• Environmental Analysis Health and Toxicology
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• v.4 no.1_2
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• pp.11-17
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• 1989

A quantitative analytical method of highly concentrated PCB is established in the research. With the quantitative analytical method PCB of insulating oil was examined. The following conclusions are derived from this research. 1. The recovery ratio was 95.7% with the quantitative analytical method, which indicates it can be used for the analysis of PCB. 2. PCB concentration of insulation oil in waste condenser was found to be 21.2% thru 13.85% , which was highly concentrated. 3. PCB insulation oil in waste condenser was same as PCB-42.

• Tribology and Lubricants
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• v.10 no.3
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• pp.1-11
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• 1994

근년에 이르러 waste oil의 문제는 그 어느 때보다도 양이나 종류에 있어서 과거에 볼 수 없었던 만큼 심각한 양상을 나타내고 있다. 1992년도 한해동안 세계적으로 발생된 바 있는 폐윤활유의 양은 약 23,200 mega liter로 추정되고 있으며, 재정제에 의하여 recycle된 oil은 각국에 따라 차이점은 있으나 대략 수요량의 2~3%로서 이들의 합계량은 약 1,890 mega liter로 추정되고 있다. 한편 우리나라 waste oil의 발생량인 경우, 통계가 명확하지는 않지만 1993년도 한해동안 약 75만톤에 이를 것으로 추정되고 있는가 하면, 이 중 특정폐기물로 분류되고 있는 자동차용 폐윤활유에 있어서는 약 18만톤이 발생된 바 있다. 본 기고에서는 각종 폐유 중 특정폐기물인 폐윤활유를 중심으로한 제목건에 대하여 간략하게 기술하기로 하겠다.

• Journal of Microbiology and Biotechnology
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• v.18 no.8
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• pp.1408-1415
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• 2008

To produce polyhydroxyalkanoate (PHA) from inexpensive substrates by bacteria, vegetable-oil-degrading bacteria were isolated from a rice field using enrichment cultivation. The isolated Pseudomonas sp. strain DR2 showed clear orange or red spots of accumulated PHA granules when grown on phosphate and nitrogen limited medium containing vegetable oil as the sole carbon source and stained with Nile blue A. Up to 37.34% (w/w) of intracellular PHA was produced from corn oil, which consisted of three major 3-hydroxyalkanoates; octanoic (C8:0, 37.75% of the total 3-hydroxyalkanoate content of PHA), decanoic (C10:0, 36.74%), and dodecanoic (C12:0, 11.36%). Pseudomonas sp. strain DR2 accumulated up to 23.52% (w/w) of $PHA_{MCL}$ from waste vegetable oil. The proportion of 3-hydroxyalkanoate of the waste vegetable-oil-derived PHA [hexanoic (5.86%), octanoic (45.67%), decanoic (34.88%), tetradecanoic (8.35%), and hexadecanoic (5.24%)] showed a composition ratio different from that of the corn-oil-derived PHA. Strain DR2 used three major fatty acids in the same ratio, and linoleic acid was the major source of PHA production. Interestingly, the production of PHA in Pseudomonas sp. strain DR2 could not occur in either acetate- or butyrate-amended media. Pseudomonas sp. strain DR2 accumulated a greater amount of PHA than other well-studied strains (Chromobacterium violaceum and Ralstonia eutropha H16) when grown on vegetable oil. The data showed that Pseudomonas sp. strain DR2 was capable of producing PHA from waste vegetable oil.

• Journal of Korea Society of Waste Management
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• v.35 no.7
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• pp.571-586
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• 2018

The Malaysian biogas upgrading technologies and policies were examined. In Malaysia, the regulation of palm oil mill effluent (POME) has been enforced to reduce the biochemical oxygen demand to 20 ppm and the biogas capture in the palm oil mills have been recently enforced for renewable energy. A huge amount of organic waste is produced from POME, and 80 million tons from palm oil trees, every year. Due to the renewable energy trends, the Malaysian government is modifying the use of biogases as fuels in favor of their conversion into compressed natural gas (CNG) and other chemicals; various green policies are being promoted because of many advantages of the organic substances. The Korean policies for biogas are a good model for exporting environmental plants after upgrading the digestion and purification technologies. Therefore, this article introduces the current status of POME and biogas production in Malaysia, it could encourage creating a new market for biomethane.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.8
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• pp.552-561
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• 2018

Biomass, a carbon-neutral resource, is an alternative energy source for exhaustion of fossil fuel and environmental problems. Most of energy production systems using biomass operate with a thermal chemical conversion method. Amongst them, gasification generates syngas and applies to boilers or engines for the production of heat and electricity. However, Tar could be formed during the production of syngas and it is condensed at low temperature which may cause to clog the pipelines and combustion chamber, ultimately resulting in decrease of process efficiency. Thus this work utilized water and oily materials such as soybean oil, waste cooking oil and mineral oil for scrubbing liquid. The removal efficiency of Tar appeared 97%, 70%, 63% and 30% for soybean oil, waste cooking oil, mineral oil and water respectively.

• Journal of the Korean Applied Science and Technology
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• v.34 no.3
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• pp.683-693
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• 2017

Transport biofuels have been recognized as a promising means to resolve the following issues like global warming, oil depletion and environmental pollutions. Among various biofuels, biodiesel has several advantages such as less emission of air pollutants and higher cetane values compared to diesel oil. Demand for biodiesel in Korea is increasing that leads to higher dependence on the imported feedstocks. Therefore, it is important to utilize the waste materials collected domestically for biodiesel production. Food waste oil collected in waste treatment facility has not been used for biodiesel production due to high free fatty contents in the oil. In this work, biodiesel conversion of food waste oil by Amberlyst 15 was studied. Synthetic and actual food waste oils have been used in the study. First, the effects of the major operating parameters including reaction temperature, methanol to oil molar ratio and catalyst loading on the conversion rates and yields were determined with synthetic waste oil. Kinetic modelling work was also done to determine the activation energy of the reaction. From the work, optimization reaction conditions were determined to be 383K, 1: 26.1 for methanol molar ratio to oil, 10 wt.% for catalyst loading and 360 min for reaction time. Activation energy of the reaction is determined to be 29.75 kJ/mol, lower than those reported in the previous works. So the solid catalyst, Amberlyst 15, was more efficient for esterification than the solid catalysts employed in the other works. Agitation rates have the negligible effects on the conversion rates and yields. With the identified optimization conditions, conversion of the actual food waste oil was also carried out. The esterification yield of actual food waste oil in 60 min was 13% lower than that of synthetic waste oil but the final yields in 240 min were similar each other, 98.12% for synthetic oil and 97.62% for actual waste oil.

• Journal of Energy Engineering
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• v.14 no.2 s.42
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• pp.159-166
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• 2005

In Korea, although the generation of waste plastic has been increasing, the rate of recycling is considerably low and moreover, there is no suitable method for the treatment of waste plastics. However, pyrolysis, which is appropriate for the treatment of highly polymerized compounds, such as plastics, has recently gained much interest. In this study, a property of the products from the pyrolysis of mixed waste plastics, with a possible practical use for the recycling oil produced, were assessed. First of all, in order to investigate the pyrolysis characteristic of waste plastics, TGA (Thermogravimetric analysis) and DCS (Differential Scanning Calorimetry) were performed on a number of different plastics, including PP, LDPE, HDPE, PET and PS, as well as others. According to the result, it appeared that PP was the most efficiently pyrolyzed by changing the temperature, followed by LDPE, HDPE, PET, PS and the other plastics, in that order. From the results, the optimum conditions f3r pyrolysis were set up, and the different waste plastics pyrolyzed. The recycling oil produced from the flammable gases generated during the pyrolysis was com-pared with fuel oil by an analysis using the petroleum quality inspection method on KS(Korea industrial Standard). The results of the analysis showed the recycling oil was of a similar standard to fuel oil, with the exception of the ignition point, with a quality somewhere between that of paraffin oil and diesel fuel. With respect to these results, the quality of the recycling oil produced by the pyrolysis of waste plastics was suf-ficient for use as fuel oil.

• International journal of advanced smart convergence
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• v.4 no.1
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• pp.162-178
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• 2015

Petroleum based fossil fuels used to power most processes today are non-renewable fuels. This means that once used, they cannot be reproduced for a very long time. The maximum combustion of fossil fuels occurs in automobiles i.e. the vehicles we drive every day. Thus, there is a requirement to shift from these non-renenewable sources of energy to sources that are renewable and environment friendly. This is causing the need to shift towards more environmentally-sustainable transport fuels, preferably derived from biomass, such as biodiesel blends. These blends can be made from oils that are available in abundance or as waste e.g. waste cooking oil, animal fat, oil from seeds, oil from algae etc. Waste Cooking Oil(WCO) is a waste product and so, converting it into a transportation fuel is considered highly environmentally sustainable. Keeping this in mind, a life cycle assessment (LCA) was performed to evaluate the environmental implications of replacing diesel fuel with WCO biodiesel blends in a regular Diesel engine. This study uses Life Cycle Assessment (LCA) to determine the environmental outcomes of biodiesel from WCO in terms of global warming potential, life cycle energy efficiency (LCEE) and fossil energy ratio (FER) using the life cycle inventory and the openLCA software, version 1.3.4: 2007 - 2013 GreenDelta. This study resulted in the conclusion that the biodiesel production process from WCO in particular is more environmentally sustainable as compared to the preparation of diesel from raw oil, also taking into account the combustion products that are released into the atmosphere as exhaust emissions.

• Elastomers and Composites
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• v.39 no.1
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• pp.61-70
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• 2004

This work is about the development or asphalt sealant using the waste edible oil. Asphalt sealant has been used for crack filler and bridge deck joint sealer Several plasticizers such as aromatic or paraffin process oils, DOP, Bunker C fuel oil, and waste edible oil were compounded with the basic components such as asphalt(AP-5), a thermoplastic elastomer(SBS triblock copolymer), a tackifying agent(petroleum resin), and stabilizers. Penetration, softening point, ductility, and elongation by tensile adhesion of those asphalt sealant compounds were measured. Their properties were changed largely depending on both the type and content of plasticizers. Waste edible oil and DOP were the best plasticizers for the low temperature tensile adhesion characteristics. Penetration and elongation by tensile adhesion of asphalt sealant compounds increased with the increase of waste edible oil content and decreased with the increase of talc content. The manufacture of asphalt sealant with low penetration and excellent low temperature tensile adhesion was possible by the recipe optimization.

• Elastomers and Composites
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• v.44 no.1
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• pp.69-75
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• 2009

Asphalt sealants for the crack repair of asphalt concrete road were prepared using waste lubricant oil in this work. The waste lubricant oil was compounded with asphalt(AP-5), SBS triblock copolymer, a tackifying agent(petroleum resin), and antioxidants. Cone penetration, softening point, ductility, elongation by tensile adhesion, and resilience of asphalt sealant compounds were measured. Cone penetration of asphalt sealant compounds increased with the increase of waste lubricant oil content while their softening point, ductility, and resilience decreased. By the addition of talc as an extender, softening point and resilience of asphalt sealants increased, but cone penetration, ductility, and elongation by tensile adhesion of those decreased with the proportion of talc content. The most economic asphalt sealant which could pass an ASTM specification could be manufactured by the big decrement of petroleum resin content.