• Title/Summary/Keyword: organic/inorganic agents

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Development of Anti-Fingers Printed EGI Steel Sheet With High Corrosion Resistance (고내식성 내지문 EGI 강판 개발)

  • 김형준
    • Journal of Surface Science and Engineering
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    • v.26 no.6
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    • pp.307-315
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    • 1993
  • A study on a new anti-finger printed EGI steel sheet with high corrosion resistance has been carried out to meet the recent requirement of high quality and performance of the pure zinc electrogalvanized steel sheet. The substrate was the pure zinc electrogalvanized sheet with the metallic coating of 20g/$\m^2$. The two differ-ent processes for inorganic(chromating) and organic(resin) coating were applied. One was a two coat/two bake type to separately treat chromating and resin coating which is now widely used. The other was a one coat/one bake type to simultaneously treat them which is newly developed in this study. The solution for the one coat/one bake type was an aqua-base coating agents which was composed of inorganic and organic components. The new anti-finger printed EGI steel sheet with the Cr and resin coating weight of 13mg/$\m^2$ and 800mg/$\m^2$, respectively shows the superior corrosion resistance besides the good paintability, formability fingerprint resistance and earth characteristics properties.

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Antimicrobial Property for Durability of Cleaner using Inorganic Antimicrobial Agent Containing Zirconium (Zr함유 무기물 항균제를 사용한 클리너 제품의 항균내구성)

  • Koo, Kang;Ma, Jae-Hyuk;Hong, Tae-Il
    • Textile Coloration and Finishing
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    • v.23 no.4
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    • pp.257-262
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    • 2011
  • The dish cloth requires antimicrobial activity for hygienic purpose. Until now, organic antimicrobial agents of low cost have been frequently used for the anitimicrobial finishing. However, a cleaner hving anitimicroial activity should be more durable considering consumers' ever-increasing expectation. In this study, the cleaner containing the bamboo fiber were finished with a formulation of a new zirconium-containing inorganic agent of zirconium phosphate and polyurethane binders. The optimum treatment condition was investigated. And its durability against repeated laundering cycles was assessed. The existence of Zr after the repeated laundering was verified and the antimicrobial effect did not decrease under 30 washing cycles.

Nutritional Effects on the Environmental Health (영양과 환경과의 관계)

  • 문현경
    • Journal of environmental and Sanitary engineering
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    • v.6 no.2
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    • pp.17-31
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    • 1991
  • The effects of environmental agents on health are great concern for all. It was recognized that each human has differential susceptibility to environmental effects. Susceptibility are changed by many factors includin gdevelopmpntal processes, genetic factors, nutritional stratus, preexisting disease conditions, life style and personal habits. Of all factors nutritional factors seem to be the area most modifiable. Consequently, It is an area that must be more thoroughly evaluated. In this paper, nutrient and environment interactions are reviewed briefly with published literatures. This paper deals with the influence of micronutrients(energy, protein and fat), Vitamins (vitamin 4, vitamin B-complex, vitamin C, vitamin D and vitamin I) and Minerals(calcium, iron, selenium, zinc and other minerls) on environmental effects. The role of arch nutrient was assessed in modifyine the expression of environmental pollutant toxicity with available litertures. In each nutrient section, the effect of environment was considered in following agents : heavy metals(lead, cadmium, mercury, silver and etc), inorganic agents(nitwits, sulfite, fluoride and etc), organic agents(benzene, carbon tatra-chloride, aflatoxin, auto dye, dialbrin etc), Irritant gas(ozone, carbon monooxide and etc), physical agents(X-irradiation, ultra violet, temperature and noise) and insectcides. The extent to which nutritional status modifies environmental effects 3nd its converse, how envirollments affects nutritional status is very complex. In deed, at the present time there are more than 50 chelnical/phycical agents that affect the nutrient metabolism and/or have their toxicity either directly diminished or enhanced by nutrients of those agents, small number of agents for each nutrients have sufficient evidence to warrant any reasonable degree of confidence in their hypothesized associtation. With these information at this present time it is hard to conclude that the recommended dietary allowance for each nutrient should be reconsidered.

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Effect of Kaolinite Treated with Silane Coupling Agent on the Reinforcement of SBR (SBR에 대한 Silane Coupling Agent 처리한 Kaolinite의 보강효과에 관한 연구)

  • Kim, Ki-Joo;Kim, Jong-Seok;Ahn, Byung-Kook;Choi, Hyoung-Jin;Chang, Young-Jae
    • Elastomers and Composites
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    • v.25 no.4
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    • pp.280-290
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    • 1990
  • The effect of surface treatment of kaolinite with silane coupling agent on the reinforcement of SBR was investigated. The possibility of the practical use of kaolinite as an organic filler was also scrutinized and it was found that the reinforcement of SBR was improved by modifying surface of the cheap inactive inorganic filler with organic silane coupling agents. 3-Chloropropyltrimethoxysilane(C-series), 3-mercaptopropyltrimethoxysilane(M-series) and 3-aminopropyltriethoxysilane(A-series) were used as coupling agents. To test the material properties of vulcanized and unvulcanized SBR, Mooney viscosity, modulus, elongation and fractured surface measurements by SEM were carried out by changing the amount of silane coupling agents. Torqe of the unvulcanized SBR following the measurement of the degree of vulcanization was to be increased as the amount of silane was increasing, and Mooney viscosity of M-series and A-series was also increased.

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The Characteristic of PU/MWNT Foaming Film (PU/MWNT 발포필름의 발포 특성연구)

  • Park, Jun-Hyeong;Park, Mi-Ra;Choi, La-Hee;Kim, Seung-Jin
    • Textile Coloration and Finishing
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    • v.24 no.1
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    • pp.79-90
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    • 2012
  • This study surveys the characteristics of the PU/MWNT foaming film according to foaming conditions. For this purpose, firstly, 16 kinds of PU/MWNT forming films were prepared with 4 kinds of dispersion solutions (IPA/MWNT, DMF/MWNT, MEK/MWNT, and Toluene/MWNT) and 4 kinds of blowing agents (organic I, organic II, capsule, and inorganic). The electrical resistivity of these PU/MWNT foaming films according to the dispersion solutions and blowing agents were analysed and discussed with surface profile and cell morphology of measured by SEM. And secondly, 24 kinds of PU/MWNT foaming films were also prepared with 2 kinds of IPA dispersion solution contents and 3 kinds of blowing agents with variation of the blowing temperatures and film thickness. The physical properties of the PU/MWNT foaming films such as electrical resistivity (surface and volume) and triboelectricity with cell morphology were measured and discused through the quantities of IPA, blowing agent added and also physical conditions(temperature, thickness so on) for establishing optimum foaming conditions with good electrostatic dissipation.

Synthesis of Organic-Inorganic Nanohybrids Using Epoxy-Functionalized Alkoxysilane and Their Properties (Epoxy-Functionalized Alkoxysilane을 이용한 Organic-Inorganic Nanohybrids합성과 물성)

  • Kim, Bo-Young;Kim, Juyoung
    • Journal of Adhesion and Interface
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    • v.15 no.2
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    • pp.69-76
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    • 2014
  • Two kinds of epoxy-functionalized alkoxysilane (EAS) compounds (EAS-MS and EAS-ES) were successfully synthesized through the reaction between epoxy resin (YD-128) and aminopropyl trimethoxysilane (APTMS) or aminopropyl triethoxysilane (APTES). By the hydrolysis-polycondensation reaction of EAS compounds with 3-Glycidyloxypropyl trimethoxysilane (GPTMS) and Tetraethyl orthosilicate (TEOS), silica/epoxy nanohybrids could be prepared at various compositions of EAS to GPTMS/TEOS. Prepared nanohybrids were yellow transparent and miscible with various organic solvents. By the reaction silica/epoxy nanohybrids with curing agents (TETA or acrylic acid), cured hybrids films could be obtained. These cured films showed higher thermal stability and mechanical property compared to cured neat epoxy resin. TEM and AFM images showed formation of nano-sized silica nanoparticles within cured hybrid films.

Preparation and Characterization of Photochromic Organic-Inorganic Hybrid Coating Using 1,2-Bis(2,4-dimethyl-5-phenyl-3-thienyl)3,3,4,4,5,5-hexafluoro-1-cyclopentene (1,2-Bis(2,4-dimethyl-5-phenyl-3-thienyl)-3,3,4,4,5,5-hexafluoro-1-cyclopentene을 사용한 유-무기 혼성 광 변색 코팅 막의 제조 및 특성)

  • Lee, Chang-Ho;Lee, Sang-Goo;Lee, Jong-Dae
    • Polymer(Korea)
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    • v.36 no.1
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    • pp.16-21
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    • 2012
  • Organic-inorganic hybrid coating film using 1,2-bis(2,4-dimethyl-5-phenyl-3-thienyl)-3,3,4,4,5,5-hexafluoro-1-cyclopentene (BTHFC) as a photochromic material was prepared under various reaction conditions such as the amounts of tetramethoxysilane (TMOS), various silane coupling agents, and solvent. It was found that color-fading speed and absorbance of the coating film was strongly dependent upon the polarity of silane coupling agent and solvent. In addition, the mole ratio of TMOS and methacryloyloxypropyltrimethoxysilane (MPTMS) was an important factor to determine color-fading speed and absorbance of the coating film. With increasing TMOS contents in coating film, the pencil hardness was increased. On the other hands, the transmittance of coating film was relatively decreased with the increase of TMOS.

Contrast Effect of Citric Acid and Ethylenediaminetetraacetic Acid on Cadmium Extractability in Arable Soil

  • Lee, Hyun Ho;Hong, Chang Oh
    • Korean Journal of Soil Science and Fertilizer
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    • v.48 no.6
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    • pp.634-640
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    • 2015
  • Chelating agents have been proposed to improve the efficiency of phytoextraction of heavy metal hyperaccumulator. However, little studies to elucidate mechanism of chelating agents to increase cadmium (Cd) extractability have been conducted. The objectives of this study were to evaluate effect of different chelating agents on Cd extractability and to determine mechanism of Cd mobilization affected by these agents. An arable soil was spiked with inorganic Cd ($CdCl_2$) to give a total Cd concentration of $20mgCdkg^{-1}$. Ethylenediaminetetraacetic acid (EDTA) and citric acid (CA) were selected and mixed with the arable soil at the rates of 0 and $5mmolkg^{-1}$. The mixture soils were incubated at $25^{\circ}C$ for 4 weeks in dark condition. Concentration of F1 Cd fractions (water soluble) significantly increased with addition of EDTA but did not changed with addition of CA. Especially; concentration of F5 Cd fractions (residual) significantly increased with addition of CA. Increase in water soluble with EDTA might be attributed to complexation of Cd and EDTA. Dissolved organic carbon concentration significantly increased with EDTA addition, but did not with CA implying that considerable amount of CA was decomposed to inorganic carbon by microorganism. Log activity of carbonate ($CO_3{^{2-}}$) which might be generated from CA increased with addition of CA. Increase in residual Cd fraction might be due to precipitation of Cd as $CdCO_3$. As a result, EDTA was effective in increasing Cd extractability, by contrast CA had significant effect in reducing Cd extractability.

Evaluation of dissolution characteristics of magnetite in an inorganic acidic solution for the PHWR system decontamination

  • Ayantika Banerjee ;Wangkyu Choi ;Byung-Seon Choi ;Sangyoon Park;Seon-Byeong Kim
    • Nuclear Engineering and Technology
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    • v.55 no.5
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    • pp.1892-1900
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    • 2023
  • A protective oxide layer forms on the material surfaces of a Nuclear Power Plant during operation due to high temperature. These oxides can host radionuclides, the activated corrosion products of fission products, resulting in decommissioning workers' exposure. These deposited oxides are iron oxides such as Fe3O4, Fe2O3 and mixed ferrites such as nickel ferrites, chromium ferrites, and cobalt ferrites. Developing a new chemical decontamination technology for domestic CANDU-type reactors is challenging due to variations in oxide compositions from different structural materials in a Pressurized Water Reactor (PWR) system. The Korea Atomic Energy Research Institute (KAERI) has already developed a chemical decontamination process for PWRs called 'HyBRID' (Hydrazine-Based Reductive metal Ion Decontamination) that does not use organic acids or organic chelating agents at all. As the first step to developing a new chemical decontamination technology for the Pressurized Heavy Water Reactor (PHWR) system, we investigated magnetite dissolution behaviors in various HyBRID inorganic acidic solutions to assess their applicability to the PHWR reactor system, which forms a thicker oxide film.

Effects of inorganic fluosilicate agent on the properties of concrete (규불화염계 혼화제가 콘크리트의 물성에 미치는 영향)

  • Lee, Sang-Ho;Moon, Han-Young
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.9 no.3
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    • pp.187-194
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    • 2005
  • This paper deals with a waterproof and mechanical feature of concrete using an inorganic self waterproof agent. The waterproof agents having been used in our country were a membrane agent, penetration agent and an organic waterproof agent. However, these agents have a lot of problems such as losing the effect of waterproof in the environment of lots of water, the difficulty of dispersion. For the clear of problems of these water -proof agents, we used the inorganic waterproof agent. This agent was made from inorganic fluosilicate. Generally, a waterproof agent has been used only for the waterproof effect. In this paper, however through the some tests of concrete using the inorganic self waterproof agent, we recognized that the concrete using the agent is more excellent in some peculiar properties than general concrete's properties. In this paper, we performed compressive strength, permeability, pore volume test, etc. As a result, the concrete of using the agent is more excellent in economy, waterproof, compressive strength.