• 분석과학
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• 제5권2호
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• pp.153-158
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• 1992

본 연구에서는 이동상 성질이 GC와 HPLC와는 전혀 다른 초임계 유체 크로마토그래피(SFC)를 사용함으로써 종래의 크로마토그래피의 방법으로는 분석하기 힘든 물질을 분석하는 방법을 개발하였다. GC로는 분리하기 힘든 긴 고리를 가진 Hydrocarbons이나 Mink Oils, Soybean oils 등이 SFC로 잘 분리될 수 있었다. 그 이유는 SFC에서는 시료가 갖고 있는 낮은 기화성이나 열에 불안정한 점 등이 이동상을 초임계 상태의 이산화탄소를 사용함으로써 극복되어질 수 있었다. 이 연구에서는 한걸음 더 나아가 극성이 강한 지방산 및 농약류를 분석하는 방법을 개발함으로써 SFC의 가장 큰 약점인 극성이 있는 시료의 처리 문제를 극복하고자 시도하였다.

• 한국분무공학회지
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• 제19권2호
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• pp.55-63
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• 2014

Pyrolysis oil (PO), also known as Bio crude oil (BCO), has the potential to displace significant amounts of fuels that are currently derived from petroleum sources. PO has been regarded as an alternative fuel for petroleum fuels to be used in diesel engine. However, the use of PO in a diesel engine requires modifications due to low energy density, high water contents, low acidity, and high viscosity of the PO. One of the easiest way to adopt PO to diesel engine without modifications is emulsification of PO with the fuels that has higher cetane number. However, PO that has high amount of polar chemicals is immiscible with non polar hydrocarbons of diesel. Thus, to stabilize a homogeneous phase of diesel-PO blends, a proper surfactant should be used. In this study, a DI diesel engine operated with diesel and diesel-PO emulsions was experimentally investigated. Performance and gaseous & particle emission characteristics of a diesel engine fuelled by diesel-PO emulsions were examined. Results showed that stable engine operation was possible with the emulsions and engine output power was comparable to diesel operation.

• Bulletin of the Korean Chemical Society
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• 제16권6호
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• pp.524-528
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• 1995

The reaction of [IrCl(cod)]2 with ppol ligand, Ph2PCH2CH2CH2P(Ph)CH2CH2CH=CH2, in ethanol gives an iridium complex, whose structure is converted from an ionic form, [Ir(cod)(ppol)]Cl·2C2H5OH (1),in polar solvents (ethanol, methanol and acetonitrile), to a molecular form, [IrCl(cod)(ppol)], in non-polar solvents (benzene and toluene). The cationic complexes, [Ir(cod)(ppol)]AsF6·1/2C2H5OH and [Ir(cod)(ppol)]PF6·1/2CH3CN, were prepared to compare with the ionic form by 31P NMR spectroscopy. When carbon monoxide is introduced to 1, cod is replaced by CO to give the 5-coordinated complex, [IrCl(CO)(ppol)]. Hydrogenation of 1-octene was not successful in the presence of 1. In order to verify the reason for 1 not behaving as a good catalyst for hydrogenation, electrophilic reactions with HCl, I2 and HBF4·etherate were performed, which yielded the oxidative addition product, [IrHCl2(ppol)], the substitution product, [IrI(cod)(ppol)], and another cationic product, [Ir(cod)(ppol)]BF4, respectively. Thus, the iridium complex is not sufficiently basic to activate hydrogen atoms or the olefin of the ppol ligand.

• 접착 및 계면
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• 제4권4호
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• pp.1-6
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• 2003

대기압 플라즈마를 이용하여 폴리프로필렌 필름의 표면을 처리한 후 각각 극성 용매(water)와 비극성 용매(diiodomethane)를 사용한 접촉각 측정기로 필름 표면의 접촉각을 측정하였다. 측정된 접촉각을 이용해 표면 자유에너지 변화를 계산한 후 대기압 플라즈마 처리 전후의 폴리프로필렌 필름의 접촉각과 표면 자유에너지 상태를 비교, 분석하였다. 또한 대기압 플라즈마의 처리 조건을 바꿔가며 폴리프로필렌 필름 표면을 처리함으로써 접촉각과 표면 자유에너지가 각각의 처리 조건에 따라 어떠한 영향을 받는지 연구하였다. 대기압 플라즈마 처리 조건에 따라 접촉각 및 표면 자유에너지는 최적값을 보여주거나 일정한 값에 도달하는 경향을 보여 주었다.

• 생약학회지
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• 제51권4호
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• pp.264-269
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• 2020

The study aimed to characterize chemical composition and anticancer property of the n-hexane fraction derived from Asiasari Radix et Rhizoma. The anticancer activity was evaluated on a panel of cancer cell lines including HN22, HSC2, HSC3, and HSC4 cells (human oral cancer), HCC827 and HCC827GR cells (human lung cancer), and KYSE30 and KYSE450 (human esophageal cancer) by MTS assay. As a result, The least polar subfraction from n-hexane-soluble layer displayed notable cytotoxicity on the tumor cell lines with IC50 ranging from 1.20 to 17.0 ㎍/ml. The chemical composition of constituents in the active subfraction was determined by gas chromatography-mass spectrometry (GC-MS). The essential oils comprised of sesquiterpenes including β-gurjunene (7.45%), γ-amorphene (6.61%), guaia-6,9-diene (6.40%), δ-guaiene (5.21%) and a phenylpropanoid, safrole (0.49%) were mainly identified in addition to long-chain hydrocarbons including n-heptadecane (24.60%), 7-hexadecene (4.44%) and a diterpenoid, ent-kaur-16-ene (6.57%).

• Korean Chemical Engineering Research
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• 제60권1호
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• pp.169-174
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• 2022

본 연구에서는 Taxus chinensis 유래 파클리탁셀의 회수 효율을 개선하기 위하여, 물 및 헥산의 순차적 세척 공정을 개발하였다. 물 세척은 시료/물 비 1:40 (w/v)에서 10 분 동안 세척함으로써 시료에 포함되어 있는 극성불순물을 효과적으로 제거할 수 있었다. 헥산 세척은 시료/헥산 비 1:160 (w/v)에서 20 분 동안 세척함으로써 시료에 포함되어 있는 비극성 불순물을 효과적으로 제거할 수 있었다. 물과 헥산의 순차적 세척을 통하여 비교적 짧은 공정 시간(~30 분)에 파클리탁셀 순도 30% 이상을 얻을 수 있었다.

• Asian-Australasian Journal of Animal Sciences
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• 제20권1호
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• pp.36-40
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• 2007

Proteins and lipids not only provide a source of energy to the cell, but also play vital roles in modifying the physical properties and function of the biological membranes. In the present study, we investigated the biochemical constituents, viz. proteins and lipids, in growing oocytes of goat antral follicles during summer and winter seasons. Goat genitalia in phosphate buffered saline (pH 7.4) were brought to the laboratory within one hour of slaughter under aseptic conditions at $37^{\circ}C$. Oocytes were aspirated from normal small (<3 mm in diameter) and large (>3 mm) follicles and pooled for biochemical estimations. A significant increase in the amount of protein and lipid was observed with the growth of the oocyte. The amount of protein varied non-significantly with the season, while the amount of lipid varied significantly. The amounts of phospholipid, cholesterol, free fatty acid, and triglyceride increased with the growth of the oocyte, but no significant effect of season in these constituents was observed. Lysolecithin, sphingomyelin, and sterols were the polar lipids identified in both oocytes prepared from small follicles (small oocytes) as well as large follicles (large oocytes). In addition, the small oocytes also contained phosphatidyl serine, while large oocytes contained phosphatidyl glycerol phosphate and phosphatidyl inositol. Among non-polar lipids, triglycerides and long chain alcohols appear only in small oocytes and not in large oocytes. Monoglycerides, 1,2-diglycerides, 1,3-diglycerides and o-dialkyl glycerol ethers, fatty acids, fatty acid methyl esters, and wax esters were identified in both small and large oocytes. Information on biochemical composition of growing oocytes is relevant to oocyte and embryo competence, culture and cryopreservation.

• The Korean Journal of Ecology
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• 제17권4호
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• pp.501-511
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• 1994

Dynamics of nutrients, non-polar, water solubles, acid solubles and acid insolubles (lignin) in decomposing litter were investigated for 2 years in the oak, Quercus acutissima, and the pitch pine, Pinus rigida, stands in the vicinity of Kongju, Chungnam Province. Nitrogen and phosphorus conetrations in decomposing litter increased with time elapsed, however, potassium decreased rapidly within three months and then remined constant with time elapsed. Calcium concentration in needle litter during experimental period was lower than that of initial concentration in needle litter during experimental period was lower than that of initial concentration, and showed no significant variation with time elapsed. Calcium concentration in oak litter during the experimental period, however, were higher than that of initial concentration. Magnesium concentration in oak litter decreased repidly during six months, and then remaines constant thereafter. Annual amount of nitrogen, phosphorus, potassium, calcium and magnesium which returned to soil via litter decomposition in the oak and the pitch pine stands was $3.3g/m^2$ and $0.9g/m^2$ for N, $0.03g/m^2$ and $0.01g/m^2$ for P, $1.3g/m^2$ and $0.7g/m^2$ for K, $0.7g/m^2$ and $1.2g/m^2$ for Ca, $0.9g/m^2$ and $0.4g/m^2$ for Mg, respectively. Non-polar, and water- and acid-soluble fractions in decomposing litter decreased and lignin increased with time.

• 전기학회논문지P
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• 제63권4호
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• pp.361-367
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• 2014

This paper is related to a new solar power conditioner for a built-in step-up chopper function. In the first step-up chopper proposed solar PV power conditioner for mutually connected in series with the input voltage of the bypass diodes are respectively connected to the positive terminal should install the mutual boosting chopper diode connected in series with the boost chopper switching element between the two power supply and at the same time the first and the second was connected to a second diode and a resonance inductor and a snubber capacitor in series with each other. And the common connection point between the bypass diode and the step-up chopper and the step-up chopper diode common connection point of the switching elements of the input voltage was set to the boost inductor for storing energy. In addition, between the step-up chopper and the step-up chopper diode and a switching element of a joint connection point of the first auxiliary diode and the second common connection point of the auxiliary diode was provided, the resonance capacitor. Between the step-up chopper and the step-up chopper diode and a switching element of a joint connection point and the common connection point of the resonance inductor snubber capacitor and connecting the third secondary diode, between two power supply lines is characterized by configuring the DC link capacitor bus lines in parallel. Therefore, it is possible to suppress the switching loss through, DC link bus lines, as well as there could seek miniaturization and weight reduction of the power conditioner itself by using a common capacitor of the non-polar non-polar electrolytic capacitor having a capacitor, the service life of the circuit can be extended and it is possible to greatly reduce the loss can be greatly improve the reliability of the product and the operation of the product itself.

• 한국재료학회지
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• 제16권11호
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• pp.692-697
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• 2006

Deodorization of natural zeolites have been improved not only for polar but also for non-polar pollutants by sucessive ion exchanges of H and Ag ions starting from Korean natural zeolite with high adsorption capacity. The modified zeolites with $TiO_2$ coating on the surface revealed high deodorization and photocatalytic decomposition effects. Further modification was made with $10{\sim}20nm$ silica nano particles coating on the surface, the resulting composite particles of $SiO_2/TiO_2/modified$ natural zeolite revealed not only comparable deodorization but also better durability and resisatnce to color change compared to the $TiO_2$/modified natural zeolite without much compensation of photocatalytic decomposition effect, when the composite particles were exposed to the polypropylene non-woven fiber coated with organic binder. It is expected for the composite particle prepared here to be used as indoor building materials for indoor air quality control.