• Title/Summary/Keyword: one-bath

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Effects of Electrodeposition condition on the fracture characteristics of 80Sn-20Pb electrodeposits aged at 15$0^{\circ}C$ (15$0^{\circ}C$에서 시효처리한 80Sn-20Pb 합금 도금층의 파괴특성에 전착조건이 미치는 영향)

  • 김정한;서민석;권혁상
    • Journal of the Korean institute of surface engineering
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    • v.27 no.5
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    • pp.292-302
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    • 1994
  • Alloy deposits of 80Sn-20Pb, electroplated on Cu-based leadframe alloy from an organic sulfonate bath were aged at $150^{\circ}C$ to form intermetallic phases between substrate and deposit, and effects of the deposit morphology, influenced by deposition conditions, on the fracture resistance of the 80Sn-20Pb deposit aged at $150^{\circ}C$ were examined. The growth rate of intermetallic compound layer on aging depended on the microstructure of deposit ; it was fastest in deposit formed using pulse current in bath without grain refining additive, but slowest in deposit formed using dc current in bath containing grain refining additive in spite of similar structure with equivalent grain size. The grain refining additive incorporated in electrodeposit appears to inhibit diffusion of atoms on aging, resulting in slow growth of intermetallic layer in the thickness direction but substantial growth in the lateral one. Density of surface cracks that were occurring when samples were subjected to the $90^{\circ}$-bending test increased with increasing the thickness of intermatallic layer on aging. For the same aged samples, the surface crack density of the sample electrodeposited from a bath containing the grain refining additive was the least due to the inhibiting effect of the additive incorporated into the deposit during electrolysis on atomic diffusion.

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Emulsion Polymerization of Octamethylcyclotetrasiloxane under Ultrasonic Irradiation (고강도 초음파를 이용한 Octamethylcyclotetrasiloxane의 에멀전 중합)

  • Kim, Jihye;Kim, Yubin;Kim, Hyungsu
    • Applied Chemistry for Engineering
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    • v.20 no.3
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    • pp.322-328
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    • 2009
  • Emulsion polymerization of octamethylcyclotetrasiloxane (OMCTS) was conducted under ultrasonic irradiation. Two sources of ultrasound with different intensities and frequencies of 20 KHz and 40 KHz were used for horn and bath type reactor, respectively. A combined process of horn and bath was also investigated. The effectiveness of the reaction systems was investigated by measuring conversion as well as intrinsic viscosity of the products. The influence of reaction temperature and sonication time on the progress of sonochemical polymerization was examined. It was found that conversion of greater than 80% and high viscosity were achieved within a few minutes of sonication in a horn type reactor, however, conversion and viscosity showed maximum values depending upon the sonication time. In a bath type reactor where a relatively weak intensity was maintained, longer duration time of more than one hour of sonication was required to reach a high level of conversion and viscosity. Compared with the horn type system, the conversion and viscosity in the bath type reactor were increased along with the sonication time. When the polymerization was carried out in a combined system of horn and bath, the evolution of conversion and molecular weight was quite different from the other cases. For the given geometry of reaction system, acoustic analysis using a commercial software was carried out and the results were correlated with experimental observation.

Studies on the Shade Tolerance of the Woody and Herbaceous Plants for Urban Forest Aromatic Bath (도시형(都市型) 삼림욕장(森林浴場) 목초본식물(木草本植物)의 내음성(耐陰性) 연구(硏究))

  • Hong, Sung Gak;Kim, Jong Jin;Im, Hyoung Tak
    • Journal of Korean Society of Forest Science
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    • v.89 no.5
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    • pp.585-590
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    • 2000
  • The studies were carried out to know shade tolerance of the plants for the urban forest aromatic bath. The one to two year old potted seedlings were grown under the one of the five light conditions such as 100%, 50%, 30%, 10% and 2% of the full sun light intensities. Pinus densiflora S. et Z., P. sylvestriformis (Takenouchi) Chien., Thymus quinquecastatus Celak, Lonicera japonica Thunb, and Zingiber officinale Roscoe showed decreasing tendencies in height and root collar diameter growth, and dry mass production as the light intensity decreases. Exceptionally Thuja koraiensis Nakai showed the best growth in the 50% of full sun light intensity. Athyrium yokoscense (Fr. et Sab.) H. Christ showed better growth in the relative light intensity of 10 to 15% than in the in the relative light intensity of 25 to 30% in the bath green house.

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Effect of current density, temperature and electrolyte concentration on Composition of Zn-Ni Electrodeposits (Zn-Ni도금의 합금화에 미치는 전류밀도, 온도와 전해액농도의 영향)

  • Kang, Soo Young
    • Journal of the Korea Convergence Society
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    • v.8 no.11
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    • pp.307-312
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    • 2017
  • In the industry, galvanizing using the principle of sacrificial anode is used Zn-Ni alloy plating was developed as one of the measures to increase the corrosion resistance rather than pure zinc plating. The alloy plating layer has a corrosion resistance of 4-5 times that of the pure zinc plating layer, so that it is applied to automotive parts requiring high corrosion resistance even though the plating cost is high. The amount of Zn-Ni alloy plating solution is a sulfuric acid bath, a chlorinated bath, an alkali bath, and an ammonia bath. Here, the influence of the electrolytic conditions on the composition of the alloy plating in the chloride bath was investigated. The results are explained by the cathode overvoltage and the diffusion coefficient. In general, as the overvoltage of the cathode increases, the concentration polarization becomes more important than the activation polarization. The concentration polarization is determined by element diffusion in the diffusion layer. That is, as the overvoltage of the cathode increases, the Zn content having a large diffusion coefficient increases.

Comparative analysis of strain according to the deposition of a constant temperature water bath of a denture-base artificial tooth produced using three-dimensional printing ultraviolet-curing resin (3D 프린팅용 광경화 수지를 사용하여 제작한 의치상용 인공치아의 항온수조 침적에 따른 변형률 비교 분석)

  • Kim, Dong-Yeon;Lee, Gwang-Young;Kim, Jae-Hong;Yang, Cheon-Seung
    • Journal of Technologic Dentistry
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    • v.42 no.3
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    • pp.202-207
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    • 2020
  • Purpose: This study is a comparative analysis of the strain according to deposition in a constant temperature water bath after manufacturing ultraviolet (UV)-cured artificial teeth. Methods: As a control group, 10 ready-made artificial teeth were selected as the first molar on the right side of the maxilla (RT group). Silicone was used as a duplicate of the artificial denture teeth. Experimental teeth were prepared in two groups using the prepared silicone mold. In the first experimental group, the UV-cured resin was injected into the negative silicone, followed by irradiation with a UV-curing machine for 5 minutes (5M group). In the second experimental group, the UV-cured resin was injected into the negative silicone, and then irradiated for 30 minutes using a UV-curing machine (30M group). The one-way ANOVA was performed, and post-test was analyzed by Tukey. Results: When immersed in a water bath for 15 days, it was found to be -0.3% in the RT group, -0.6% in the 5M group, and -0.7% in the 30M group. The results revealed -0.2% in the RT group, 0.2% in the 5M group, and -0.2% in the 30M group when they were in the bath for 30 days. Conclusion: In the water bath, the swelling was greater when deposited for 1 to 15 days, but was less when deposited for 15 to 30 days.

A Study on the Extraction of Soluble Colorants of the Gardenia jasminoides Ellis (수용성 치자 색소의 추출에 관한 연구)

  • Kim, Kwang Soo;Kim, Yeon Joong
    • Textile Coloration and Finishing
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    • v.9 no.3
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    • pp.10-17
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    • 1997
  • The study was performed to obtain the optimum extraction conditions for crocin from gardenia fructus. Generally crocin is unstable on heat, light, acid and base solution. The extraction efficiency of crocin from gardenia depended upon the extraction time, extraction temperature, pH in the extraction bath and the optimum conditions of crocin extraction were determined as 60 minutes of extraction time, 4$0^{\circ}C$ of extraction temperature, pH 7 of extraction bath. The molar extinction coefficient of crocin was 12,515 and the color yield of purified crocin was about six times higher than that of non-purified crocin. The heat-stability at extraction temperature and lightstability in irradiation with xenon lamp for one hour of the purified crocin were higher than those of non-purified crocin. Intensity of &{\lambda}_{max}&of crocin was decreased by irradiation for one hour but UV-Vis. spectra of crocin was not changed. The colors of purified and non-purified crocin dissolved wit methanol was evaluated by means of CIE L* a* b* system.

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One Bath Dying of Silk/Synthetic Fiber Blends (2) (Color perseption of adsorption and desorption behavior of disperse dyes on silk and transfer to synthetic fibers) (견/합성섬유 혼방품의 일욕 염색 (II)(견에대한 분산염료의 염착, 탈착 및 합성섬유에의 이염의 색지각))

  • 김공주;곽인준;박미라;전재홍
    • Textile Coloration and Finishing
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    • v.5 no.2
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    • pp.99-108
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    • 1993
  • In one dyeing system of silk/synthetic blend fabrics (polyester, nylon, acetate) with acid dyes/disperse dyes, dyeability and desorptibility of disperse dyes on silk fabric and transfer from dyed silk fabrics to synthetic fabrics by color difference were examined. When silk dyed with C.I. Disperse Red 19 and C.I. Disperse Red 60 at 10$0^{\circ}C$ for 60 minutes, color difference of dyed silk were $\Delta$E=56.72, $\Delta$E=47.65 for blank silk, respectively. The desorption rate of the dyed silks were measured in boiling bath with and without dye-free synthetic fibers. The desorption rate of dyed silk was effected by affinity of synthetic fabrics contained. When silk dyed with Red 19 and Red 60 was reduced at 10$0^{\circ}C$ for 60 minutes, the decolouration rates of dyed silk were 75% and 40%, respecdtively.

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One Bath Dyeing of Silk/Synthetic Fiber Blends (V) (견/합성섬유 혼방품의 일욕염색 (V) -견/나일론 혼방품의 일욕염색-)

  • 이재덕;전재홍;김공주
    • Textile Coloration and Finishing
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    • v.6 no.3
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    • pp.67-73
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    • 1994
  • The adsorption behaviors of acid dye and disperse dye on silk and nylon fabrics were examined, in one bath dyeing system on silk/nylon blend fabric with disperse dyes and acid dyes. In the dyeing of nylon fabric with C. I. Disperse Red 19 (Red 19) and C. I. Disperse Red 60 (Red 60), dye uptake of Red 19 was higher than that of Red 60. When silk/nylon blend fabric was dyed with Red 19 and Red 0, the dye uptake on nylon was influenced by the ffinity of the dye to the silk fabric. In the dyeing of silk/nylon with C. I. Acid Blue 80 and C. I. Acid Yellow 121, solid shade could not be obtained with the conventional method but could be obtained with the dyeing resist agent for nylon. There was not any relationship between K/S value and Munsell value, but Munsell value tended to change with the K/S value.

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Synthesis of Temporarily Solubilized Reactive Disperse Dyes and Their Application to the Polyester/Cotton Blend Fabric

  • Lee, Jung-Jin;Han, Nam-Keun;Lee, Won-Jae;Park, Jae-Hong;Kim, Jae-Pil
    • Fibers and Polymers
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    • v.3 no.3
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    • pp.85-90
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    • 2002
  • Five temporarily solubilized reactive disperse dyes were synthesized and characterized. They were applied to polyester/cotton blend fabric using one-bath dyeing method without dispersing agent. The dye that has azonaphthalene chro-mophore seemed to not only be exhausted on polyester but also react with cotton. But other dyes were selectively dyed on polyester and showed limited uptake on cotton. Good levelling as well as moderate to good colour fastness was obtained with the dyes on P/C blend fabric.