폴리머 (Polymer(Korea))

  • 제36권1호
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  • Pages.16-21
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  • 2012
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  • 0379-153X(pISSN)
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  • 2234-8077(eISSN)
한국고분자학회 (The Polymer Society of Korea)
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DOI QR코드

DOI QR Code

1,2-Bis(2,4-dimethyl-5-phenyl-3-thienyl)-3,3,4,4,5,5-hexafluoro-1-cyclopentene을 사용한 유-무기 혼성 광 변색 코팅 막의 제조 및 특성

Preparation and Characterization of Photochromic Organic-Inorganic Hybrid Coating Using 1,2-Bis(2,4-dimethyl-5-phenyl-3-thienyl)3,3,4,4,5,5-hexafluoro-1-cyclopentene

  • 이창호 (충북대학교 화학공학과, 충북대학교 산업과학기술연구소) ;
  • 이상구 (한국화학연구원 그린화학연구단) ;
  • 이종대 (충북대학교 화학공학과, 충북대학교 산업과학기술연구소)
  • Lee, Chang-Ho (Department of Chemical Engineering, Research Institute of Industrial Science & Technology, Chungbuk National University) ;
  • Lee, Sang-Goo (Division of Green Chemistry, Korea Research Institute of Chemical Technology) ;
  • Lee, Jong-Dae (Department of Chemical Engineering, Research Institute of Industrial Science & Technology, Chungbuk National University)
  • 투고 : 2011.05.06
  • 심사 : 2011.07.12
  • 발행 : 2012.01.25
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초록

광 변색 물질로 1,2-bis(2,4-dimethyl-5-phenyl-3-thienyl)-3,3,4,4,5,5-hexafluoro-1-cyclopentene(BTHFC)를 사용하는 유-무기 혼성 코팅막이 금속 알콕사이드인 tetramethoxysilane(TMOS), 다양한 실란 커플링제, 그리고 용매와 같은 다양한 반응 조건하에서 제조되었다. 제조된 코팅 막 중에서 상대적으로 비극성인 실린 커플링제를 사용한 경우, 광 변색 유기물인 BTHFC는 우수한 흡광도 및 소색속도를 나타내었다. 더욱이 용매 THF 존재 하에서 TMOS와 methacryloyloxypropyltrimethoxysilane(MPTMS)의 몰 비가 1:1로 하여 제조되었을 때 흡광도와 소색속도는 크고 빠른 것을 알 수 있었다. 연필강도는 TMOS의 함량이 증가할수록 증가한 반면, 투과도는 상대적으로 감소하였다.

Organic-inorganic hybrid coating film using 1,2-bis(2,4-dimethyl-5-phenyl-3-thienyl)-3,3,4,4,5,5-hexafluoro-1-cyclopentene (BTHFC) as a photochromic material was prepared under various reaction conditions such as the amounts of tetramethoxysilane (TMOS), various silane coupling agents, and solvent. It was found that color-fading speed and absorbance of the coating film was strongly dependent upon the polarity of silane coupling agent and solvent. In addition, the mole ratio of TMOS and methacryloyloxypropyltrimethoxysilane (MPTMS) was an important factor to determine color-fading speed and absorbance of the coating film. With increasing TMOS contents in coating film, the pencil hardness was increased. On the other hands, the transmittance of coating film was relatively decreased with the increase of TMOS.

키워드

참고문헌

  1. H. Cho, S. Y. Cho, Y. M. Kim, D. J. Jeon, and E. Kim, J. Kor. Soc. Imag. Sci. Technol., 8, 29 (2002).
  2. N. Sanz-Menez, V. Monnier, I. Colombier, P. L. Baldeck, M. Irie, and A. Ibanez, Dyes and Pigments, 89, 241 (2011). https://doi.org/10.1016/j.dyepig.2010.03.017
  3. M. Irie, Photo-reactive materials for ultrahigh-density optical memory, Elsevier, Amsterdam, 1994.
  4. J. C. Crano and R. J. Guglielmetti, Organic photochromic and thermochromic compound, Plenum, NY, 1999.
  5. E. K. Kim and M. H. Lee, Polymer(Korea), 29, 25 (2005).
  6. M. Mening, K. Fries, M. Lindenstruth, and H. Schmidt, Thin Solid Films, 351, 230 (1999). https://doi.org/10.1016/S0040-6090(99)00341-7
  7. J. K. Kim, M. J. Kim, S. J. Park, and B. K. Ryu, J. Kor. Cer. Soc., 43, 28 (2006). https://doi.org/10.4191/KCERS.2006.43.1.028
  8. R. Pardo, M. Zayat, and D. Levy, C. R. Chimie, 13, 212 (2010). https://doi.org/10.1016/j.crci.2009.05.006
  9. D. H. Kim and K. C. Song, News Inf. Chem. Eng., 26, 534 (2008).
  10. J. Biteau, F. Chaput, K. Lahlil, and J. P. Boilt, Chem. Mater., 10, 1945 (1998). https://doi.org/10.1021/cm980106h
  11. S. H. Jang, Polym. Sci. Tech., 12, 676 (2001).
  12. S. E. Yun, H. G. Woo, and D. P. Kim, Polymer(Korea), 24, 389 (2000).
  13. M. J. Han, J. Y. Maeng, and J. Y. Seo, Polymer(Korea), 34, 405 (2010).
  14. A. Jitianu, M. Gartner, M. Zaharescu, D. Cristea, and E. Manea, Mater. Sci. Eng., C23, 301 (2003).
  15. Y. Y. Yu and W. C. Chen, J. Mater. Chem., 82, 388 (2003). https://doi.org/10.1016/S0254-0584(03)00259-1
  16. J. D. Lee and C. H. Lee, J. Ind. Sci. Tech. Inst., 23, 7 (2009).
  17. D. Levy and D. Avir, J. Phys. Chem., 92, 4734 (1988). https://doi.org/10.1021/j100327a035
  18. D. Levy, Chem. Mater., 9, 2666 (1997). https://doi.org/10.1021/cm970355q
  19. M. Irie, Chem. Rev., 100, 1685 (2000). https://doi.org/10.1021/cr980069d
  20. K. Matsuda and M. Irie, J. Photochem. Photobiol., C5, 170 (2004).
  21. M. Irie, Supramol. Sci., 3, 87 (1996). https://doi.org/10.1016/0968-5677(96)00019-3
  22. C. J. Yun and E. Y. Kim, NICE, 26, 526 (2008).
  23. H. Cho, S. Y. Cho, Y. M. Kim, D. J. Jeon, and E. Kim, J. Kor. Soc. Imag. Sci. Technol., 8, 29 (2002).
  24. N. Khummalai and V. Boonamnuayvitaya, J. Biochem. Bioph. Methods, 99, 277 (2005).

피인용 문헌

  1. Preparation of UV-curable Ozone Resistance Coating Solutions using Fluoromonomer vol.50, pp.3, 2012, https://doi.org/10.9713/kcer.2012.50.3.421
  2. Mechanical properties of sol–gel coatings on polycarbonate: a review vol.75, pp.3, 2015, https://doi.org/10.1007/s10971-015-3781-6