• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.323-323
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• 2014

기존의 태양전지 기술은 기술 장벽이 매우 낮고 대량 생산을 통한 단가 절감하는 구조를 가지고 있어 대규모 자본을 가진 후발 기업에게 잠식되기 쉽다. 그러나, III-V족 화합물 반도체를 이용한 집광형 고효율 태양전지는 기술 장벽이 매우 높은 기술 집약 산업이므로 독자적인 기술을 확보하게 되면 독점적인 시장을 확보 할 수 있어 미래 고부가 가치 산업으로 적합하다. 특히 III-V족 화합물 반도체 태양전지는 III족 원소(In, Ga, Al)와 V족 원소(As, P)의 조합으로 0.3 eV~2.5 eV까지 밴드갭을 가지는 다양한 박막 제조가 가능하여 다양한 흡수 대역을 가지는 태양전지 제조가 가능하기 때문에 다중 접합 태양전지 제작이 가능하다. 또한 III-V 화합물 반도체는 고온 특성이 우수하여 온도 안정성 및 신뢰성이 우수하고, 또한 집광 시 효율이 상승하는 특성이 있어 고배율 집광형 태양광 발전 시스템에 가장 적합하다. Si 태양전지의 경우 100배 이하의 집광에서 사용하나, III-V 화합물 반도체 태양전지의 경우 500~1000배 정도의 고집광이 가능하다. 이러한 특성으로 III-V 화합물 반도체 태양전지 모듈 가격을 낮출 수 있고, 따라서 Si 태양전지 시스템과 비교하여 발전 단가 면에서 경쟁력을 확보할 수 있다. III-V 화합물 반도체는 다양한 밴드갭 에너지를 가지는 박막 제조가 용이하고, 직접천이(direct bandgap) 구조를 가지고 있어 실리콘에 비해 광 흡수율이 높다. 또한 터널정션(tunnel junction)을 이용하면 광학적 손실과 전기적 소실을 최소화 하면서 다양한 밴드갭을 가지는 태양전지를 직렬 연결이 가능하여 한 번의 박막 증착 공정으로 넓은 흡수대역을 가지며 효율이 높은 다중접합 태양전지 제작이 가능하다. 이에 걸맞게 본연구에서는 화학기상증착장치(MOCVD)를 이용하여 InAsP 나노선을 코어 쉘 구조로 성장하여 태양전지를 제작하였다. P-type Dopant로는 Disilane (Si2H6)을 전구체로 사용하였다. 또한 Benzocyclobutene (BCB) 폴리머를 이용하여 Dielectric을 형성하였고 Sputtering 방법으로 증착한 ZnO을 투명 전극으로 사용하여 나노선 끝부분과 실리콘 기판에 메탈 전극을 형성하였다. 이를 통해 제작한 태양전지는 솔라시뮬레이터로 측정했을때 최고 7%에 달하는 변환효율을 나타내었다.

• Journal of Korean Library and Information Science Society
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• v.49 no.2
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• pp.59-78
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• 2018

This study is to suggest the concrete application plan of BIBFRAME under the development of BIBFRAME as library specific ontology for linked open data. The several research methods are used as the literature reviews, the case study of LC and LD4P, and the survey of cataloging librarians which is to grasp understanding level of the linked data related terms and requirements for constructing LOD. The application plan is suggested as follows. First, publishing name authority data and subject heading in LOD are prominent as the startup with creating terms list or vocabulary in LOD that has been used in library for controlled vocabulary and data value. Second, it is needed to develop BIBFRAME application and extension modeling in Korea, to map KORMARC and the properties and classes of BIBFRAME, and to develop the editor and MARC to BIBFRAME Transformation Tools. Third, the systematical training for cataloging librarians is designed to regard BIBFRAME related works as the librarian's main field. Therefore, this study would contribute to seek the practical application plan for BIBFRAME in Korea.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.11 no.2
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• pp.85-93
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• 2013

This study has been carried out to elucidate the characteristics of the dissolution for Thermal Decomposed Solid Waste of uranium-bearing sludge (TDSW), the removal of impurities by an alkalization in a nitric acid dissolving solution of TDSW, and the selective removal (/recovery) of uranium by an acidification in an carbonate alkali solution, respectively. TDSW generated by thermal decomposition of U-bearing sludge which was produced in the uranium conversion plant operation, was stored in KAERI as a solid-powder type. It is found that the dissolution of TDSW is more effective in nitric acid dissolution than oxidative-dissolution with carbonate. At 1 M nitric acid solution, TDSW was undissolved about 30wt% as a solid residue, and uranium contained in TDSW was dissolved more than 99%. In order to the alkalization for the nitric acid dissolving solution of TDSW, carbonate alkalization is more effective with respect to remove the impurities. At the carbonate alkali solution controlled to about 9 of pH, Al, Ca, Fe and Zn co-dissolved with U in dissolution step was removed about $98{\pm}1%$. On the other hand, U could be recovered more than 99% by an acidification at pH about 3 in a carbonate alkali solution, which was nearly removed the impurities, adding 0.5M $H_2O_2$. It was found that uranium could be selectively recovered (/removed) from TDSW.

• Proceedings of the Korean Vacuum Society Conference
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• 2016.02a
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• pp.337.2-337.2
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• 2016

역 구조 유기태양전지는 가격이 저렴하고 우수한 경량성, 간단한 제조공정 그리고 휘어짐이 가능한 소자를 제작할 수 있는 것이 큰 장점이다. 또한, 광활성층과 전극 사이에 표면개질 물질을 도입하여 에너지장벽을 줄임으로써 소자 전반적인 전하수송을 증가시킬 수 있게 되었다. 나아가 용액공정과 저온 공정을 통해 유기 광전자소자의 roll-to-roll 대면적화 기술을 기반으로 가격대비 성능을 개선시켰다. 본 연구에서는 CdSe 또는 CdSe@ZnS 양자점을 표면개질 유기물질인 polyethylenimine ethoxylated (PEIE)에 정전기적 인력의 결합을 통한 양자점 단일층을 얻었고 이는 전기수송층, 광흡수층 그리고 표면플라즈몬 공명(Surface plasmon resornace)의 역할을 수행하게 되면서 태양전지 전반적인 성능 향상을 관찰 할 수 있었고 양자점 단일층으로 인해 20%가 증가된 에너지변환효율 얻었다. 또한 단일층으로 형성된 CdSe 또는 CdSe@ZnS 양자점 은 $F{\ddot{o}}rster$ resonance energy transfer (FRET) 메커니즘을 통해 PC60BM과 P3HT의 Photo luminescence 세기를 99% 감쇄시켰고, CdSe 양자점을 유기 광활성층인 PTB7:PC71BM에 적용하여 8.1%의 수치를 나타내었다.

• Transactions of the Korean hydrogen and new energy society
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• v.17 no.3
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• pp.338-346
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• 2006

In this paper, the test results of medium-size(120 kW class) PV system which was installed in the Taeahn thermal power station of Korea Western Power Co., Ltd., were summarized for developing the practical technology to applicate high voltage grid connection PV system. The 120 kW photovoltaic system which was consisted of 1,300 modules, PCS, and 150 kVA transformer station has been operated since Aug. 05, 2005. For verifying the modeling results of PV system, the operation data was compared with modeling results which was executed commercial PSCAD/EMTD and Psim tools. An equivalent circuit model of a solar cell has been also used for solar array modeling. A series of parameters required for array modeling have been estimated from general specification data of a solar module. A PWM voltage source inverter(VIS) and its current control scheme have been analyzed by using P&O (perturbation and Observation) MPPT algorithms technique.

• The Transactions of the Korean Institute of Electrical Engineers B
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• v.55 no.1
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• pp.33-38
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• 2006

This paper proposes a simple MPPT control scheme of a based Current-Control-Loop system that can be obtains a lot of advantage to compare with another digital control method, P&O(Perturbation and Observation) and IncCond(Incremental Conductance) algorithm, that is applied mostly a PV system. An existent method is needed an expensive processor such as DSP that calculated to change the measure power of a using current and voltage sensor at the once. Therefore, it is applied a small home power generation system that required many expenses. But, a proposed method is easy to solve the cost reduction and power unbalance Problems that it is used by control scheme to limit error of a current control of common sensor. This proposed algorithm had verified through a simulation and an experiment results on battery charger using PIC that is the microprocessor of a low price.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.5 no.3
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• pp.223-232
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• 1995

Abstract Urea($(NH_2)_2CO$) and THAMP (Tris(hydroxymethyl) aminomethane phosphate) are new organic nonlinear optical materials (NLO) for the device application such as the frequency conversion of laser radiation. The single crystals of urea and THAMP have been grown by the falling temperature method and the temperature difference method. The crystal growth parameters were presented associated with the molphology of the grown crystals. Based on the solubility measurements, methanol was a suitable solvent for the growth of urea. The solubilities of urea have a positive temperature coefficient and the heat of solution of urea was estimated to be -2.58 kcal/mol. The grown crystals of urea have the preferential growth habit in the z-axis. Additives such as $NH_4_H_2PO_4$, KCL, $H_3PO_4$, $CaCl_2{\cdot}2H_2O$, $C_2H_5OH$ were used for the favourable growth in the x - and y-axis and the preventive growth in the z-axis. The moleratio of THAM and H3P04 for the solution of THAMP was 1 : 1. The solubilities of THAMP have a positive temperature coefficient. The heat of solution was estimated to be - 1.70 kcal/ mol.

• Journal of the Society of Naval Architects of Korea
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• v.32 no.3
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• pp.62-71
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• 1995

In the numerical analysis of incompressible unsteady Navier-stokes equation, large time is required for solving the pressure Poisson equation of the elliptic type at each time step. In this paper, a numerical analysis by the direct method is carried out to solve the pressure Poisson equation and the computing time is analyzed as mesh size increases. The pressure Poisson equation can be transformed to the boundary value problem by the Green theorem. The computing time for the convolution type of the domain integral can be reduced by using F.F.T. and the computing time in the direct method depends entirely on obtaining the solution of the boundary value problem. The numerical analysis on the known solutions is carried out and compared for the verification of the direct method. And the numerical analysis on the body boundary and domain decomposition problem are carried out with the computing time less than O($n^{3}$) in the (n.n) mesh.

• Journal of the Microelectronics and Packaging Society
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• v.18 no.1
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• pp.23-27
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• 2011

Fabrication of porous silicon(PS) double layer by electrochemical etching is the first step in process of ultrathin solar cell using PS layer transfer process. The porosity of the porous silicon layer can be controlled by regulating the formation parameters such as current density and HF concentration. PS layer is fabricated by electrochemical etching in a chemical mixture of HF and ethanol. For electrochemical etching, highly boron doped (100) oriented monocrystalline Si substrates was used. Ths resistivity of silicon is $0.01-0.02\;{\Omega}{\cdot}cm$. The solution composition for electrochemical etching was HF (40%) : $C_2H_5OH$(99 %) : $H_2O$ = 1 : 1 : 2 (by volume). In order to fabricate porous silicon double layer, current density was switched. By switching current density from low to high level, a high-porosity layer was fabricated beneath a low-porosity layer. Etching time affects only the depth of porous silicon layer.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.08a
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• pp.305-305
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• 2013

태양전지는 무기태양전지와 유기태양전지 등이 연구 되고 있는데 [1] 그 중 유기물질의 장점(높은 수율, solution phase processing, 저비용으로 전력 생산)과 무기재료의 장점(높은 전자 이동도, 넓은 흡수 범위, 우수한 환경 및 열 안정성)을 융합함으로써 장기적 구조안정성의 확보와 광전변환의 고 효율화를 동시에 달성하기 위한 유기무기 하이브리드 태양전지가 최근 큰 관심을 끌고 있다[2]. 본 연구에서는 hybrid photovoltaics에 유기물 MDMO-PPV와 전도성 고분자 PEDOT:PSS를 무기물 GaN 위에 spin coating 하여 두께에 다른 효율을 측정하였다. 유기물 MDMO-PPV는 p-형으로 클로로벤젠, 톨루엔과 같은 유기 용매에 잘 녹으며 HOMO 5.33eV, LUMO 2.97eV, energy band gap 2.4eV이며 99.5%의 순도 물질을 사용하였다. 또한 정공 수송층(hole transport layer, HTL)으로 PEDOT:PSS를 사용하였으며, HOMO 5.0eV, LUMO 3.6eV, energy band gap 1.4eV를 가지며 증류수나 에탄올과 같은 수용성 용매에 잘 녹는 특성을 가지고 있다. 무기물은 III-V 족 물질 n-GaN(002)을 사용하였고 valence band energy 1.9eV, conduction band energy 6.3eV, energy band gap 3.4eV, 높은 전자 이동도와 높은 포화 속도, 광전자 소자에 유리한 광 전기적 특성을 가지고 있다. 기판으로는 GaN와 격자 부정합도와 열팽창계수 부정합도가 큰 Sapphire (Al2O3) 이종 기판을 사용하였다. 전극으로 Au를 사용하였으며 E-beam증착하였다. Reflector로서 Al를 thermal evaporator로 증착하였다 [3]. 실험 과정은 두께에 따른 효율을 알아보기 위해 MDMO-PPV를 900~1,500 rpm으로 spin coating 하였고, 열처리에 따른 효율을 알아보기 위해 열처리 온도 조건을 $110{\sim}170^{\circ}C$의 변화를 주었다. FE-SEM으로 표면과 단면을 관찰하였으며 J-V 특성을 알아보기 위해 각 샘플마다 solar simulator를 사용하여 측정하였고 그 결과를 논의하였다.