• Title/Summary/Keyword: organic N

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Characteristics of $NH_3$-N removal in nitrification reactor according to organic loading rate (질산화 반응조에서 유기물 부하에 따른 암모니아 제거 특성)

  • Kang, Min-Koo;Kim, Keum-Yong;Kim, Seung-Ha;Ryu, Hong-Duck;Lee, Sang-Ill
    • Journal of environmental and Sanitary engineering
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    • v.24 no.3
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    • pp.7-15
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    • 2009
  • The objective of this study was to investigate difference in nitrogen, organic, phosphorus and $NH_3$-N removal efficiency according to organic loading, comparing M-DEPHANOX process which has two nitrification reactor with M-eBNR process which has one nitrification reactor. As a result of this study, $NH_3$-N removal efficiency of M-DEPHANOX and M-eBNR resulted in average level of 91.8%, 96.9%, respectively. M-DEPHANOX and M-eBNR processes showed high removal efficiency in view of $NH_3$-N removal efficiency. Comparing organic removal efficiency by M-DEPHANOX and M-eBNR processes, the average removal efficiency in terms of TCOD, SCOD was 84.1%, 78.2% and 83.4%, 75.6%. Also, the results that observed about $NH_3$-N removal efficiency regarding organic loading revealed that nitrification reactor of RBC type are little influenced by flowing organic without precipitating at settling tank. Therefore, although inflow characteristics of municipal wastewater changes, M-eBNR process appeared to remove $NH_3$-N reliably.

Binding affinity of some herbal extracts on the glycine binding site of NMDA (N-Methyl-D-Aspartate) receptor (수종 생약추출물의 NMDA(N-Methyl-D-Aspartate) 수용체 glycine binding site에 대한 친화력 검색)

  • Kim, Young-Sup;Kim, Jeoung-Seob;Kim, Seong-Kie;Heor, Jung-Hee;Lee, Byung-Eui;Ryu, Shi-Yong
    • Korean Journal of Pharmacognosy
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    • v.32 no.3 s.126
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    • pp.212-218
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    • 2001
  • The water extracts of 82 Korean medicinal herbs were prepared and were examined for the binding affinity on the glycine binding site of NMDA (N-methyl-D-aspartate) receptor prepared by the synaptic membranes from the forebrains of male Sprague-Dawley rats. Among the tested, the extracts of Dioscoreae Rhizoma, Hoveniae Semen cum Fructus, Astragali Radix, Armeniacae Semen, Huttuynia cordata Herba, Acanthopanacis Cortex, Aurantii nobilis Pericarpium, Phellinus linteus, Amomi Fructus, Artemisiae capillaris Herba, Polyporus, Agastachis Herba and of Galli Stomachichum Corium were found to exhibit significant competitions with $[^3H]-MDL$ 105,519 for the glycine specific binding site of NMDA receptor in a dose dependent manner, respectively.

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Fluorescence-Quenched Sensor for Trinitophenol in Aqueous Solution Based on Sulfur Doped Graphitic Carbon Nitride

  • Min, Kyeong Su;Manivannan, Ramalingam;Satheshkumar, Angu;Son, Young-A
    • Textile Coloration and Finishing
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    • v.30 no.2
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    • pp.63-69
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    • 2018
  • In this study, we report on successful attempt towards the synthesis of sulfur self-doped $g-C_3N_4$ by directly heating thiourea in air. The synthesized materials were characterized using UV-vis spectral technique, FT-IR, XRD and TEM analysis. Further, the obtained material shows an excellent detection of carcinogenic TNP(Tri nitro phenol) in the presence of 10-fold excess of various other common interferences. The strong inner filter effect and molecular interactions(electrostatic, ${\pi}-{\pi}$, and hydrogen bonding interactions) between TNP and the $S-g-C_3N_4$ Nano sheets led to the fluorescence quenching of the $S-g-C_3N_4$ Nano sheets with an excellent selectivity and sensitivity towards TNP compared to that of other nitro aromatics under optimal conditions and the detection limit calculated was found to be 6.324 nM for TNP. The synthesized nanocomposite provides a promising platform for the development of sensors with improved reproducibility and stability for ultra-sensitive and selective sensing of TNP.

Effects of Hole-Injection Buffer Layer in Organic Light-Emitting Diodes (유기 발광 소자에서 정공 주입 버퍼층의 효과)

  • 정동희;김상걸;오현석;홍진웅;이준웅;김영식;김태완
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.9
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    • pp.816-825
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    • 2003
  • Current-voltage-luminance characteristics of organic light-emitting diodes (OLEDs) were measured in the temperature range of 10 K~300 K. Indium-tin-oxide (ITO) was used as an anode and aluminum as a cathode in the device. Organic of N,N'-diphenyl-N,N'-di(m-tolyl)-benzidine (TPD) was used for a hole transporting material, and tris (8-hydroxyquinolinato) aluminum (Alq$_3$) for an electron transporting material and emissive material. And copper phthalocyanine (CuPc), poly(3,4-ethylenedi oxythiophene);poly(styrenesulfonate) (PEDOT:PSS), and poly(N-vinylcarbazole) (PVK) were used for hole-injection buffer layers. From tile analysis of electroluminescence (EL) and photoluminesccnce (PL) spectra of the Alq$_3$, the EL spectrum is more greenish then that of PL. And the temperature-dependent current-voltage characteristics were analyzed in the double and multilayer structure of OLEDS. Electrical conduction mechanism was explained in the region of high-electric and low-electric field. Temperature-dependent luminous efficiency and operating voltage were analyzed from the current-voltage- luminance characteristics of the OLEDS.

A Study on Electron Injection Characteristics of Organic Light Emitting Diodes with Doped Cathodes of Organic Light Emitting Diodes

  • Kwak, Yun-Hee;Lee, Yong-Soo;Park, Jae-Hoon;Kim, Yeon-Ju;Park, Jong-Sun
    • KIEE International Transactions on Electrophysics and Applications
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    • v.3C no.1
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    • pp.19-22
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    • 2003
  • The co-evaporated cathodes composed of A1 and CsF is adopted to enhance the electrical and the optical properties of organic light emitting diodes (OLEDs). The hole transport layer (HTL), made of 50nm thick N,N-dipheny1-N,N-bis(3-methylphenyl)-1,1-bipheny14,4-diamine (TPD), and the electron transport layer (ETL), made of 50nm thick tris(8-hydroxy-quinoline) aluminum (A1q$_3$), were deposited under the base pressure of 1.6$\times$10$^{-6}$ Torr. In depositing A1-CsF, the mass ratio of CsF is varied between 1 and 10wt%. OLEDs with co-evaporated cathodes have luminance of about 35,000cd/$m^2$, and external quantum efficiency of about 1.38%. Cs tends to diffuse into the organic layer and then re-forms Cs$^{+}$cation and free electron with the Cs-doped surface region.n.

Organic Light Emitting Diodes (OLED) with Electrostatic spray deposition (ESD)

  • Hwang, Won-Tae;Kim, Nam-Hun;Xin, Guoqing;Jang, Hae-Gyu;Chae, Hee-Yeop
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.432-432
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    • 2010
  • Organic light emitting diodes (OLED) thin films were fabricated by Electrostatic spray deposition (ESD). In this study, we reported the thickness, morphology, current efficiency, luminescence of OLED fabricated by ESD. These results were compared with the spin coating method, and showed that also ESD is a good fabrication method for OLED because of its characteristics similar with the results using spin coating. The active layer consists of organic blends with Poly(N-vinylcarbazole) (PVK), 2-(4-Biphenyl)-5-(4-tert-butylphenyl)-1,3,4-oxadiazole (PBD), N,N'-Bis(3-methylphenyl) -N,N'-bis(phenyl)-benzidine (TPD), Tris(2-phenylpyridine)iridium(III) (Ir(ppy)3), and the structure of OLED consists of aluminum (Al), lithium fluoride (LiF), organic blends, PEDOT:PSS and Indium-tin-oxide (ITO), which was used as the top cathode, cathode interfacial layer, emitting layer and bottom anode, respectively. The results suggest that Electrostatic spray deposition is a promising method for the next generation of OLED fabrication since it has a probability fabricating large-area thin films.

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Organic Farming in Korea-I. Study on Microarthropods in Rice Fields of Organic Farming- (유기농업에 관한 연구-I.유기농법 답포장에서의 절지동물상 조사-)

  • 이용환;고현관;황광남;호교순
    • Korean Journal of Organic Agriculture
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    • v.6 no.2
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    • pp.75-80
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    • 1998
  • Organically cultured rice fields were surveyed to compare the population density and the structure of microarthropod communities between chemically controlled and un-controlled fields. In rice fields, microarthropod communities were also compared among four treatments based on different input of fertilzer : 1)No fertilizer, 2)Chemical fertilizer(N-P2O5-K2O = 11 - 7 - 8 kg/10a, 3) Compost (5,000kg/10a), 4) Compost com-plemented with chemical N. Richness index of microarthropod communities in rice fields was greater in the chemically uncontrolled field than controlled field. Within field. the compost plot had greater value of richness index for microarthopod commuities than the non-fertilizer polt. A total of 9 aquatic insects species were identified in the water of organic farming rice field the population density was found to be higher in the compost plot than the other plot. The population of insect pests was found to be high in the late stage of plant whereas the population of insects was high in the early stage of rice plant.

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Effect of Sex Pheromone Trap and Bio-insecticides against Large Black Chafer (Holotrichia parallela) in Organic Pear Orchards (배 유기재배 과원에서 성페르몬 트랩과 살충효과 유기농자재가 큰검정풍뎅이 방제에 미치는 영향)

  • Song, Jang-Hoon;Md, Abdul Alim;Choi, Eu-Ddeum;Seo, Ho-Jin
    • Korean Journal of Organic Agriculture
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    • v.26 no.2
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    • pp.245-257
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    • 2018
  • The efficacy of different control techniques against the large black chafer, Holotrichia parallela Motschulsky (Coleoptera: Scarabaeidae), in organic pear (Pyrus pyrifolia) orchards was evaluated. In this study, field trials were conducted in three locations in Korea-Naju, Hampyeong, and Boseong-to evaluate different techniques to suppress these beetles. Pheromone traps, bio-insecticides (Hongmengye and Melchungdaejang), and a combination of the two were applied as treatments. In Naju, Hampyeong, and Boseong, the highest number of adult H. parallela were caught in the control plots (n=45, n=39, and n=20, respectively), while the fewest were caught in the pheromone plus bio-insecticide plot (n=19) in Naju and in the combined treatment plot in Hampyeong (n=10). In Naju, the greatest leaf damage was observed in the control (66%), and in all locations (Naju, Boseong, and Hampyeong), the least damage occurred in the combined treatment plots (42%, 36%, and 24%, respectively). Regarding the tree canopy, the greatest leaf damage was observed in the upper canopy, and less damage was observed in the lower canopy. These results demonstrate that the combination of sex pheromone traps and bio-insecticides can be used to manage H. parallela in organic pear orchards.

Effect of Soil Respiration on Light Fraction-C and N Availability in Soil Applied with Organic Matter

  • Ko, Byong-Gu;Lee, Chang-Hoon;Kim, Myung-Sook;Kim, Gun-Yeob;Park, Seong-Jin;Yun, Sun-Gang
    • Korean Journal of Soil Science and Fertilizer
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    • v.49 no.5
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    • pp.510-516
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    • 2016
  • Soil respiration has been recognized as a key factor of the change of organic matter and fertility due to the carbon and nitrogen mineralization. In this study, we evaluated the effect of soil respiration on the light fraction-C and inorganic N content depending on temperature in soil applied with organic matter. Soil respiration was calculated by using total $CO_2$ flux released from soil applied with $2Mg\;ha^{-1}$ of rice straw compost and rye for 8 weeks incubation at 15, 25, $35^{\circ}C$ under incubation test. After incubation test, light fraction and inorganic N content were investigated. Rye application dramatically increased soil respiration with increasing temperature. $Q_{10}$ value of rye application was 1.69, which was higher 27% than that of rice straw compost application. Light-C and $NO_3-N$ contents were negatively correlated to soil respiration. Light-C in rye application more decreased than that in rice straw compost with temperature levels. These results indicate that temperature sensitivity of soil respiration could affect soil organic mater content and N availability in soil due to carbon availability. Also, light fraction would be useful indicator to evaluate decomposition rate of organic matter in soil under a short-term test.

Studies on Change of Organic Farming in Korea from ($1907{\sim}2007$) (한국 유기농업 100년($1907{\sim}2007$)의 변화에 관한 연구)

  • Lee, Hyo-Won;Yun, Jin-Hyeon
    • Korean Journal of Organic Agriculture
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    • v.15 no.4
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    • pp.399-411
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    • 2007
  • Korean organic farming has been well developed over the last two decades. It demonstrates that the number of certificated farm for organic agriculture and products have been drastically increased in recent year. However, the organic farmers have thought that organic farming rely only on organic fertilizer and they don't keep organic farming principle in which organic farmer should enhance biological activity and crop rotation. This study was to compare nutrient input, recommendation, cropping system and organic product circulation between the early $20^{th}$ century and beginning of the $21^{st}$ century. The population of Korea has increased 7.3 times more than that of a century ago but cultivated land has been decreased during 100 years. The rice production in 2002 was 4.2 times higher than that of production in 1912. The input of N, P and K in 1907 on the basis of King's suggestion was 95.6kg/ha, 15.9kg/ha and 3.0kg/ha, respectively. Nitrogen came from excreta (40%), green manure (55%) and compost (5%) in the early 20th century. On the other hand, organic farmer input organic resources such as wood chip (30.1%), compost (27.8%), rice straw (14%) and others (25%) these days. In terms of nutrient balance calculated nutrient and absorption by plants, organic rice farmer apply excessive nitrogen and phosphorus to the soil. They was used to put $7{\sim}10$ times more nitrogen than that of a century ago. Nutrient recommendation was similar in N and P between early 20th century and early $21^{st}$ century. Farmers in both century did not rotate crops in the field. Today, organic farmers engaged in more continuous cultivation than in early 20th century. Farmers in the early $20^{th}$ century produced locally, consumed locally the agricultural products, but organic farmers in the $21^{st}$ century produce the organic product in the local farmland and consumed in the large city and also a lot of foreign organic products have been imported in recent year.

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