• 제목/요약/키워드: optimum condition

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NdFeB계 영구자서 산화배소 스크랩의 초산침출에 의한 네오디뮴 회수 (Recovery of Neodymium from NdFeB Oxidation-Roasted Scrap by Acetic Acid Leaching)

  • 윤호성;김철주;김준수
    • 자원리싸이클링
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    • 제13권6호
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    • pp.43-48
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    • 2004
  • 본 연구는 NdFeB 영구자석 폐 스크랩 분말을 600$^{\circ}C$에서 산화배소한 후, 초산을 사용한 약산침출을 수행하여 네오디뮴을 선택적으로 분리하고자 하였다. 산화배소된 스크랩 분말의 초산침출 결과, 네오디뮴의 침출율 90% 이상을 얻기 위한 조건은 반응온도 80$^{\circ}C$, 반응시간 3시간 그리고 광액농도 35%이었다. 초산 침출용액으로부터 분별결정화에 의한 네오디뮴아세테이트 회수 시, 증발후 여액의 네오디뮴 조성은 243 g/l 네오디뮴아세테이트의 초산에 대한 용해도(260 g/l)에 근접하는 것을 알 수 있으며, 침출용액으로부터 네오디뮴아세테이트 결정회수를 위한 최적 조건은 온도 100$^{\circ}C$ 이상에서 초기 침출용액 부피에 대하여 약 1/5 정도 농축하는 것이 적절하였다. 이 때 침출용액 대비 약 67.5%의 네오디뮴을 분리하였으며, 농축여액에 잔존하는 나머지 네오디뮴은 옥살산과 반응시켜 전량 회수할 수 있었다.

엔드밀 가공시 진동, 표면거칠기, 절삭온도에 미치는 최적가공조건에 관한 연구 (The Study on the Optimal Working Condition for Vibration, Surface Roughness and Cutting Temperature in End-milling)

  • 홍도관;김동영;안찬우
    • 한국소음진동공학회논문집
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    • 제14권12호
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    • pp.1322-1329
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    • 2004
  • End-milling has been used widely in industrial system because it is effective to a material manufacturing with various shapes. Recently the end-milling processing is needed the high-precise technique with good surface roughness and rapid time in precision machine part and electronic part. The optimum mechanical vibration of main spindle, surface roughness and cutting temperature have an effect on end-milling condition such as, cutting direction, revolution of spindle, feed rate and depth of cut, etc. Therefore, this study carried to decide the working condition for optimum mechanical vibration of main spindle, surface roughness and cutting temperature using design of experiments, ANOVA and characteristic function. From the results of experimentation, mechanical vibration has an effect on revolution of spindle, radial depth of cut, and axial depth of cut. The surface roughness has an effect on cutting direction, revolution of spindle and depth of cut. And then the optimum condition used design of experiments is upward cutting In cutting direction, 600 rpm in revolution of spindle, 240 mm/min in feed rate, 2 mm in axial depth of cut and 0.25 mm in radial depth of cut. By design of experiments and characteristic function, it is effectively represented shape characteristics of mechanical vibration, surface roughness and cutting temperature in end-milling.

식물체 플라보노이드 성분 분석을 위한 적정 가수분해 조건 (Determination of Optimum Hydrolysis Conditions for Flavonoid Analysis in Plant Leaves)

  • 박진순;황인욱;정호철;김숙경;정신교
    • 한국식품저장유통학회지
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    • 제17권2호
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    • pp.261-266
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    • 2010
  • 식물체의 플라보노이드 성분 함량 분석에 필요한 적정 가수분해 조건을 구명하기 위하여 은행잎을 이용하여 중심합성법으로 설계한 산 가수분해 시간과 HCl 농도에 따라 myricetin, quercetin, kaempferol 함량을 HPLC로 분석하고, SAS의 반응표면분석법으로 산 가수분해 조건의 최적화를 시도하였다. HCl 0.5~2.5 M, 0.5~2.5시간 범위 내에서 10개의 구간을 잡아서 최적화한 결과 1.5~1.9 M의 HCl 농도와 1.4~2.0시간의 가수분해 조건에서 myricetin, quercetin, kaempferol 성분이 가장 높았다. Superimposing하여 구한 식물체의 플라보노이드의 적정 가수분해 조건은 HCl 1.5 M, 1.5시간이었으며, 이 조건에서 구한 플라보노이드 함량의 예측치와 측정치는 95% 이상 일치하였다. 본 연구에서 구한 적정 가수분해 조건을 이용하여 녹차잎, 무화과잎, 상동나무잎의 플라보노이드 함량을 분석하여 보았다.

고성능 쉴드 세그먼트용 고로슬래그 미분말을 혼입한 콘크리트의 역학적 특성 및 증기양생 효과 분석 (Mechanical characteristics of high-performance concrete shield segment containing ground granulated blast furnace slag and their improvement by steam curing)

  • 김병권;이진섭;이규필;장수호;배규진
    • 한국터널지하공간학회 논문집
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    • 제13권3호
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    • pp.233-242
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    • 2011
  • 본 연구에서는 쉴드터널에 사용되는 세그먼트의 성능향상과 경제성향상을 위하여 고로슬래그 미분말을 혼합한 고강도 콘크리트에 대한 기초 연구를 실시하였다. 특히, 설계강도가 60 MPa 세그먼트용 콘크리트에 대해서 고로슬래그 미분말의 최적 치환율과 최적의 증기양생 조건을 도출하고자 하였다. 이상의 결과로부터, 고로슬래그 치환율 50%와 단위수량 125 kg/$m^3$ 일 경우가 성능과 경제적인 측면에서 가장 적합한 배합조건으로 나타났다. 또한 표준양생 조건과 비교할 때 증가양생에 의하여 약 110~442%의 강도증진 효과를 기대할 수 있는 것으로 확인되었다.

초임계유체 추출에 의한 초피나무 과피 중 신미성분의 추출조건 (The extraction condition of pungent compounds from Zanthoxylum piperitum D.C pericarps by using supercritical fluid extraction)

  • 이창주;김명석;신경우;김용두;심재한
    • 한국약용작물학회지
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    • 제11권1호
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    • pp.19-23
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    • 2003
  • 초임계추출(SFE)를 이용한 초피나무 과피 중 신미성분의 최적추출조건을 조사하였다. 최적 추출 압력은 $300kg/cm^2$ 이었으며 온도는 $60^{\circ}C$, 추출 부피는 $12\;m{\ell}$, flow rate는 3m/min 그리고 modifier로 사용한 methanol의 함량비율은 20%였다. 추출시간은 초반 20분 안에 대부분의 신미성분이 추출되었다. 또한 용매추출법과 비교한 결과 추출효능이 약 40%정도 향상되었고 시간은 20분으로 단축되었으며 유기용매 methanol은 12 ml밖에 소요되지 않을 뿐만 아니라 주요한 추출용매로 무독성 액화$CO_2$를 사용하기에 독성 유기용매의 다량 사용을 피할 수 있는 친환경적이고 경제적인 방법으로 생각되어 진다.

유로코드를 이용한 주름웨브보의 최적설계 연구 (A Study on Optimum design of Corrugated web girder using Eurocode)

  • 손수덕;유미나;이승재
    • 한국공간구조학회논문집
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    • 제12권4호
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    • pp.47-56
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    • 2012
  • This paper describes the structural design and optimization of sinusoidally corrugated web girder by using EUROCODE (EN 1993-1-5). The optimum design methodology and characteristics of the optimal cross-section are discussed. We investigate a shear buckling and the concerned standards for corrugated web and explain the equations to obtain a critical stress according to buckling type. In order to perform optimization, we consider an objective function as minimum weight of the girder and use the constraint functions as slenderness ratio and stresses of flanges as well as corrugated web and deflection. Genetic Algorithm is adopted to search a global optimum solution for this mathematical model. For numerical example, the clamped girder under the concentrated load is considered, while the optimum cross-sectional area and design variables are analyzed. From the results of the adopted example, the optimum design program of the sinusoidally corrugated web girder is able to find the suitable solution which satisfied a condition subject to constraint functions. The optimum design shows the tendency to decrease the cross-sectional area with the yielding strength increase and increase the areas with load increase. Moreover, the corrugated web thickness shows a stable increase concerning the load.

프리스트레스트 콘크리트 거더 철도교의 최적설계 II: 동적안정성을 고려한 30m 지간의 최적단면 (Optimum Design of Prestressed Concrete Girder Railway Bridge II : Optimum Section with 30m Span Length Accounting for Dynamic Stability)

  • 이종민;김수현;정재동;이종선;조선규
    • 한국철도학회논문집
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    • 제9권1호
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    • pp.102-109
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    • 2006
  • The PSC girders which currently used at highway bridge have the standard cross sections about 25m, 30m and 35m span. Thus, in case of highway bridge design, the bridge designer can choose the adequate standard cross section according to constructional condition. However, in railway bridge design, there are limitations on reasonable bridge design considering circumstances of a construction site and conditions of location etc, because the PSC girders used at railway bridge have the cross section about only 25m span length. In this study, the optimum design for the PSC girder railway bridge with 30m span length has been performed. Also, in order to investigate the dynamic stability of railway bridge using the optimum section of PSC girder, dynamic analysis has been carried out. From the results of analysis, it is suggested to denote the optimum section which satisfied the structural safety, dynamic stability and economical efficiency all together.

파이프 골조온실의 원주형 콘크리트 기초의 인발저항력에 관한 연구 (A Study on the Uplift Capacity of Cylindrical Concrete Foundations for Pipe-Framed Greenhouse)

  • 윤용철;윤충섭;서원명;강만호
    • 한국농공학회지
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    • 제40권4호
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    • pp.109-119
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    • 1998
  • Recently pipe-framed greenhouses are widely constructed on domestic farm area. These greenhouses are extremely light-weighted structures and so are easily damaged under strong wind due to the lack of uplift resistance of foundation piles. This experiment was carried out by laboratory soil tank to investigate the displacement be haviors of cylindrical pile foundations according to the uplift loads. Tested soils were sampled from two different greenhouse areas. The treatment for each soil type are consisted of 3 different soil moisture conditions, 2 different soil depths, and 3 different soil compaction ratios. Each test was designed to be repeated 2 times and additional tests were carried out when needed. The results are summarized as follows : 1. When the soil moisture content are low and/or pile foundations are buried relatively shallow, ultimate uplift capacity of foundation soil was generated just after begining of uplift displacement. But under the high moisture conditions and/or deeply buried depth, ultimate up-lift capacity of foundation soil was generated before the begining of uplift displacement. 2. For the case of soil S$_1$, the ultimate uplift capacity of piles depending on moisture contents was found to be highest in optimum moisture condition and in the order of air dryed and saturated moisture contents. But for the case of soil S$_2$, the ultimate uplift capacity was found to be highest in optimum moisture condition and in the order of saturated and air dryed moisture contents. 3. Ultimate uplift capacities are varied depending on the pile foundation soil moisture conditions. Under the conditions of optimum soil moisture contents with 60cm soil depth, the ultimate uplift capacity of pile foundation in compaction ratio of 80%, 85%, and 90% for soil 51 are 76kg, 115kg, and 155kg, respectively, and for soil S$_2$are 36kg, 60kg, and 92kg, respectively. But considering that typical greenhouse uplift failure be occurred under saturnted soil moisture content which prevails during high wind storm accompanying heavy rain, pile foundation is required to be designed under the soil condition of saturated moisture content. 4. Approximated safe wind velosities estimated for soil sample S$_1$and S$_2$are 32.92m/s and 26.58m/s respectively under the optimum soil condition of 90% compaction ratio and optimum moisture content. But considering the uplift failure pattern under saturated moisture contents which are typical situations of high wind accompanying heavy rain, the safe wind velosities for soil sample S$_1$and S$_2$are not any higher than 20.33m/s and 22.69m/s respectively.

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Lycoris속(屬)의 종자발아(種子發芽) 특성(特性) 연구(硏究) (Studies on the Characteristics of Seed Germination of Lycoris genera)

  • 박윤점;정연옥
    • 한국약용작물학회지
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    • 제4권2호
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    • pp.163-171
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    • 1996
  • Lycoris의 종자발아(種子發芽) 특성(特性)을 구명(究明)하고자 온도(溫度), 채종시기(採種時期)와 파종시기(播種時期), 파종용토(播種用土)과 용토(用土)의 수분량(水分量) 및 광선(光線)의 유무(有無)가 종자발아(種子發芽)에 미치는 영향(影響)을 조사(調査)한 결과(結果)는 다음과 같다. 1. 백양꽃과 개상사화(想思花)는 90% 이상 결실(結實)하였고 종자성숙(種子成熟)은 $9{\sim}10$월 상순(上旬)으로 나타났는데 60% 이상의 발아율(發芽率)을 얻는데는 6개월이 소요되었다. 2. 발아적온(發芽適溫)은 $25^{\circ}C$로 나타났고 변온처리(變溫處理)는 $20,\;25^{\circ}C$에서 효과적(效果的)이었다. 3. 채종적기(採種適期)는 9월(月) 20일(日)경이었고 파종시기(播種時期)는 채종(採種) 즉시 파종(播種)하는 것이 가장 좋았다. 4. 파종용토(播種用土)은 사양토가 가장 좋았고 용토(用土)의 수분량(水分量)은 용토(用土) 400mg당 PF 1. 9가 가장 적당하였다. 4. 종자발아(種子發芽)는 암조건(暗條件)이 명조건(明條件)보다 좋은 것으로 나타났다.

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복합사이클 발전플랜트 폐열회수 보일러의 구성요소 크기비의 최적화 (Ratio Optimization Between Sizes of Components of Heat Recovery Steam Generator in Combined Cycle Gas Turbine Power Plants)

  • 인종수;이상용
    • 대한기계학회논문집B
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    • 제33권6호
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    • pp.403-410
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    • 2009
  • This paper proposes a new approach to find the optimum ratios between sizes of the heat exchangers of the heat recovery steam generator (HRSG) system with limited size to maximize the efficiency of the steam turbine (bottom) cycle of combined cycle power plants (CCPP), but without performing the bottom cycle analysis. This could be achieved by minimizing the unavailable exergy (the sum of the destroyed and the lost exergies) resulted from the heat transfer process of the HRSG system. The present approach is relatively simple and straightforward because the process of the trial-and-error method, typical in performing the bottom cycle analysis for the system optimization, could be avoided. To demonstrate the usefulness of the present method, a single-stage HRSG system was chosen and the optimum evaporation temperature was obtained corresponding to the condition of the maximum useful work. The results show that the optimum evaporation temperature based on the present exergy analysis appears similar to that based on the bottom cycle analysis. Also shown is the dependency of size (NTU) ratios between the heat exchangers on the inlet gas temperature, which is another important factor in determining the optimum condition once overall size of the heat recovery steam generator is given. The present approach turned out to be a useful tool for optimization of the singlestage HRSG systems and can easily be extended to multi-stage systems.