• 제목/요약/키워드: optimum mixture ratio

검색결과 346건 처리시간 0.025초

자체반응열 고온합성법을 이용한 Titanium Carbonitride의 합성에 관한 연구 (A Study on the Synthesis of Titanium Carbonitride by SHS(Self-propagating High-temperature Synthesis) Method)

  • 하호;황규민;이희철
    • 한국세라믹학회지
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    • 제31권6호
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    • pp.637-642
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    • 1994
  • Using SHS(Self-propagating High-temperature Synthesis) method, the optimum synthetic condition of titanium carbonitride was established by controlling the parameters such as relative density of mixture (Ti+C), nitrogen pressure, additive amounts of titanium hydride(TiH1.924) and protecting heat loss. Under 1 atm nitrogen pressure, nitridation ratio with changing relative density of the sample compacts has a maximum (87.2%) at about 55%, and in the case of enveloping the pellet with a quartz tube, the highest nitridation ratio of 90% was obtained at about 68%. At relative density of 55%, nitridation ratio with the nitrogen pressure has a miximum (87.3%) at 7 atm. As the amounts of additive titanium hydride increased, nitridation ratio decreased at below 7 atm nitrogen pressure and, increased at above this pressure until percent of addition percent reached 15 wt% and decreased abruptly upon futher increases in titanium hydride. In the synthesis of TiCxNy by combustion reaction, heat transfer from combustion zone to preheating zone and nitrogen gas penetration into the compact were found to be important factors affecting the TiCxNy formation. It was difficult to obtain high nitridation ratio when the conbustion temperature was either too high or too low, and it seems that the retention of high temperature after a combustion wave sweeped through the reactant mixture pellet is critical to obtain a satisfactory nitridation ratio.

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Ammonium and Nitrate Uptake and Utilization Efficiency of Rice varieties as Affected by Different N-Concentrations

  • Choi Kyung-Jin;Swiader John M.
    • 한국작물학회지
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    • 제50권1호
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    • pp.22-27
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    • 2005
  • To find out the optimum mixture ratio of ammonium and nitrate on rice plant, 4 rice varieties were examined during 14days after transplanting in hydroponics with the different ratio of ammonium to nitrate(100 : 0, 75: 25,50: 50, 25: 75 and 0: 100). The highest N uptake from solution and the maximum plant dry weight were $60\~70\%$ ammonium and $30\~40\%$ nitrate mixture treatment both in Japonica and Tongil type rice plants. And with the same varieties N-uptake and N use-efficiency were compared between 10.0 mM and 1.0 mM nitrogen using $70\%$ ammonium and $30\%$ nitrate for 24 days after transplanting. Rice plants absorbed more nitrogen$(131\~145\%)$ in 10.0mM than 1.0mM treatment but accumulated N in rice plants were almost the same in both treatment. Among the tested rice cultivars, dry matter production and total accumulative nitrogen in rice plants were much high in Tongil type than japonica type rice cultivars. N-recovery ratios of rice plants from uptake N were $90.8-99.0\%$ in low concentration N solution(1.0 mM), but $69.4-81.7\%$ were observed in high concentration N solution(10.0 mM). It means that suppling low concentration N steadily will be better to prevent loss of N without reducing of growth in rice plants.

Experimental tensile test and micro-mechanic investigation on carbon nanotube reinforced carbon fiber composite beams

  • Emrah Madenci;Yasin Onuralp Ozkilic;Ahmad Hakamy;Abdelouahed Tounsi
    • Advances in nano research
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    • 제14권5호
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    • pp.443-450
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    • 2023
  • Carbon nanotubes (CNTs) have received increased interest in reinforcing research for polymer matrix composites due to their exceptional mechanical characteristics. Its high surface area/volume ratio and aspect ratio enable polymer-based composites to make the most of its features. This study focuses on the experimental tensile testing and fabrication of carbon nanotube reinforced composite (CNTRC) beams, exploring various micromechanical models. By examining the performance of these models alongside experimental results, the research aims to better understand and optimize the mechanical properties of CNTRC materials. Tensile properties of neat epoxy and 0.3%; 0.4% and 0.5% by CNT reinforced laminated single layer (0°/90°) carbon fiber composite beams were investigated. The composite plates were produced in accordance with ASTM D7264 standard. The tensile test was performed in order to see the mechanical properties of the composite beams. The results showed that the optimum amount of CNT was 0.3% based on the tensile capacity. The capacity was significantly reduced when 0.4% CNT was utilized. Moreover, the experimental results are compared with Finite Element Models using ABAQUS. Hashin Failure Criteria was utilized to predict the tensile capacity. Good conformance was observed between experimental and numerical models. More importantly is that Young' Moduli of the specimens is compared with the prediction Halpin-Tsai and Mixture-Rule. Although Halpin-Tsai can accurately predict the Young's Moduli of the specimens, the accuracy of Mixture-Rule was significantly low.

Effect of Glycols and Catalysts on Cotton Fabrics Treated with Glyoxal

  • Lee, Eui-So;Kim, Seung-Il
    • Fibers and Polymers
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    • 제5권3호
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    • pp.230-233
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    • 2004
  • The optimum conditions for durable press treatment of cotton fabrics using glyoxal as a nonformaldehyde crosslinking agent were investigated. Crosslinking reaction was conducted in the presence of different catalysts such as aluminum sulfate, magnesium chloride, or magnesium chloride-citric acid mixture at various mole ratios of catalyst to glyoxal. Aluminum sulfate was proven the most effective one among those used. Glycol addition into a glyoxal padding bath increased the wrinkle recovery angle(WRA) and whiteness of treated fabrics. The optimum mole ratio of glycol to glyoxal was 1:1. Diethylene glycol addition produced better overall performance to the glyoxal-crosslinked fabric compared to ethylene glycol addition.

Simple Detection Based on Soft-Limiting for Binary Transmission in a Mixture of Generalized Normal-Laplace Distributed Noise and Gaussian Noise

  • Kim, Sang-Choon
    • ETRI Journal
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    • 제33권6호
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    • pp.949-952
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    • 2011
  • In this letter, a simplified suboptimum receiver based on soft-limiting for the detection of binary antipodal signals in non-Gaussian noise modeled as a generalized normal-Laplace (GNL) distribution combined with Gaussian noise is presented. The suboptimum receiver has low computational complexity. Furthermore, when the number of diversity branches is small, its performance is very close to that of the Neyman-Pearson optimum receiver based on the probability density function obtained by the Fourier inversion of the characteristic function of the GNL-plus-Gaussian distribution.

반응표면분석을 이용한 녹차와 애엽 혼합물의 추출조건 최적화 (Optimization of Extraction Conditions for Mixture of Camellia sinensis L. and Artemisia argyi by Response Surface Methodology)

  • 김영현;김우식;김재민;최선일;정태동;이진하;김종대;임재각;이옥환
    • 한국식품위생안전성학회지
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    • 제31권4호
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    • pp.278-285
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    • 2016
  • 본 연구는 초음파 진동에 의해 발생하는 공동현상을 이용하여 다양한 유용성분과 생리활성을 가지고 있는 녹차와 애엽을 혼합하여 새로운 식품소재를 개발하기 위해서 반응표면분석법에 의한 추출특성을 모니터링 하여 최적 추출조건을 예측하였다. 초음파를 지속적으로 가하는 조건에서 Box-Behnken design에 의해 녹차와 애엽의 혼합비, 용매와 용질의 비, 추출시간을 독립변수로 하여 15구간의 추출조건을 설정하고 추출수율(Y)을 종속변수로 하여 모니터링 하였다. 반응표면분석결과 녹차 및 애엽 혼합 추출물은 녹차의 함량과 추출용매의 양이 증가 할수록 추출수율이 증가 하였으며, 추출시간은 결과에 큰 영향을 주지 않는 것으로 나타났다. 추출수율을 최대로 얻을 수 있는 녹차 및 애엽 혼합물의 최적 추출조건은 녹차와 애엽의 혼합비 85.86%, 용매와 용질의 비 92.73 mL/g, 추출시간 56.52분으로 확인되었으며, 추출수율의 최대값은 30.03%로 예측되었다.

어린 보릿잎을 첨가한 키위잼 재료 혼합비율의 최적화 (Optimization of the Ingredient Mixing Ratio for Preparation of Kiwifruit (Actinidia deliciosa) Jam Prepared with added Barley Sproutling Powder)

  • 장명숙
    • 한국식품조리과학회지
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    • 제25권2호
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    • pp.234-242
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    • 2009
  • This study was performed to find the optimum ratio of ingredients for the manufacture of kiwifruit jam. The experiment was designed according to the D-optimal design of RSM (response surface methodology), which included 18 experimental points with 4 replicates for three independent variables (sugar $35{\sim}60%$, pectin $0.1{\sim}1.0.%$, kiwifruit paste $0.37{\sim}0.90%$). The compositional and functional properties of the prepared products were measured, and these values were applied to mathematical models. A canonical form and trace plot showed the influence of each variable on the quality attributes of the final product mixture. By use of the F-test, viscosity, color values (L, a, b), and sensory characteristics (color) were expressed by a linear model, while the L color value and select sensory characteristics (smell, taste, overall acceptance) were also expressed by a quadratic model. The optimum formulations by the numerical and graphical methods, were similar, and with the numerical method it presented as: sugar, pectin, and barley sproutling powder at 49.7%, 0.5%, and 0.6%, respectively. The above results demonstrate the feasibility of preparing kiwifruit jam added with barley sproutling powder, and therefore, the commercialization of a kiwifruit jam marketed as a functional food is deemed possible.

부분적 예혼합 LPG/공기 화염에서 음향자진이 NOx 배출에 미치는 영향 (Effects of Acoustic Excitation on NOx Emission in Partially Premixed LPG/Air Flames)

  • 장준영;박성호;김태권
    • 한국자동차공학회논문집
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    • 제10권3호
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    • pp.77-84
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    • 2002
  • Measurements of NO and NOx emission of laminar partially premixed LPG/air flames with and without acoustic excitation are reported. The NOx emission at the tailpipe of a combustion chamber is determined by chemiluminescent analyser. The NOx measurements are taken in flames with several different center tube equivalance ratio( ø$\sub$o/), and overall equivalace ratio(ø$\sub$o/) for a fixed fuel flowrate. The NOx emission decrease to reach a minimum value at an optimum ø$\sub$c/ 2. Theø$\sub$c/ 2 flame gives a compromise of thermal NO and prompt NO mechanism. In the case of excitation. the visual shape of the flame is changed from laminar flame to turbulent-like flame. With increasing levels of excitation amplitude, an optimum value of the NO and NOx emission exists. A shorter flame caused by the enhanced upstream mixing due to acoustic excitation results in the reduction of NO and NOx emission in the present flames. The reduction of flame length affects the shorter residence time of center tube mixture, and significantly influences the NOx reduction.

고품질의 청국장 생산 발효균주 선별 및 최적화 (Selection of Microorganisms and Optimization of Manufacture Process for Cheonggukjang)

  • 황현애;이남근;조일재;함영태;권기옥;김병용
    • 한국식품과학회지
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    • 제40권4호
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    • pp.406-411
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    • 2008
  • 본 연구는 청국장의 품질을 향상시키고 최적화시키기 위해 경기도 이천에서 높은 효소가를 가진 균주를 분리 동정하며 선택된 균주들을 이용하여 최적배합비를 산출하고자 하였다. 16S rDNA와 PCR을 이용하여 균주를 동정한 결과, 39개의 균주 대부분이 B. subtilis와 B. licheniformis이었으며 곰팡이는 검출되지 않았고 그 중 5개의 균주가 높은 역가를 나타내었다. 고품질의 장류생산 및 최적화 공정을 확립하기 위해 분리 동정한 균주중에서 amylase, protease, lipase와 cellulase의 활성이 높은 균주를 3개 선택하여 최적화 공정작업에 이용하였고 실험법에 의해 청국장을 제조하였다. 암모니아태질소, 선호도, 아미노태질소 및 항산화가에 근거를 두어 contour map과 numerical 최적화를 한 결과, 50%의 Bacillus sp. SC-l과 50% SC-3을 섞었을 때 최적의 청국장이 만들어졌다.

Synthesis of Isopropyldichlorosilane by Direct Process

  • Lim, Weon-Cheol;Cho, Joo-Hyun;Han, Joon-Soo;Yoo, Bok-Ryul
    • Bulletin of the Korean Chemical Society
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    • 제28권10호
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    • pp.1661-1664
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    • 2007
  • Direct reaction of elemental silicon with a gaseous mixture of isopropyl chloride (1) and hydrogen chloride in the presence of copper catalyst using a stirred bed reactor equipped with a spiral band agitator gave isopropyldichlorosilane having a Si-H bond (2a) as a major product and isopropyltrichlorosilane (2b) along with chlorosilanes, trichlorosilane and tetrachlorosilane. A process for production of 2a was maximized using the 1:0.5 mole ratio of 1 to HCl and smaller size of elemental silicon at a reaction temperature of 220 °C. When a reaction was carried out by feeding a gaseous mixture of 1 [12.9 g/h (0.164 mol/h)] and HCl [2.98 g/h (0.082 mol/h)] to a contact mixture of elemental silicon (360 g) and copper (40 g) under the optimum condition for 45 h, 2a among volatile products kept up about 82 mol % until 35 h and then slowly decreased down 68 mol % in 45 h reaction. Finally 2a was obtained in 38% isolated yield (based on 1 used) with an 85% consumption of elemental silicon in a 45 h reaction. In addition to 2a, 2b was obtained as minor product along with chlorosilanes, trichlorosilane, and tetrachlorosilane. The decomposition of 1 was suppressed and the production of 2a improved by adding HCl to 1.