물질로 사용하였을 경우에는 dichlorfluanid, chlorofenvinfos, folpet 및 dicofol의 recovery가 증가하였으며 aldrin도 그러하였다. 하지만 captan과 captafol은 그렇지 못하였다. Thrin계 pesticides, captan 및 captafol을 동시에 검출하기 위하여 florisil과 alumina N을 충진 물질로 동시에 사용하고 n-hexane을 충진시켜 용출시킨 결과, captan과 captafol이 검출되지 않았는데 이는 column이 충분히 활성화되지 않았기 때문이라고 생각된다. Column(florisil과 alumina N을 충진 물질로 동시 사용)을 충분히 활성화시키고 여러가지 용출 용매를 사용하여 불순물을 제거하였을때 분석 결과가 가장 우수하였다(31 종류의 유기 염소계 잔류 농약이 sharp하게 검출되었고 높은 감도를 나타내었다).

• 자원리싸이클링
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• 제31권1호
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• pp.46-55
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• 2022

최근 희유금속 자원 회수에서 초경합금 스크랩 재활용의 중요성이 증가하고 있다. 그러나 IV, V족 전이금속 질화물로 코팅된 초경합금 스크랩에서 고순도 분말 회수에서 어려움을 겪고 있다. 제1원리 계산을 사용하여 IV 및 V족 전이금속 질화물(TiN, VN, ZrN, NbN, HfN 및 TaN)의 구조, 탄성 및 기계적 특성을 조사하였다. IV족 전이금속 질화물은 V족 전이금속 질화물보다 높은 공유결합 특성을 보였다. 따라서 IV족 전이금속 질화물은 V족 전이금속 질화물보다 취성 거동을 보였다. 대조적으로 V족 전이금속 질화물은 최외각전자 농도에 영향받는 금속결합의 특성 때문에 IV족 전이금속 질화물보다 전단응력에 대한 약한 저항성과 연성 거동을 보였다. Crystal orbital Hamilton population 분석 결과는 모든 전이금속 질화물의 전단 저항 경향성이 일치함을 보여주었다.

• 한국유기농업학회지
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• 제8권1호
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• pp.111-129
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• 1999

In order to get some basic data to check the environmental sound function against soil and water pollution and the safe vegetable production by korean organic farming where an internationally recognized basic concepts of soil fertility management for organic farming is not practiced and only applying the organic fertilizer to maintain the soil fertility, the chemical characteristics of soils and $NO_{3}^{-}$ content of chinese cabbage and lettuce cultivated by the conventional farming, greenhouse cultivation and organic farming were investigated. The highest value of $NO_{3}^{-}$-N in 0~30cm subsoil among the three different farming systems was found in the subsoil of organic farming and it was 3.6 and 6.6 times higher than those of conventional farming in chinese cabbage and lettuce respectively. $P_2O_5$ accumulation in the rhizosphere by organic farming also showed the highest value. The accumulation of $NO_{3}^{-}$-N and $P_2O_5$ in organic farming soil were similar or even more higher to those of greenhouse cultivation. The $NO_{3}^{-}$ accumulation in the vegetable by organic farming reached 3224ppm for chinese cabbage and 2543ppm for lettuce, and it were 4.7 and 6.4 times higher than those by conventional farming. It was concluded that there is urgently necessary to introduce the main concepts of soil fertility management of the Basic Standard of IFOAM, EU regulation and FAO/WHO Codex Alimentarius on organic agriculture(draft) into korean organic agriculture for the operation of environmental sound system and the production of sate vegetable in terms of $NO_{3}^{-}$ content.

• 한국섬유공학회:학술대회논문집
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• 한국섬유공학회 2007년도 학술발표회 논문집
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• pp.261-262
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• 2007

• 한국섬유공학회:학술대회논문집
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• 한국섬유공학회 2007년도 학술발표회 논문집
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• pp.349-350
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• 2007

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2001년도 하계학술대회 논문집
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• pp.648-651
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• 2001

We studied about luminance characteristics of blue organic electroluminecent device as thickness ratio. The device is fabricated TPD(N,N'-dyphenyl-N-N'-bis(3-methyphenyl) -1,1'-biphenyl-4,4'-diamine) as hole transport layer and Butyl -PBD(1,1,4,4-Tetraphenyl-1,3-butadiene) as emission layer and electron transport layer. Total thickness is 1000${\AA}$ as HTL and ETL, each devices has 500${\AA}$:500${\AA}$. 400${\AA}$:600${\AA}$ and 600${\AA}$:400${\AA}$ of TPD : Butyl-PBD. We obtained the maximum brightness about 175cd/㎡ 500${\AA}$: 500${\AA}$ thickness devices as HTL:ETL

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2001년도 하계학술대회 논문집
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• pp.943-946
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• 2001

In this study, We have investigated degradation effects of blue organic electroluminescence devices that was consisted of TPD(N,N'-dyphenyl-N-N\`-bis(3-methyphenyl) as hole transport layer and Butyl-PBD (2- (4-Biphenylyl)-5-(4-tert-butylphenyl)-1,3,4-oxadiazole)-as emission layer and electron transport layer. We have studied characteristics of brightness and current density about blue OEL that was degradated layer. Two kinds of samples that were fabricated each continuous and non-continuous method was used.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2002년도 하계학술대회 논문집
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• pp.198-201
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• 2002

We have studied the temperature dependence of current-voltage and luminance-voltage characteristics of Organic Light Emitting Diodes(OLEDs). The OLEDS are based on the molecular compounds, N,N'-diphenyl-N,N'-bis(3-methylphenyl)-1,1'-biphenyl-4,4'-diamine (TPD) as a hole transport, tris(8-hydroxyquinolinoline) aluminum(III) (Alq$_3$) as an electron transport, and poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) as a buffer layer. The current-voltage and luminance-voltage characteristics were measured in the temperature range of 10[K] and 300[K]. A conduction mechanism in OLEDs has been interpreted in terms of space-charge-limited current(SCLC) and tunneling mechanism.

• 환경위생공학
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• 제17권3호
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• pp.83-88
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• 2002

This study was performed to determine the possibility of sludge treatment by ozone for reducing the sludge production in sewage treatment. To evaluate the characteristics of the release of organic matters and nutrient from sludge degradation by ozone, SCOD, SBOD/TCOD, T-N and T-P were analyzed. From the results, we concluded that the concentration of soluble organic matters(SCOD) was increased with reaction time. Also, The concentration of T-N and T-P were increased with time like as organic matters. Quantities of released SCOD, SBOD, T-N and T-P by ozonization were 0.038g, 0.058 g, 0.011 g, 0.012 g per g MLSS, respectively.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2007년도 7th International Meeting on Information Display 제7권1호
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• pp.741-744
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• 2007

The research applied the processes of spin-coating and thermal-evaporating in proper order to deposit the hole transport material N,N'-Bis(naphthalen-1-yl)- N,N'-bis(phenyl)-benzidine (NPB) on the ITO substrate to make flexible organic light emitting diodes (FOLED) with double hole transport layer.