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Separation of Hydrogen-Nitrogen Gases by PTMSP/PDMS-Borosilicate Composite Membranes (PTMSP/PDMS-Borosilicate 복합막에 의한 수소-질소 기체 분리에 관한 연구)

  • Lee, Suk Ho;Lee, Hyun Kyung
    • Membrane Journal
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    • v.25 no.2
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    • pp.123-131
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    • 2015
  • The PTMSP/PDMS graft copolymer were synthesized from the PTMSP[poly(1-trimethylsilyl-1-propyne)] and the PDMS[poly(dimethylsiloxane)] and then the PTMSP/PDMS-borosilicate composite membranes were prepared by adding the porous borosilicates to the PTMSP/PDMS graft copolymer. The number-average molecular weight (${\bar{M}}_n$) and the weight-average molecular weight (${\bar{M}}_w$) of PTMSP/PDMS graft copolymer were 460,000 and 570,000 respectively, and glass transition temperature ($T_g$) of PTMSP/PDMS graft copolymer appeared at $33.53^{\circ}C$ according to DSC analysis. According to the TGA measurements, the addition of borosilicate to the PTMSP/PDMS graft copolymer leaded the decreased weight loss and the completed weight loss temperature went down. SEM observation showed that borosilicate was dispersed in the PTMSP/PDMS-borosilicate composite membranes with the size of $1{\sim}5{\mu}m$. Gas permeation experiment indicated that the addition of borosilicate to PTMSP/PDMS graft copolymer resulted in the increase in free volume, cavity and porosity resulting in the gradual shift of the mechanism of the gas permeation from solution diffusion to molecular sieving surface diffusion, and Knudsen diffusion. Consequently, the permeability of $H_2$ and $N_2$ increased and selectivity ($H_2/N_2$) decreased as the contents of borosilicate increased.

Development of Intelligent GNSS Positioning Technique Based on Low Cost Module for an Alley Navigation (골목길 내비게이션을 위한 저가 모듈 기반의 지능형 GNSS 측위 기술 개발)

  • Kim, Hye In;Park, Kwan Dong
    • Journal of Korean Society for Geospatial Information Science
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    • v.24 no.3
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    • pp.11-18
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    • 2016
  • Since GNSS signals get blocked by buildings in urban canyons or narrow alleys, it is very difficult to secure a enough number of visible satellites for satellite navigation in those poor signal-reception environments. In those situations, one cannot get their coordinates or obtain accurate positions. In this study, a couple of strategies for improving positioning accuracy in urban canyons were developed and their performance was verified. First of all, we combined GPS and GLONASS measurements together and devised algorithms to quality-control observed signals and eliminate outliers. Also, a new multipath reduction scheme was applied to minimize its effect by utilizing SNR values of the observed signals. For performance verification of the developed technique, a narrow alley of 10m width located near the back gate of the Inha University was selected as the test-bed, and then we conducted static and kinematic positioning at four pre-surveyed points. We found that our new algorithms produced an 45% improvement in an open-sky environment compared with the positioning result of a low-cost u-blox receiver. In the alleys, 3-D accuracy improved by an average of 37%. In the case of kinematic positioning, especially, biases showing up in regular receivers got eliminated significantly through our new filtering algorithms.

Estimating Quantiles of Extreme Rainfall Using a Mixed Gumbel Distribution Model (혼합 검벨분포모형을 이용한 확률강우량의 산정)

  • Yoon, Phil-Yong;Kim, Tae-Woong;Yang, Jeong-Seok;Lee, Seung-Oh
    • Journal of Korea Water Resources Association
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    • v.45 no.3
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    • pp.263-274
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    • 2012
  • Recently, due to various climate variabilities, extreme rainfall events have been occurring all over the world. Extreme rainfall events in Korea mainly result from the summer typhoon storms and the localized convective storms. In order to estimate appropriate quantiles for extreme rainfall, this study considered the probability behavior of daily rainfall from the typhoons and the convective storms which compose the annual maximum rainfalls (AMRs). The conventional rainfall frequency analysis estimates rainfall quantiles based on the assumption that the AMRs are extracted from an identified single population, whereas this study employed a mixed distribution function to incorporate the different statistical characteristics of two types of rainfalls into the hydrologic frequency analysis. Selecting 15 rainfall gauge stations where contain comparatively large number of measurements of daily rainfall, for various return periods, quantiles of daily rainfalls were estimated and analyzed in this study. The results indicate that the mixed Gumbel distribution locally results in significant gains and losses in quantiles. This would provide useful information in designing flood protection systems.

Analyzing the Efficiency of Defense Basic Research Projects using DEA (자료포락분석(DEA)을 활용한 국방 기초연구개발 사업의 효율성 분석)

  • Lim, Yong-Hwan
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.7
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    • pp.517-524
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    • 2020
  • In line with the recent wave of the 4th Industrial Revolution, the environment for defense R&D is transforming into a center of high-tech military technology. In particular, developed countries are strengthening control of technology exports and technology transfer to protect advanced defense science and technology. For this reason, the budget demand for securing the ability to develop independently high-tech weapons and core technologies suitable for the future battlefield environment is increasing, and increasing efficiency in R&D investment has been highlighted for efficient distribution of limited budgets. This study examined the efficiency of the defense basic R&D project using the non-parametric approach, DEA. The R&D budget, R&D researcher, and R&D period were selected as the input variables, and the number of papers and patents were used as output variables. The efficiency of basic R&D projects was analyzed through CCR, BCC models, and SE. Lastly, based on the efficiency measurements, the cause of the inefficiency of R&D projects was suggested, and ways to improve efficiency were suggested. This study is expected to be used as useful information that can be applied to project performance management through efficiency analysis of basic defense R&D projects and be reflected in the project planning stage through feedback.

Estimation of Structural Deformed Shapes Using Limited Number of Displacement Measurements (한정된 계측 변위를 이용한 구조물 변형 형상 추정)

  • Choi, Junho;Kim, Seungjun;Han, Seungryong;Kang, Youngjong
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.33 no.4
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    • pp.1295-1302
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    • 2013
  • The structural deformed shape is important information to structural analysis. If the sufficient measuring points are secured at the structural monitoring system, reasonable and accurate structural deformation shapes can be obtained and structural analysis is possible using this deformation. However, the accurate estimation of the global structural shapes might be difficult if sufficient measuring points are not secure under cost limitations. In this study, SFSM-LS algorithm, the economic and effective estimation method for the structural deformation shapes with limited displacement measuring points is developed and suggested. In the suggested method, the global structural deformation shape is determined by the superposition of the pre-investigated structural deformed shapes obtained by preliminary FE analyses, with their optimum weight factors which lead minimization of the estimate errors. 2-span continuous bridge model is used to verify developed algorithm and parametric studies are performed. By the parametric studies, the characteristics of the estimation results obtained by the suggested method were investigated considering essential parameters such as pre-investigated structural shapes, locations and numbers of displacement measuring points. By quantitative comparison of estimation results with the conventional methods such as polynomial, Lagrange and spline interpolation, the applicability and accuracy of the suggested method was validated.

Effects of Microstructure and Plate Orientation on the Acoustic Emission Behavior of an Al-Li 8090 Alloy (Al-Li 8090 합금의 미세조직과 이방성에 따른 음향방출 거동)

  • Lee, K.A.;Lee, C.S.;Jeong, H.D.
    • Journal of the Korean Society for Nondestructive Testing
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    • v.16 no.4
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    • pp.215-224
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    • 1997
  • A study has been made to investigate the acoustic emission(AE) behavior during the tensile and fracture tests of an Al-Li 8090 alloy, and to correlate it with the deformation mechanisms as a function of microstructure and plate orientation. Mechanical tests and AE measurements were conducted on the specimens with different microstructures (the ${\delta}'$ phase dominant microstructure and the $S'+{\delta}'$ microstructure) and with different orientations (L and ST). In the ${\delta}'$ structure, continuous emissions were produced in both the L and ST oriented specimens, while only the burst emissions were observed to occur in the $S'+{\delta}'$ structure. It was inferred from the above results that continuous type emissions were mainly attributed to the shearing of coherent ${\delta}'$ precipitates in the ${\delta}'$ structure, while the burst type emissions were produced due to the shearing or microcracking of incoherent S' phase in the $S'+{\delta}'$ structure. As to the effect of plate orientation, the ST oriented specimens showed more burst emissions than the LT oriented ones. A large number of burst emissions produced in the ST specimen were presumably due to the rapid crack propagation along the intergranular boundary located parallel to the crack propagation direction.

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Preparation of Porous Polyacrylonitrile Nanofibers Membrane for the MF Application (MF 적용을 위한 다공성 PAN 나노섬유막의 제조)

  • Ahn, Hyeonryun;Jang, Wongi;Tak, Taemoon;Byun, Hongsik
    • Membrane Journal
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    • v.23 no.2
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    • pp.112-118
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    • 2013
  • Polyancrylonitrile nanofiber membrane (PAM) was prepared by using the electrospinning method with a solution of polyacrylonitrile (PAN) in DMF. The pore-diameter of PAMs and the number of PAM's layer were controlled for the microfiltration (MF) application. In addition, in order to improve the water-flux, AN-PEGMA copolymers have been synthesized via free radical polymerization with poly (ethylene glycol) methyl ether methacrylate and azobisisobutylronitrile (AIBN), and then PAN/AN-PEGMA nanofiber membranes (PAM/APM) were prepared by electrospinning with a mixture of PAN (9 wt%) and AN-PEGMA (3 wt%) in DMF (88 wt%). The prepared membranes were investigated with FT-IR and E.D.S. It was confirmed through scanning electron microscope (SEM), porometer, and porosity analysis that the porous membrane with a uniform diameter (400~600 nm) and a uniform pore characteristics (0.5~0.4 ${\mu}m$) was prepared. For the MF application, water-flux measurements were investigated and then the result was shown that the water permeability value of PAM/APMs introduced AN-PEGMA copolymers was relatively higher than that of the PVdF commercial membrane. From these results, PAN nanofiber membranes prepared by electrospinning could be utilized as a MF membrane.

Study on Temperature Dependence of Molecular Structure in Stearic Acid LB Films Using FTIR-RAS (FTIR-RA 분광법을 이용한 스테아르산 단분자막에서 분자구조의 온도의존성 고찰)

  • Kim, Dong Won;Park, Sang Rae;Umemura Junjo;Takeda Satoshi;Hasegawa Takeshi;Takenaka Tohru;Lee Hai Won
    • Journal of the Korean Chemical Society
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    • v.37 no.6
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    • pp.570-576
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    • 1993
  • 1-, 3-, 9-, and 21-Monolayer Langmuir-Blodgett(LB) films of stearic acid were deposited on silver-coated glass slides at the surface pressure of 30 mN/m. Fourier transform infrared(FTIR) reflection-absorption spectra (RAS) of these LB films were recorded at various temperatures from 31 to $72^{\circ}C.$ The spectra at $31^{\circ}C$ exhibited characteristic features of highly perpendicular orientation of the hydrocarbon chain. In the 1-monolayer LB film, the C=O stretching band was not observed, presumably due to the image dipole effect on the silver surface. In the 1-and 3-monolayer LB films, the trans isomer of stearic acid was prominent, but the cis isomer was dominant in the 21-monolayer LB film. FTIR-RAS measurements at an elevated temperature indicated that the chain melting temperature increases and approached to the bulk melting point with increasing the number of monolayer, except for the 1-monolayer LB film which has a higher melting temperature than the 3-monolayer film due to the strong interaction with the silver substrate.

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Analysis of Lake Water Temperature and Seasonal Stratification in the Han River System from Time-Series of Landsat Images (Landsat 시계열 영상을 이용한 한강 수계 호수 수온과 계절적 성충 현상 분석)

  • Han, Hyang-Sun;Lee, Hoon-Yol
    • Korean Journal of Remote Sensing
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    • v.21 no.4
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    • pp.253-271
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    • 2005
  • We have analyzed surface water temperature and seasonal stratification of lakes in the Han river system using time-series Landsat images and in situ measurement data. Using NASA equation, at-satellite temperature is derived from 29 Landsat-5 TM and Landsat-7 ETM+ images obtained from 1994 to 2004, and was compared with in situ surface temperature on river-type dam lakes such as Paro, Chuncheon, Euiam, Chongpyong, Paldang, and with 10m-depth temperature on lake-type dam lake Soyang. Although the in situ temperature at the time of satellite data acquisition was interpolated from monthly measurements, the number of images with standard deviation of temperature difference (at-satellite temperature - in situ interpolated temperature) less than $2^{\circ}C$ was 24 on which a novel statistical atmospheric correction could be applied. The correlation coefficient at Lake Soyang was 0.915 (0.950 after correction) and 0.951-0.980 (0.979-0.997 after correction) at other lakes. This high correlation implies that there exist a mixed layer in the shallow river-like dam lakes due to physical mixing from continuous influx and efflux, and the daily and hourly temperature change is not fluctuating. At Lake Soyang, an anomalous temperature difference was observed from April to July where at-satellite temperature is $3-5^{\circ}C$ higher than in situ interpolated temperature. Located in the uppermost part of the Han river system and its influx is governed only by natural precipitation, Lake Soyang develops stratification during this time with rising sun elevation and no physical mixture from influx in this relatively dry season of the year.

Comparative Insect Biodiversity Analyses on the Agricultural Ecosystems of Goesan District of Korea (괴산군 지역 농업 생태계의 곤충 다양성 비교 분석)

  • Kim, Hoon;Sun, Yan;Lee, Seung-Min;Ku, Bon-Jin;Ku, Yun-Mo;Kim, Tae-Yeon;Moon, Myung-Jin
    • Korean Journal of Organic Agriculture
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    • v.29 no.4
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    • pp.539-559
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    • 2021
  • Agricultural ecosystem biodiversity monitoring and community variation analysis of insects were conducted from 2016 to 2018 in selected conventional and organic farming fields in Goesan district, Chungcheongbuk-do, South Korea. The total number of 1,125 species in 16 orders and 207 families were identified. The numbers of species collected in the locations practicing organic farming were greater than the conventional farming both in the paddy fields (564 vs. 383 species) and the upland fields (471 vs. 365 species). Among them, Hemiptera had the most abundant of species, followed by Diptera, Hymenoptera, Coleoptera and Araneae. We calculated various index values of biodiversity (diversity index H', richness index R, evenness index J', dominance index D, and similarity index QS) based on quantitative measurements of species and individuals collected over three years of field monitoring. Variations in biodiversity index values in different agricultural systems show that the positive effect of organic farming is to produce more biodiversity than conventional farming systems. When compared to other index results reported in Korea, Japan and China, the richness index was higher and other index values were at similar levels.