• Title/Summary/Keyword: oil-degradation

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A Study on the Engine Oil Resistant Behaviors of Room Temperature Vulcanizing Silicone Adhesives (상온 경화형 실리콘 접착제의 내엔진 오일성에 관한 연구)

  • Park, Soo-Jin;Jin, Fan-Long;Kim, Jong-Hak;Joo, Hyeok-Jong;Kim, Joon-Hyung
    • Elastomers and Composites
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    • v.40 no.3
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    • pp.196-203
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    • 2005
  • In this work, the engine oil resistant evaluation and breakdown analysis of room temperature vulcanizing silicone adhesives were performed through the surface properties, thermal stabilities, adhesive strength, and morphology measurements. As a result, the permeation of engine oil into adhesive specimens was carried out from surface to center in the specimens. And the oil content in the adhesive specimens was increased and the Si-O-Si bond of the adhesives was decomposed with increasing the aging time. The TGA results indicated that the thermal degradation was mainly occurred at under and surfaces of the specimens. The tensile strength, elongation, and adhesive strength of the adhesives were significantly decreased after the engine oil resistant tests, which could be attributed to the initial lose of adhesive properties resulting from the engine oil absorption and thermal aging. And the failure mode of the adhesive specimens was changed from cohesive failure to interfacial failure.

Effect of the Properties of Diesel Engine Oil and Aging on Exhaust Gases and DPF (경유엔진용 윤활유의 성상 및 열화가 배출가스 및 후처리 장치에 미치는 영향 연구)

  • Kim, JeongHwan;Kim, KiHo;Lee, JungMin
    • Tribology and Lubricants
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    • v.34 no.6
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    • pp.292-299
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    • 2018
  • The objective of this research is to investigate the impact of engine oil aging on PM(Particulate Matter), exhaust gases, and DPF. It is widely known that the specification of a lubricant and its consumption in an ICE considerably influences the release of regulated harmful emissions under normal engine operating conditions. Considering DPF clogging phenomena associated with lubricant-derived soot/ash components, a simulated aging mode is designed for DPF to facilitate engine dynamometer testing. A PM/ash accumulation cycle is developed by considering real-world engine operating conditions for the increment of engine oil consumption and natural DPF regeneration for ash accumulation. The test duration for DPF aging is approximately 300 h with high- and low-SAPs engine oils. Detailed engine lubricant properties of new and aged oils are analyzed to evaluate the effect of engine oil degradation on vehicle mileage. Furthermore, physical and chemical analyses are performed using X-CT, ICP, and TGA/DSC to quantify the engine oil contribution on the PM composition. This is achieved by sampling with various filters using specially designed PM sampling equipment. Using high SAPs engine oil causes more PM/ash accumulation compared with low SAPs engine oils and this could accelerate fouling of the EGR in the engine, which results in an increase in harmful exhaust gas emissions. These test results on engine lubricants under operating conditions will assist in the establishment of regulated and unregulated toxic emissions policies and lubricant quality standards.

Degradation of Cement Mortar with Supplementary Cementitious Materials Submerged in Various Oils (각종 유지류에 침지된 혼화재 치환 시멘트 모르타르의 열화특성)

  • Han, Cheon-Goo;Hwang, Chan-Woo
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.2
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    • pp.137-143
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    • 2017
  • There has been a number of research on concrete durability. specially, as a research on chemical ingression, the research on the degradation against acid, alkali, and sulfate has been conducted. On the other hand, for the research on oils, especially, the influence of various oils on cement mortar with Supplementary Cementitious Materials(SCMs) is not sufficiently studied. hence, in this research, the degradation of cement mortar incorporated fly ash and blast furnace slag is researched when the cement mortar is submerged in various oils. For the result of experiment, as the content of fatty acid in the oils, the degradation of cement mortar with SCMs was occurred more, and the cement mortar with SCMs suffered more degradation than the ordinary portland cement regarding the oil submerging.

A Novel Method to Assess the Aerobic Gasoline Degradation by Indigenous Soil Microbial Community using Microbial Diversity Information (토양 미생물 다양성 지표를 이용한 토착 미생물 군집의 호기성 가솔린 오염분해능력 평가 기법 개발 연구)

  • Hwang, Seoyun;Lee, Nari;Kwon, Hyeji;Park, Joonhong
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.36 no.5
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    • pp.839-846
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    • 2016
  • Since oil leakage is one of the most common nonpoint pollution sources that contaminate soil in Korea, the capacity of soil microbial community for degrading petroleum hydrocarbons should be considered to assess the functional value of soil resource. However, conventional methods (e.g., microcosm experiments) to assess the remediation capacity of soil microbial community are costly and time-consuming to cover large area. The present study suggests a new approach to assess the toluene remediation capacity of soil microbial community using a microbial diversity index, which is a simpler detection method than measuring degradation rate. The results showed that Shannon index of microbial community were correlated with specific degradation rate ($V_{max}$), a degradation factor. Subsequently, a correlation equation was generated and applied to Michaelis-Menten kinetics. These results will be useful to conveniently assess the remediation capacity of soil microbial community and can be widely applied to diverse engineering fields including environment-friendly construction engineering fields.

A Study on Conductivity Characteristics of X-ray Irradiated Insulating Oil (X선조사(線照射)에 의한 절연유(絶緣油)의 도전특성(導電特性)에 관한 연구(硏究))

  • Kim, Young-Il;Lee, Duck-Chool;Chung, Yon-Tack
    • Journal of radiological science and technology
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    • v.10 no.1
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    • pp.75-83
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    • 1987
  • The insulating oil used for X-ray tube housing were degraded by X-ray irrdiation, high temperature and high anode voltage for normal operation. This study was measured the conduction current-X-ray dose, heating degradation, time, temperature and electric field characteristics and the dependense of electrode materials and gap length in the X-ray irradiatied insulating oil under of D.C voltage. The obtained results can be summarized as following. 1. The conduction current of X-ray irradiated insulating oil is more about $2.5{\sim}3$ times as large as than that of non x-ray irradiated, and is become saturation phenomena after some degree. 2. The conduction current of many times heating x-ray irradiated insulating oil is more than that of a few times heating. 3. The higher temperature x-ray irradiated insulating oil is increased, the more conduction current, and that is increased about ten times as large as when it's temperatures is increased to $80^{\circ}C\;at\;30^{\circ}C$, twenty five times at $100^{\circ}C$. 4. The dependence of electrode materials is appeared at the low electric field, and the small gap length with Fe > Cu > Al. 5. The low electric field than 3000 v/cm is appeared Ohm's law region, and the high is become saturation region at the I-E characteristics. 6. The larger gap length is become, the more conduction current is increased at the same electric field.

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Oxidative Stability and Antioxidant Changes in Perilla Seeds and Perilla Oil Affected by UV Irradiation (들깨 및 들기름의 자외선 조사 중 지방질 산화와 산화방지제의 변화)

  • Wang, Seon-Yeong;Choe, Eun-Ok
    • Korean Journal of Food Science and Technology
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    • v.44 no.1
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    • pp.8-13
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    • 2012
  • Effects of UV irradiation on lipid oxidation in perilla seeds and perilla oil were evaluated by determining the contents of peroxides, conjugated dienoic acids, and thiobarbituric acid reactive substances, and analyzing fatty acid composition. Tocopherols and polyphenol contents were also determined. Perilla seeds were unroasted or roasted at $180^{\circ}C$ for 20 min, and perilla oil was obtained by pressing the roasted perilla seeds. Lipid oxidation during UV irradiation was higher and faster in perilla oil than that in perilla seeds, with a slight loss of linolenic acid. Unroasted perilla seeds were more oxidation-stable than roasted seeds. Tocopherols and polyphenols were degraded during UV irradiation, with a higher degradation rate observed in unroasted perilla seeds than in roasted ones. Antioxidant concentration dependency of the lipid oxidation during UV irradiation was higher in perilla oil than that in perilla seeds, and the contribution of polyphenols to oxidative stability was higher than that of tocopherols in all samples.

A Study on the Property and Performance Characteristics of Different Kind Engine Oil by Endurance Test of Heavy-duty Diesel Engine (대형 디젤엔진 내구 시험에 의한 다른 종류 엔진오일의 물성 및 성능 특성에 관한 연구)

  • Lee, Minho;Kim, Jeonghwan;Song, Hoyoung;Kim, Giho;Ha, Jonghan
    • Transactions of the Korean Society of Automotive Engineers
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    • v.22 no.7
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    • pp.48-56
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    • 2014
  • Engine oil is an oil used for lubrication of various internal combustion engines. The main function is to reduce wear on moving parts; it also cleans, inhibits corrosion, improves sealing, and cools the engine by carrying heat away from moving parts. In engines, there are parts which move against each other. Otherwise, the friction wastes the useful power by converting the kinetic energy to heat. Those parts were worn away, which could lead to lower efficiency and degradation of the engine. It increases fuel consumption, decreases power output, and can induce the engine failure. This study was conducted to evaluate the relation between engine oil property changes and engine performance for the diesel engine. This test was performed by using 12L, 6 cylinder, heavy duty engines. Low SAPS 10W30 engine oil (two type engine oils) was used. Test procedure and method was in accordance with the modified CEC L-57-T97 (OM441LA) method. In this study, TAN, TBN, KV and metal components, engine power, blowby gas, A_F were presented to evaluate the relation with engine oil property changes and engine performance. TAN, TBN, KV and metal We found that the components were generally increased but engine performance did not change. This results mean that property changes did not affect on engine performance because those were not enough to affect engine performance.

Evaluation of Dispersant Application to Stranded Oil as a Clean-up Technique at Sandy Tidal Flat (사질 조간대 표착유의 방제를 위한 유화분산제의 적용 평가)

  • Cheong, Cheong-Jo
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.11 no.4
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    • pp.227-231
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    • 2008
  • The purpose of this study is to clarify the behavior of stranded crude oil and to estimate the restoration of seawater infiltration by application of dispersant as one of cleaning techniques. We made visualization of infiltration process of seawater and stranded crude oil on the sandy beach sediments by using of a model sandy beach. Major conclusions derived from this study are as follows. The seawater infiltration volume was reduced by the stranded crude oil. However, thirty percentage of the sweater infiltration into the sediments was restored by dispersant application to the penetrated oil in sandy beach. The penetration depth of stranded oil were dropped at first falling tide, but were not significantly fluctuated after that. Moreover, oil concentration was most high within the upper 2 cm. The stranded crude oil was broken into small size droplets and dispersed into the sediments by the dispersant application. Therefore, dispersant applications play an important roles in the large increase of surface area of given volume of oil, and it resulted in promoting to biological degradation process at the oil/water interface, dispersing the stranded oil into the water column and restoration of the supplement of the dissolved oxygen and nutrients to the benthic organisms.

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Characteristics on the Removal of Emulsified Vegetable Oil in Wastewater using Bio logical Fluidized Bed (생물학적(生物學的) 유동층(流動層)을 이용(利用)한 수중(水中)의 식물성유(植物性油) 제거특성(除去特性))

  • Kim, Hwan Gi;Park, Ro Sam
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.10 no.3
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    • pp.127-136
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    • 1990
  • In this paper, the experimental study was carried out for the removal of olive oil in wastewater by the use of Biological Fluidized Bed(BFB) with the reticulated polypropylene sheets as media. The nonbiodegradable olive oil, one of the animal and vegitable oil, was used bacause of the relative simplicity of constitution. Biological degraciability and removal characteristics of emulsified olive oil were studied by batch and continuous experiments respectively. From the results of batch experiments, it was observed that the emulsified olive oli used in BFB reactor was absorbed by media and sludge in about 12 hours, and degradation of the absorbed olive oli was mostly completed for 24 hours. The functional relationship of Michaelis-Menten's Enzyme reaction equation exists between oil concentration and maximum specific rate of olive oil. From the continuous experiments for the removal of olive oil using BFB reactor, it was proved that the substrate removal rate coefficient $k=0.004d^{-1}$, which is the first order kinetics. It was apperared that oxygen utlization coefficients for synthesis(a') and endogeneous respiration(b') of microorganisms in the reactor are respectively 0.85mg $O_2/mg$ $COD_{cr}$ and 0.011mg $O_2/mg$ BVS. day.

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Study on The Thermochemical Degradation Features of Empty Fruit Bunch on The Function of Pyrolysis Temperature (반응온도에 따른 팜 부산물(empty fruit bunch)의 열화학적 분해 특성에 관한 연구)

  • Lee, Jae Hoon;Moon, Jae Gwan;Choi, In-Gyu;Choi, Joon Weon
    • Journal of the Korean Wood Science and Technology
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    • v.44 no.3
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    • pp.350-359
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    • 2016
  • We performed fast pyrolysis of empty fruit bunch (EFB) in the range of temperature from $400{\sim}550^{\circ}C$ and 1.3 s of residence time. The effect of temperature on the yields and physicochemical properties of pyrolytic products were also studied. Elemental and component analysis of EFB showed that the large amount of potassium (ca. 8400 ppm) presents in the feedstock. Thermogravimetric analysis suggested that the potassium in the feedstock catalyzed degradation of cellulose. The yield of bio-oil increased with increasing temperature in the range of temperature from $400{\sim}500^{\circ}C$, while that of gas and biochar decreased and showed monotonous change each with increasing temperature. When the EFB was pyrolyzed at $550^{\circ}C$, the yield of bio-oil and char decreased while that of gas increased. Water content of the bio-oils obtained at different temperatures was 20~30% and their total acid number were less than 100 mg KOH/g oil. Viscosity of the bio-oils was 11 cSt (centistoke), and heating value varied from 15 to 17 MJ/kg. Using GC/MS analysis, 27 chemical compounds which were classified into two groups (cellulose-derived and lignin-derived) were identified. Remarkably the concentration of phenol was approximately 25% based on entire chemical compounds.