• Title/Summary/Keyword: optical conductivity

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$GeH_4$ 가스 함량에 따른 SiGe 박막의 특성변화

  • Jo, Jae-Hyeon;An, Si-Hyeon;Park, Hyeong-Sik;Jang, Gyeong-Su;Lee, Jun-Sin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.227-227
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    • 2010
  • 기존 실리콘 박막 태양 전지는 적외선에 대한 감응도와 흡수도가 낮아서 광흡수율을 증가시킬 경우 효율의 효과적인 개선이 기대되어진다. 이를 개선하기 위해서 밴드갭이 Si에 비해 상대적으로 낮은 Ge을 도입함으로써 Si와 Ge 화합물을 형성할 경우 결정상태와 수소 함유량에 따라 밴드갭 조절이 가능하다. 또한 Ge는 Si에 비해 빛에 대한 감응도가 우수하여 광흡수율을 증가시킬수 있다. 단 SiGe 박막의 Ge 량이 일정량이상 많아질 경우 박막 내 결함 등의 생성으로 광변환 효율이 오히려 감소하므로 Ge 량의 적정화가 필요하다. 본 실험에 사용된 SiGe:H Layer는 $SiH_4$ 가스와 $GeH_4$ 가스를 혼합하여 증착하였고 증착두께는 150nm로 고정하였으며 증착장비는 PECVD를 이용하였다. 파워는 플라즈마의 방전특성을 알아본 후 최소파워를 이용하여 증착하였다. 이는 증착 시 플라즈마에 의한 박막 손상을 최소화하기 위함이다. Ellipsometry를 이용하여 박막의 두께와 optical bandgap을 측정하였다. 박막의 특성을 평가하기 위해서 STA 장비를 이용하여 dark conductivity, photo conductivity, activation energy 등을 측정하였고, MDC를 이용해 C-V 곡선을 측정하였고, 이를 terman method를 이용하여 $D_{it}$를 계산하였다.

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The Relation Among the Linear Energy Transfer and Changes of Polyphenylene Sulfide Surface by ion Implantation (이온주입에 의한 고분자(Polyphenylene Sulfide)표면 특성 변화와 선에너지전달(Pineal Energy Transfer)과의 관계)

  • Lee, Jae S.;Kim, Bo-Young;Lee, Jae-Hyung
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.18 no.5
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    • pp.407-413
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    • 2005
  • Ion implantation provides a unique way to modify the mechanical, optical and electrical properties of polymer by depositing the energy of ions in the material on the atomic scale. Implantation of ions into the polymers generally leads to a radiation damage, which, in many cases, modifies the properties of the surface and bulk of the material. These modifications result from the changes of the chemical structure caused in their turn by changing the chemical bonding when the incident ions cut the polymer chains, breaks covalent bonds, promotes cross-linking, and liberates certain volatile species. We studied the relation among the linear energy transfer (LET) and changes of surface microstructure and surface resistivity on PPS material using the high current ion implantation technology The surface resistivity of nitrogen implanted PPS decreased to $10^{7}{\Omega}/cm^{2}$ due to the chain scission, cross linking, ${\pi}$ electron creation and mobility increase. In this case, the surface conductivity depend on the 1-dimensional hopping mechanism.

Electrically Controllable Terahertz Wave Modulator Based on a Metamaterial and VO2 Thin Film (메타물질 및 VO2 박막 기반의 전기적 제어 가능한 테라헤르츠파 변조기)

  • Ryu, Han-Cheol
    • Korean Journal of Optics and Photonics
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    • v.25 no.5
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    • pp.279-285
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    • 2014
  • We propose an electrically controllable terahertz wave modulator based on a metamaterial and vanadium dioxide ($VO_2$) thin film. A square loop shape is designed to play the roles of both a resonating metamaterial and a heater to electrically control the conductivity of $VO_2$. The transmission characteristics of the modulator were controlled by voltage. The transmission coefficient of the modulator was stably changed from 0.27 to 0.80 at 470 GHz according to the conductivity values of $VO_2$.

Enhancing Solar Cell Properties of Heterojunction Solar Cell in Amorphous Silicon Carbide (수광층의 카바이드 함량 변화에 따른 실리콘 이종접합 태양전지 특성 변화)

  • Kim, Hyunsung;Kim, Sangho;Lee, Youngseok;Jeong, Jun-Hui;Kim, Yongjun;Dao, Vinh Ai;Yi, Junsin
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.6
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    • pp.376-379
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    • 2016
  • In this paper, the efficiency improvement of the heterojunction with intrinsic thin layer (HIT) solar cells is obtained by optimization process of p-type a-SiC:H as emitter. The optoelectronic of p-type a-SiC:H layers including the optical band-gap and conductivity under the methane gas content variation is conducted in detail. A significant increase in the Jsc by $1mA/cm^2$ and Voc by 30 mV are attributed to enhanced photon-absorption due to broader band-gap of p-a-SiC:H and reduced band-offsets at p-side interface, respectively of HIT solar cells.

A Study of The $NO_2$ Gas Detect Properties of Tetra-3-hexadecyl-sulphamoylcopperphthalocyanine(HDSM-CuPc) Langmuir-Blodgett Film. (HDSM-CuPc LB막의 $NO_2$ 가스특성에 관한 연구)

  • Han, Y.J.;Kim, H.S.;Yoo, B.H.;Lee, C.H.;Kim, Y.K.;Kim, J.S.
    • Proceedings of the KIEE Conference
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    • 1994.11a
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    • pp.237-239
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    • 1994
  • The $NO_2$ gas-detection characteristics were investigated using the functional organic Langmuir-Blodgett(LB) film of Tetra-3-hexadecyl-sulphamoylcopperphthalocyanine(HDSM-CuPc). A surface pressure of 30mN/m was obtained as a proper one for a film deposition. A deposited film status was confirmed by electrical and optical methods such as UV/visible absorption spectra and current-voltage(I-V) characteristics. The $NO_2$ gas response experiments under 200ppm concentration show that there is not increment of electrical conductivity in room temperature and is identified by UV/visible absorption spectra. But There are some increments of electrical conductivity in $160^{\circ}C$.

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Effect of H2 Addition on the Properties of Transparent Conducting Oxide Films Deposited by Co-sputtering of ITO and AZO (동시 스퍼터링으로 제조한 AZO-ITO 혼합박막의 증착 중 수소 혼입 영향 분석)

  • Kim, Hye-Ri;Kim, Dong-Ho;Lee, Sung-Hun;Lee, Gun-Hwan
    • Journal of the Korean institute of surface engineering
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    • v.42 no.6
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    • pp.267-271
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    • 2009
  • Multicomponent transparent conducting oxide films were deposited on glass substrates at 150 by dual magnetron sputtering of AZO and ITO targets. In the case of mixing a limited amount of ITO (10W), resistivity of TCO films was significantly increased compared to the AZO film; from $3.5{\times}10^{-3}$ to $9.7{\times}10^{-3}{\Omega}{\cdot}cm$. Deterioration of the electrical conductivity is attributed to the decreases in carrier concentration and Hall mobility. Improvement of the conductivity could be obtained for the films prepared with ITO powers larger than 40 W. The lowest resistivity ($\rho$) of $7.3{\times}10^{-4}{\Omega}{\cdot}cm$ was achieved when ITO power was 100 W. Effects of $H_2$ incorporation on the electrical and optical properties of AZO-ITO films were investigated in this work. Addition of small amount of hydrogen resulted in the increase of carrier concentration and the improvement of electrical conductivity. It is apparent that the roughness of AZO-ITO films decreases dramatically after the transition of microstructure from polycrystalline to amorphous phase, which gives practical advantages such as an excellent uniformity of surface and a high etching rate. AZO-ITO films grown at sputtering ambient with hydrogen gas are expected to be applicable to optoelectronic devices such as organic light emitting diodes and flexible displays due to their sufficient electrical and structural properties.

The Properties of Boron-doped Zinc Oxide Film Deposited according to Oxygen Flow Rate

  • Kim, Dong-Hae;Son, Chan-Hee;Yun, Myoung-Soo;Lee, Jin-Young;Jo, Tae-Hoon;Seo, Il-Won;Jo, I-Hyun;Roh, Jun-Hyung;Choi, Eun-Ha;Uhm, Han-Sup;Kwon, Gi-Chung
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.358-358
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    • 2012
  • The application of BZO (Boron-doped Zinc Oxide) films use as the TCO(Transparent Conductive Oxide) material for display and solar cell industries, where the conductivity of the BZO films plays a critical role for improvement of cell performance. Thin BZO films are deposited on glass substrates by using RF sputter system. Then charging flow rates of O2 gas from zero to 10 sccm, thereby controlling the impurity concentration of BZO. BZO deposited on soda lime glass and RF power was 300 W, frequency was 13.56 MHz, and working pressure was $5.0{\times}10-6$ Torr. The Substrate and glass between distance 200 mm. We measured resistivity, conductivity, mobility by hall measurement system. Optical properties measured by photo voltaic device analysis system. We measured surface build according to oxygen flow rate from XPS (X-ray Photoelectron Spectroscopy) system. The profile of the energy distribution of the electrons emitted from BZO films by the Auger neutralization is measured and rescaled so that Auger self-convolution arises, revealing the detail structure of the valence band. It may be observed coefficient ${\gamma}$ of the secondary electron emission from BZO by using ${\gamma}$-FIB (Gamma-Focused Ion Beam) system. We observed the change in electrical conductivity by correlation of the valence band structure. Therefore one of the key issues in BZO films may be the valence band that detail structure dominates performance of solar cell devices. Demonstrating the secondary electron emission by the Auger neutralization of ions is useful for the determination of the characteristics of BZO films for solar cell and display developments.

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A Study on the Detection Characteristics of the Magneto-Plethysmography According to Fluid Properties (유체의 성질에 따른 자계용적맥파의 검출 특성에 관한 연구)

  • Kim, Sang-Min;Lee, Kang-Hwi;Lee, Seong-Su;Lee, Hyeok-Jae;Lee, Byoung-Hun;Kim, Kyeoung-Seop;Lee, Jeong-Whan
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.67 no.7
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    • pp.946-953
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    • 2018
  • Photo-plethysmography (PPG), which measures changes in the peripheral blood flow of a human body using difference in absorption rate of light, is a measurement method that is studied and used in clinical and various applications due to its simple circuit configuration and measurement convenience. Magneto-plethysmography (MPG), which is newly developed by our team, is a method of measuring changes in the conductivity of biological tissues by using a eddy current induced by a time-varying magnetic field, and is not subject to optical interference. In this study, we investigated the detection characteristics of MPG according to the change of the conductivity of the object and fluid to be measured by simultaneously measuring PPG and MPG. In order to control the speed of fluid known in advance, a blood flow simulator was implemented and used. The fluid used in the experiment was general mineral water and physiological saline (0.9% NaCl) solution. Experimental results show that the amplitude change of the measured PPG was 0.3% in normal water and saline solution, and that of MPG was 77.3%. Therefore, it is considered that the magneto-plethysmography (MPG) has a strong correlation with the conductivity of the fluid.

Property Estimation of Functionally Graded Materials Between M2 Tool Steel and Cu Fabricated by Powder Metallurgy (분말야금으로 제작된 M2 공구강과 Cu 간 기능성 경사 복합재의 물성 평가)

  • Jeong, Jong-Seol;Shin, Ki-Hoon
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.38 no.9
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    • pp.953-958
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    • 2014
  • The use of functionally graded materials (FGMs) may enhance thermal conductivity without reducing the desired strength in many applications such as injection molds embedding conformal cooling channels and cutting tools with heat sinks (or cooling devices). As a fundamental study for cutting tools having FGM heat sinks between M2 tool steel and Cu, six FGM specimens (M2 and Cu powders were premixed such that the relative compositions of M2 and Cu were 100:0, 80:20, 60:40, 40:60, 20:80, and 0:100 wt%) were fabricated by powder metallurgy in this study. The cross sections of these specimens were observed by optical microscopy, and then the material properties (such as thermal conductivity, specific heat, and coefficient of thermal expansion) related to heat transfer were measured and analyzed.

A performance study of organic solar cells by electrode and interfacial modification (전극과 계면간의 개질에 의한 유기태양전지의 성능 연구)

  • Kang, Nam-Su;Eo, Yong-Seok;Ju, Byeong-Kwon;Yu, Jae-Woong;Chin, Byung-Doo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.67-67
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    • 2008
  • Application of organic materials with low cost, easy fabrication and advantages of flexible device are increasing attention by research work. Recently, one of them, organic solar cells were rapidly increased efficiency with regioregular poly(3-hexylthiophene) (P3HT) and [6,6]-phenyl-C61-butyricacidmethylester (PCBM) used typical material. To increased efficiency of organic solar cell has tried control of domain of PCBM and crystallite of P3HT by thermal annealing and solvent vapor annealing. [4-6] In those annealing effects, be made inefficiently efficiency, which is increased fill factor (FF), and current density by phase-separated morphology with blended P3HT and PCBM. In addition, increased conductivity by modified hole transfer layer (HTL) such as Poly(3,4-ethylenedioxythiophene) poly(styrenesulfonate) (PEDOT:PSS), increased both optical and conducting effect by titanium oxide (TiOx), and changed cathode material for control work function were increased efficiency of Organic solar cell. In this study, we had described effect of organic photovoltaics by conductivity of interlayer such as PEDOT:PSS and TCO (Transparent conducting oxide) such as ITO, which is used P3HT and PCBM. And, we have measured with exactly defined shadow mask to study effect of solar cell efficiency according to conductivity of hole transfer layer.

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