• Title/Summary/Keyword: nucleation

Search Result 1,111, Processing Time 0.03 seconds

Effect of Hexa-methylenetetramine (HMT) on Nucleation and Growth Behaviors of Ni(OH)2 Nanosheets Produced by Electrodeposition (전착법으로 제작한 Ni(OH)2 나노 시트의 핵 형성과 성장 거동에 미치는 헥사-메틸렌테트라민(HMT)의 영향)

  • Kim, Dong Yeon;Son, Injoon;Choi, Mun-Hyun
    • Journal of the Korean institute of surface engineering
    • /
    • v.54 no.1
    • /
    • pp.37-42
    • /
    • 2021
  • Electrodeposition is a synthetic method that allows fine control of the nucleation and growth factors of metals and is a suitable method for studying the nucleation and growth of Ni(OH)2. Hexa-methylenetetramine (HMT) helps to form Ni(OH)2 nanosheets by increasing the OH- of the nickel precursor solution and helps to improve the electrochemical properties of the electrode. In this study, the structural properties of Ni(OH)2 nanosheets according to the HMT concentration change using electrodeposition were studied. As the concentration of HMT increased, the size and thickness of the Ni(OH)2 nanosheet adsorbed on the surface increased and porosity increased. Also, the Scharifker-Hills nucleation theory model and experimental data were compared. In conclusion, the nanosheet shape of the HMT 7.5 mM sample electrodeposited with -0.85 V vs. Ag/AgCl grew most uniformly, and the best result was obtained as an electrode material for a pseudocapacitor.

Analysis of Initial Stage of Copper Electrodeposition for Fine Pattern (미세패턴용 구리도금시 초기 전착 거동 해석)

  • 조차제;최창희;김상겸;박대희
    • The Transactions of the Korean Institute of Electrical Engineers C
    • /
    • v.52 no.4
    • /
    • pp.164-168
    • /
    • 2003
  • The initial stage of copper electrodeposition has been known to be very important role for morphology and physical properties after final growth. The factors affecting the nucleation are electrode, current density, electrolyte and temperature. Current studies has illuminated the initial nucleation of copper electrodeposition in the viewpoint of the surface status of electrode and analyzed using EIS and SEM observation

Nucleation kinetics and technology design for crystal growth from aqueous solution

  • Kidyarov, B.I.
    • Journal of the Korean Crystal Growth and Crystal Technology
    • /
    • v.13 no.2
    • /
    • pp.51-55
    • /
    • 2003
  • The interrelation into nucleation and thermodynamic parameters of solutions has been established by plotting of various dependencies: the enthalpy of dissolution, solubility product and super-solubility on ionic salt radii and also the extent of deviation from an ideal Debye -Huckel model of electrolyte solution on solubility product. The possible methods of perfect crystal growth from aqueous solution have been found a priori by separating of known set of pair values of solubility and super-solubility into no less than six-nine characteristic and distinctive sub-sets.

Phase Separation of Lennard-Jones Particles Using Molecular Dynamics and Brownian Dynamics Simulations

  • Jeong, Ji-Yun;Lee, Ju-Min;Kim, Jun-Su
    • Proceeding of EDISON Challenge
    • /
    • 2014.03a
    • /
    • pp.169-182
    • /
    • 2014
  • 이 연구에서는 Lennard-Jones (LJ) particle을 이용하여 상분리 현상을 이해하기 위한 컴퓨터 시뮬레이션 연구를 수행하였다. 초기에 균일하게 분포되어 있는 LJ 입자들을 시뮬레이션 하면 상대적으로 dense phase와 dilute phase로 상분리 현상이 일어나게 된다. 상분리 현상의 첫 번째 단계를 핵 생성 (nucleation) 이라고 한다. 본 연구에서는 Brownian Dynamics (BD) Simulation과 Molecular Dynamics (MD) Simulation을 이용하여 상평형 그림을 구하고 초기에 일어나는 LJ 입자들의 nucleation rates를 구하였다.

  • PDF

Crystallization in Li$_2$O-A1$_2$O$_3$-SiO$_2$ Glass induced by 355 nm Nd:YAG Laser Irradiation

  • Lee, Yong-Su;Kang, Won-Ho
    • Journal of the Microelectronics and Packaging Society
    • /
    • v.7 no.2
    • /
    • pp.43-46
    • /
    • 2000
  • Nd:YAG laser of 355 nm wavelength, which amounts to 3.5 eV, produced by a harmonic generator was used to create Ag metallic particles as seeds for nucleation in photosensitive glass containing $Ag^+$ and $Ce^{3+}$ . The pulse widths and frequency of the laser were 8ns and 10 Hz, respectively. For crystalline growth, heat-treatment following laser irradiation was carried out at $570^{\circ}C$ for 1h. Then, the $LiAlSi_3O^8$ crystal phase appeared in the laser irradiated lithium aluminum silicate glass. We present the effect of laser-induced nucleation compared with spontaneous nucleation by heat treatment fur crystallization in the glass.

  • PDF

Bubble Formation in Liquid Helium under Negative Pressure by Quantum Tunneling near Absolute Zero Temperature (절대 0도 부근에서 양자터널링에 의한 헬리움(He)액체의 부압하에서의 기포형성)

  • Kwak, H.;Jung, J.;Hong, J.
    • Proceedings of the KSME Conference
    • /
    • 2001.06d
    • /
    • pp.354-359
    • /
    • 2001
  • As the temperature of liquid under negative pressure approaches the absolute zero, the nucleation process due to thermal fluctuations hardly occurs. Instead of this mechanism, quantum fluctuations may lead the formation of nucleus for new phase in metastable state. In this study, the thermal as well as quantum nucleation bubble in liquid helium under negative pressure was investigated theoretically. The energy barrier against nucleation was estimated by molecular interaction due to the Londom dispersion force. It is shown that the phase transition from liquid to vapor in is possible due to the quantum tunneling below 0.2 K for Helium-4 and 0.1 K for Helium-3, at negative pressures close to the ideal tensile strength at which every liquid molecules become bubbles simultaneously.

  • PDF

Combustion and Microexplosion of AI/Liquid Fuel Slurry Droplets(II)-Theoretical Study- (Al/액체연료 슬러리 액적의 연소와 미세폭발 (II)-이론적 연구-)

  • Jo, Ju-Hyeong;Byeon, Do-Yeong;An, Guk-Yeong;Baek, Seung-Uk
    • Transactions of the Korean Society of Mechanical Engineers B
    • /
    • v.22 no.6
    • /
    • pp.813-822
    • /
    • 1998
  • The microexplosion of a slurry droplet was considered to be caused by the shell formation and the following pressure build-up in the shell which would be promoted by the suppression of evaporation, subsequent superheating and heterogeneous nucleation of liquid carrier. To closely investigate the pressure build-up and the heterogeneous nucleation, a numerical model was introduced by considering the internal temperature distributions with the shell formation, suppression of evaporation and pressure build-up inside. The microexplosion time was estimated by postulating the limit of superheat for heterogeneous nucleation. The simulation yielded a reasonably good agreement with experimental results for Al/n-heptane slurry droplets under various solid loadings.

Defects Nucleation in the Liquid Crystal Director Field from Inhomogeneous Surface

  • Lee, Gi-Dong;Lee, Jong-Wook;Ko, Tae-Woon;Lee, Joun-Ho;Oh, Chang-Ho;Choi, Hyun-Chul;Kim, Jae-Chang
    • 한국정보디스플레이학회:학술대회논문집
    • /
    • 2004.08a
    • /
    • pp.1159-1162
    • /
    • 2004
  • A modeling of the nucleation and dynamical behavior of defects from an inhomogeneous surface configuration using fast Q-tensor method is realized. On modeling the defect nucleation and dynamics, A fast Q-tensor method is applied. From the numerical modeling, we confirmed that surface inhomogeneity which makes strong strain energy in the local liquid crystal director field could cause defects. Experimental result has compared with numerical modeling in order to verify the simulation of the defect nucleation.

  • PDF

Mechanism, Function and Regulation of Microtubule-Dependent Microtubule Amplification in Mitosis

  • Zhu, Hui;Fang, Kayleen;Fang, Guowei
    • Molecules and Cells
    • /
    • v.27 no.1
    • /
    • pp.1-3
    • /
    • 2009
  • Mitotic spindle mediates the segregation of chromosomes in the cell cycle and the proper function of the spindle is crucial to the high fidelity of chromosome segregation and to the stability of the genome. Nucleation of microtubules (MTs) from centrosomes and chromatin represents two well-characterized pathways essential for the assembly of a dynamic spindle in mitosis. Recently, we identified a third MT nucleation pathway, in which existing MTs in the spindle act as a template to promote the nucleation and polymerization of MTs, thereby efficiently amplifying MTs in the spindle. We will review here our current understanding on the molecular mechanism, the physiological function and the cell-cycle regulation of MT amplification.

Polysulfone 제막공정중 Morphology의 형성에 관한 연구

  • 김성철;김제영;백기전;이환광
    • Proceedings of the Membrane Society of Korea Conference
    • /
    • 1997.10a
    • /
    • pp.11-15
    • /
    • 1997
  • Liquid-liquid phase separation에는 nucleation and growth와 spinodal decomposition의 2가지 경로가 있다. 상온에서 고농도의 고분자 용액과 저량의 비용매의 조성의 근처에는 용해도 갭으로 들어가게 되면 비용매에 아주 미량의 고분자가 있는 조성을 갖는 핵이 고분자 용액 내에서 형성되고 이러한 핵은 여러게가 액적의 형태로 주위의 고분자 용액의 gelation에 의해서 성장이 멈출 때까지 커지게 된다. 여기서 어떤 고분자 상이 nucleation되는지가 매우 중요하게 된다. 실제 우리가 상전이 막을 제조할 경우는 대부분 10wt% 이상의 고분자 농도이므로 polymer-poor상이 nucleation이 된다. Spinodal decomposition의 경우는 용해도 갭을 빠르게 통과해서 nucleation이 일어나지 않고 spinodal line을 지나는 경우이다. 이러한 경우의 용액은 매우 불안정해서 약간의 농도 변화에도 자발적인 상분리가 일어나서 polymer-poor상과 polymer-rich상이 서로 얽혀져 있는 network구조를 형성하게 된다.

  • PDF