• 제목/요약/키워드: ordered structure

검색결과 385건 처리시간 0.025초

Structure and Properties of TLCP/Polyester Composite Fibers

  • Kim, Jun-Young;Kim, Seong-Hun
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 2003년도 The Korea-Japan Joint Symposium
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    • pp.102-102
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    • 2003
  • TLCP/polyester composite fibers (TPCFs) based on melt blends of PEN, PET, and TLCP were prepared by melt blending and spinning process to achieve high performance fibers. Reinforcement effect and TLCP fibrillar structure resulted in improvement of mechanical properties for TPCFs. The increase in the apparent crystallite size was attributed to the development of larger crystallites and more ordered crystalline structures in the annealed TPCFs. Molecular orientation was an important factor to determine mechanical property of TPCFs.

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Ubiquitous Crisis and Renormalization Approach for e-commerce : Critical Phenomena and Emergence of Phase Transition ; Logarithmic convergence

  • Ito, Ken;Kazuomi;Fukuta, Takanari
    • 한국전자거래학회:학술대회논문집
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    • 한국전자거래학회 2004년도 e-Biz World Conference
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    • pp.89-97
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    • 2004
  • 1. Introduction; Fundamental Difference between conventional old commerce and e-commerce? 2. "Quantity changes into Quality"; Phase transition and Critical phenomena Logarithmic Convergence and Emergence of Quality 3. Networked Small World; Indications from Genomics; Power-Law Ordered Plain Structure of Super-Complex System ⇔ The Structure of e-Biz. 4. Uniquitous Crisis to Ubiquitous Critical Points for the Emergence of Qualified Business with e-strucrure

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AN ALGEBRAIC STRUCTURE INDUCED BY A FUZZY BI-PARTIALLY ORDERED SPACE I

  • JU-MOK OH
    • Journal of Applied and Pure Mathematics
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    • 제5권5_6호
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    • pp.347-362
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    • 2023
  • We introduce an algebraic structure induced by a fuzzy bipartial order on a complete residuated lattices with the double negative law. We undertake an investigation into the properties of fuzzy bi-partial orders, including their various characteristics and features. We demonstrate that the two families of l-stable and r-stable fuzzy sets can be regarded as complete lattices, and we establish that these two families are anti-isomorphic. Furthermore, we provide two examples related to them.

숙성조건 의한 메조포러스 SBA-15 실리카의 기공구조와 특성 (Characterization and Pore Structure of Ordered Mesoporous SBA-15 Silica by Aging Condition)

  • 김한호;박현;김경남
    • 한국재료학회지
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    • 제20권5호
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    • pp.252-256
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    • 2010
  • The study was done to change the morphology and pore size of SBA-15 silica, and the characteristics of SBA-15 silica were investigated with TG-DSC, XRD, SEM, TEM and N2 adsorption-desorption under changing aging conditions. SBA-15 silica having a 2D-hexagonal structure was synthesized and confirmed by SEM and TEM. The structure of mesoporus silica SBA-15 showed a pore having regularly formed hexagonal structure and a passage having a cylindrical shape. This result is in good agreement with the pore forming in XRD and cylindrical shape of the structure in $N_2$ adsorption-desorption isotherm. SBA-15 silica showed a large BET surface area of $603-698\;m^2/g$, a pore volume of $0.673-0.926\;cm^3/g$, a large pore diameter of 5.62-7.42 nm, and a thick pore wall of 3.31-4.37 nm. This result shows that as the aging temperature increases, the BET surface area, pore volume, and pore diameter increase but the pore wall thickness decreases. The BET surface areas in SM-2 and SM-3 are as large as $698\;m^2/g$. However, SM-2 has a large surface area and forms a thick pore wall, when the aging temperature is $100^{\circ}C$ and is synthesized into stable mesoporous SBA-15 silica.

SiGe Nanostructure Fabrication Using Selective Epitaxial Growth and Self-Assembled Nanotemplates

  • Park, Sang-Joon;Lee, Heung-Soon;Hwang, In-Chan;Son, Jong-Yeog;Kim, Hyung-Jun
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2009년도 춘계학술발표대회
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    • pp.24.2-24.2
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    • 2009
  • Nanostuctures such as nanodot and nanowire have been extensively studied as building blocks for nanoscale devices. However, the direct growth of the nanostuctures at the desired position is one of the most important requirements for realization of the practical devices with high integrity. Self-assembled nanotemplate is one of viable methods to produce highly-ordered nanostructures because it exhibits the highly ordered nanometer-sized pattern without resorting to lithography techniques. And selective epitaxial growth (SEG) can be a proper method for nanostructure fabrication because selective growth on the patterned openings obtained from nanotemplate can be a proper direction to achieve high level of control and reproducibility of nanostructucture fabrication. Especially, SiGe has led to the development of semiconductor devices in which the band structure is varied by the composition and strain distribution, and nanostructures of SiGe has represented new class of devices such nanowire metal-oxide-semiconductor field-effect transistors and photovoltaics. So, in this study, various shaped SiGe nanostructures were selectively grown on Si substrate through ultrahigh vacuum chemical vapor deposition (UHV-CVD) of SiGe on the hexagonally arranged Si openings obtained using nanotemplates. We adopted two types of nanotemplates in this study; anodic aluminum oxide (AAO) and diblock copolymer of PS-b-PMMA. Well ordered and various shaped nanostructure of SiGe, nanodots and nanowire, were fabricated on Si openings by combining SEG of SiGe to self-assembled nanotemplates. Nanostructure fabrication method adopted in this study will open up the easy way to produce the integrated nanoelectronic device arrays using the well ordered nano-building blocks obtained from the combination of SEG and self-assembled nanotemplates.

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Structure and Electrochemical Behavior of Aromatic Thiol Self-Assembled Monolayers on Au(111)

  • Noh, Jae-geun;Park, Ha-jung;Jeong, Young-do;Kwon, Seung-wook
    • Bulletin of the Korean Chemical Society
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    • 제27권3호
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    • pp.403-406
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    • 2006
  • The surface structure and electrochemical behavior of self-assembled monolayers (SAMs) formed by aromatic thiols on Au(111) were investigated by scanning tunneling microscopy (STM) and cyclic voltammetry. Benzenethiol (BT) forms disordered phases on Au(111) which are composed of many bright domains, while benzyl mercaptan (BM), with a methylene unit between the aromatic group and sulfur atom, forms twodimensional ordered SAMs on Au(111). In addition, two phase-separated domains consisting of disordered and ordered phases were observed in binary SAMs formed from a 1 : 1 mixed ethanol solution of BT and BM. From STM and CV measurements, we found that the blocking efficiency of aromatic thiol SAMs coated on an Au(111) electrode for an electron transfer reaction decreases as the structural order of the SAMs increases. Molecular-scale STM and CV results obtained here will be very useful in designing functional SAMs for further applications, such as the improvement of corrosion passivation of Au(111) on an aromatic thiolmodified Au(111) surface.

Phase Transition of Octaneselenolate Self-assembled Monolayers on Au(111) Studied by Scanning Tunneling Microscopy

  • Choi, Jung-Seok;Kang, Hun-Gu;Ito, Eisuke;Hara, Masahiko;Noh, Jae-Geun
    • Bulletin of the Korean Chemical Society
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    • 제32권8호
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    • pp.2623-2627
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    • 2011
  • We investigated the surface structure and wetting behavior of octaneselenolate self-assembled monolayers (SAMs) on Au(111) formed in a 50 ${\mu}M$ ethanol solution according to immersion time, using scanning tunneling microscopy (STM) and an automatic contact angle (CA) goniometer. Closely-packed, well-ordered alkanethiol SAMs would form as the immersion time increased; unexpectedly, however, we observed the structural transition of octaneselenolate SAMs from a molecular row phase with a long-range order to a disordered phase with a high density of vacancy islands (VIs). Molecularly resolved STM imaging revealed that the missing-row ordered phase of the SAMs could be assigned as a $(6{\times}{\surd}3)R30^{\circ}$ superlattice containing three molecules in the rectangular unit cell. In addition, CA measurements showed that the structural order and defect density of VIs are closely related to the wetting behaviors of octaneselenolate SAMs on gold. In this study, we clearly demonstrate that interactions between the headgroups and gold surfaces play an important role in determining the physical properties and surface structure of SAMs.

Patterned Surfaces in Self-Organized Block Copolymer Films with Hexagonally Ordered Microporous Structures

  • Hayakawa Teruaki;Kouketsu Takayuki;Kakimoto Masa-alki;Yokoyama Hideaki;Horiuchi Shin
    • Macromolecular Research
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    • 제14권1호
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    • pp.52-58
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    • 2006
  • A novel fabrication of the patterned surfaces in the polymer films was demonstrated by using the self-organizing character of the block copolymers of polystyrene-b-oligothiophenes and polystyrene-b-aromatic amide dendron. Hexagonally arranged open pores with a micrometer-size were spontaneously formed by casting the polymer solutions under a moist air flow. The amphiphilic character of the block copolymers played the crucial role as a surfactant to stabilize the inverse emulsion of water in the organic solvent, and subsequently the aggregated structure of the hydrophilic oligothiophene or aromatic amide dendron segments remained on the interiors of the micropores. The chemical composition on the top of the surface of the microporous films was characterized by energy-filtering transmission electron microscopy (EFTEM) or a time-of-flight secondary ion mass spectrometer (ToF-SIMS). The characterizations clearly indicated that the patterned surfaces in the self-organized block copolymer films with the hexagonally ordered microporous structures were fabricated in a single step.

의사 랜덤치환을 이용한 다중레벨 키분배 (A Multilevel Key Distribution using Pseudo - random Permutations)

  • 김주석;신원;이경현
    • 한국정보처리학회논문지
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    • 제4권10호
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    • pp.2493-2500
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    • 1997
  • 대칭키 관리 시스템에서 계층적 구조를 지닌 다중 사용자 그룹에 대한 새로운 키관리 방안을 제안한다. 제안된 방식은 의사 랜덤치환에 의해 새성되는 트랩도어 일방향 치환을 이용하며, 구현시 시간과 공간적 측면에서 유리하기 때문에, 완전순서 집합과 부분순서가 있는 집합으로 구성되는 다단계 계층적 구조에 사용 가능하다. 또한, 다른 제안 방식과 비교하여 성능을 분석하고, 제안 방식이 키생성 시간과 키저장 크기에서 보다 효율적인 것을 보인다.

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Precipitation Behaviors of Hydroxyapatite on Highly Ordered Nanotubular Ti-35Ta-xNb Alloy Surface

  • Jo, Chae-Ik;Eun, Sang-Won;Choe, Han-Cheol
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2013년도 춘계학술대회 논문집
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    • pp.81-82
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    • 2013
  • In this study, precipitation behaviors of hydroxyapatite on highly ordered nanotubular Ti-35Ta-xNb alloy surface were researched. Ta and Nb additions to Ti increased corrosion resistance. The surface characteristics of anodized alloy depended on the nanotube formed voltage and alloy element. The HA precipitation morphology was influenced by nanorubular structure of alloys.

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