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Review on asbestos analysis (석면 분석방법에 대한 고찰)

  • Ham, Seung hon;Hwang, Sung Ho;Yoon, Chungsik;Park, Donguk
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.19 no.3
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    • pp.213-232
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    • 2009
  • This document was prepared to review and summarize the analytical methods for airborne and bulk asbestos. Basic principles, shortcomings and advantages for asbestos analytical instruments using phase contrast microscopy(PCM), polarized light microscopy(PLM), X-ray diffractometer (XRD), transmission electron microscopy(TEM), scanning electron microscopy(SEM) were reviewed. Both PCM and PLM are principal instrument for airborne and bulk asbestos analysis, respectively. If needed, analytical electron microscopy is employed to confirm asbestos identification. PCM is used originally for workplace airborne asbestos fiber and its application has been expanded to measure airborne fiber. Shortcoming of PCM is that it cannot differentiate true asbestos from non asbestos fiber form and its low resolution limit ($0.2{\sim}0.25{\mu}m$). The measurement of airborne asbestos fiber can be performed by EPA's Asbestos Hazard Emergency Response Act (AHERA) method, World Health Organization (WHO) method, International Standard Organization (ISO) 10312 method, Japan's Environmental Asbestos Monitoring method, and Standard method of Indoor Air Quality of Korea. The measurement of airborne asbestos fiber in workplace can be performed by National Institute for Occupational Safety and Health (NIOSH) 7400 method, NIOSH 7402 method, Occupational Safety and Health Administration (OSHA) ID-160 method, UK's Health and Safety Executive(HSE) Methods for the determination of hazardous substances (MDHS) 39/4 method and Korea Occupational Safety and Health Agency (KOSHA) CODE-A-1-2004 method of Korea. To analyze the bulk asbestos, stereo microscope (SM) and PLM is required by EPA -600/R-93/116 method. Most bulk asbestos can be identified by SM and PLM but one limitation of PLM is that it can not see very thin fiber (i.e., < $0.25{\mu}m$). Bulk asbestos analytical methods, including EPA-600/M4-82-020, EPA-600/R-93/116, OSHA ID-191, Laboratory approval program of New York were reviewed. Also, analytical methods for asbestos in soil, dust, water were briefly discussed. Analytical electron microscope, a transmission electron microscope equipped with selected area electron diffraction (SAED) and energy dispersive X-ray analyser(EDXA), has been known to be better to identify asbestiform than scanning electron microscope(SEM). Though there is no standard SEM procedures, SEM is known to be more suitable to analyze long, thin fiber and more cost-effective. Field emission scanning electron microscope (FE-SEM) imaging protocol was developed to identify asbestos fiber. Although many asbestos analytical methods are available, there is no method that can be applied to all type of samples. In order to detect asbestos with confidence, all advantages and disadvantages of each instrument and method for given sample should be considered.

The effect of hypersonic wave sound for EEG (초음파가 뇌파에 미치는 영향)

  • Jang, Seok Woo;Park, In Gil;Kim, Dae Kyeum;Choi, Hyun
    • Science of Emotion and Sensibility
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    • v.17 no.2
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    • pp.101-110
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    • 2014
  • High-frequency is sound produced in non-audible area, which couldn't be heard in daily life. The frequency range above 22Khz is called 'high-frequency' and its components are called 'HFC(High-Frequency Components)'. It is known that ocean wave sound is rich in HFC, because it brings serenity and causes ${\alpha}$-waves in human mind. When this natural sound is combined with high-frequency, it seems to give a pleasurable feeling, indicated by an ${\alpha}$-wave increase and a ${\beta}$-wave decrease. We call this phenomena "the hypersonic effects". In this experiment, subjects listened to the ocean wave sound simultaneously with corresponding frequencies similar to ocean wave frequency components created artificially in a electric circuit. Brain waves were measured by an EEG system with 8 channels using 8 electrodes on Fp1, Fp2, F3, F4, T3, T4, O1, and O2. The results showed that ${\alpha}$-wave increase and ${\beta}$-wave decrease were statistically significant while subjects were listening to the ocean wave sound along with the high frequency components, reflecting the hypersonic effect.

Studies on the Microbiological Treatment of Hazardous Compounds in Waste Waters from Chemical Plants - (I) Relationship between the Content of Mercury Compound and Microbial Growth - (공장폐수중(工場廢水中) 유독성분(有毒成分)의 미생물학적(微生物學的) 처리방법(處理方法)에 관(關) 연구(硏究) - 수은함유량(永銀含有量)과 미생물(徵生物)의 생육(生育)과의 관계(關係)(제1보(第1報)) -)

  • Lee, Ji-Yul;Chang, Hyun-Ki
    • The Korean Journal of Mycology
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    • v.3 no.1
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    • pp.21-25
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    • 1975
  • This is a study to determine the content of the mercury compound and the distribution of microorganisms in the waste waters flowing from the chemical plants in the Ulsan area (at 4 stations). The summary of the result of this study is as follows: 1. The content of the mercury compound has ranged from non-detection to 0.075 ppm with an average of 0.03 ppm. The highest content has been detected from the water at station A. 2. As for the distribution of the microorganisms, one species each of bacteria, Mucor, Aspergillus, Cladosporium, and Trichothecium (T. roseum); 4 species of Penicillium; and 3 species of Sterile hyphae; a total of 12 species have been isolated. 3. The following results have been found with regard to the growth of these microorganisms in terms of the content of the mercury compound. In the case of an inorganic mercury compound, most of the microbes can grow in water with a content of up to 10 ppm. Pe. sp No. 1 particularly can grow even in 50 ppm. In the case of an organic mercury compound, the growth of the microbes seems to be somewhat restrained even in 2 ppm.

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A Study on Feasible 3D Object Model Generation Plan Based on Utilization, Demand, and Generation Cost (입체모형 활용 현황, 수요 및 구축 비용을 고려한 실현 가능한 3차원 입체모형 구축 방안 연구)

  • Kim, Min-Soo;Park, Doo-Youl
    • Journal of Cadastre & Land InformatiX
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    • v.50 no.1
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    • pp.215-229
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    • 2020
  • In response to the recent 4th industrial revolution, the demand for 3D object models in the latest fields of digital twin, autonomous driving, and VR/AR, as well as the existing fields such as city, construction, transportation, and energy has increased significantly. It is expected that the demand for 3D object models with various precision from LOD1 to LOD4 will increase more and more in various industry fields. However, the Ministry of Land, Infrastructure and Transport, and the local government and the private sector have partially built 3D object models of different precisions for some specific regions because of the huge cost. Therefore, this study proposes a feasible plan that can solve the cost problem in generating 3D object models for the whole territory. For our purpose, we first analyzed usage, demand, generation technology and generation cost for 3D object models. Afterwards, we proposed LOD3 model generation plan for all territory using automatic 3D object model generation technology based on image matching. Additionally, we supplemented the proposed plan by using LOD4 generation plan for landmarks and LOD2 generation plan non-urban area. In the near future, we expect this would be a great help in establishing a feasible and effective 3D object model generation plan for the whole country.

Effect of Styrene and Maleic Anhydride Content on Properties of PP/Pulp Composites and Reactive Extrusion of Random PP (랜덤 PP의 반응압출 및 PP/Pulp 복합체 특성에 대한 스티렌과 무수말레인산 함량의 영향)

  • Lee, Jong Won;Kim, Ji Hyun;Kim, Youn Cheol
    • Applied Chemistry for Engineering
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    • v.25 no.3
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    • pp.318-323
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    • 2014
  • In order to analyze the effect of maleic anhydride (MAH) content and styrene monomer (SM)/MAH mole ratio on reactive extrusion of maleic anhydride grafted random polypropylenes (MAH-g-rPP), MAH-g-rPPs were prepared by using a twin screw extruder. MAH contents were 0.5, 1.0, 3.0, and 5.0 phr and SM/initiator mole ratio was 0.0, 1.0, and 2.0. Dicumyl peroxide (DCP) was used as an initiator. The graft degree of MAH was confirmed by the existence of carbonyl group (C = O) stretching peak at $1700cm^{-1}$ from FT-IR spectrum. The degree of graft reaction increased up to 3.0 phr MAH and showed the optimum value at 1.0 SM/MAH mole ratio from the area ratio of C = O and C-H stretching peak. Thermal and crystallization properties of MAH-g-rPP and PP/MAH-g-rPP/pulp composites were investigated by DSC, TGA, XRD, and POM. There was a decrease in non-isothermal crystallization temperature of PP/MAH-g-PP/pulp composites. Based on tensile properties and SEM pictures for the fractured surface of PP/MAH-g-PP/pulp composites, MAH content of 1.0 wt% and SM/MAH mole ratio of 1.0 were the optimum formulation as the compatibilizer. The rheological properties of the composites were measured by dynamic Rheometer to compare the processability of the composites with and without compatibilizer. The power law index showed slightly low value at the composites with compatibilizer.

Characteristics of the Social Innovation Cluster Formation in Seongdong-gu and Eunpyeong-gu, Seoul, Korea (서울 성동구와 은평구의 사회혁신클러스터 형성 특성)

  • Roh, Kyeongran;Choo, Sungjae
    • Journal of the Economic Geographical Society of Korea
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    • v.22 no.2
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    • pp.214-235
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    • 2019
  • This study adopts the concept of social innovation cluster in which social economy organizations as one of the emerging axes of economic systems operate in collaboration with government agencies, investment institutions, intermediate supporting organizations and non-profit organizations, and investigates how the clusters of this kind grow in the context of the Korean socio-economic situation for the cases of Seongdong-gu and Eunpyeong-gu in Seoul, Korea. For this purpose, it has identified the actors of the clusters and their internal relations, and analyzed the process of cluster formation. A social network analysis of the partnerships between the actors has shown that Seongdong-gu has more diversified types of the network participation of universities, global networks and investment institutions than Eunpyeong-gu. It is interpreted that this pattern has resulted from the domination of private organizations in the former area, which is also confirmed by in-depth interviews with persons involved in the clusters. Although the facets of social innovation clusters are manifested in both areas, even in their initial stage, such factors as linkages between industrial actors and convergence with other clusters, which appear in the maturing stage of cluster formation, has yet to be found. It is suggested that the sustainable growth of social innovation clusters should be accompanied by information sharing and cooperation between the two areas on the future orientation of development.

A Study on the Preparation of Ternary Transition Metal Coated-Dimensionally Stable Anode for Electrochemical Oxidation (전기화학적 산화를 위한 삼원 전이 금속 코팅 불용성 산화 전극 제조에 관한 연구)

  • Park, Jong-Hyeok;Choi, Jang-Uk;Park, Jin-Soo
    • Applied Chemistry for Engineering
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    • v.32 no.4
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    • pp.409-416
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    • 2021
  • Dimensionally stable electrodes are one of the important components in electrochemical water treatment processes. In the manufacturing of the dimensionally stable electrodes, the type of metal catalyst coated on the surface of the metal substrate, the coating and sintering methods substantially influence their performance and durability. In this study, using Ir-Ru-Ta ternary metal coating, various electrodes were prepared depending on the coating method under the same pre-treatment and sintering conditions, and its performance and durability were studied. As a coating method, brush and spray coating were used. As a result, the reduction in the amount of catalyst ink was achieved because more amount of metal could be coated for the electrode using spraying with the same amount of catalyst ink. In addition, the spray_2.0_3.0 electrode prepared by a specific spray coating method shows the phenomenon of cracking and the uniform coating of the ternary metal on the surface of the coating layer, and results in a high electrochemically active specific surface area, and the decomposition performance of 4-chlorophenol was superior to the other electrodes. However, it was found that there was no significant difference in durability depending on the coating method.

Heavy Metals in Road Deposited Sediments and Control of Them in Urban Areas: A Review (문헌고찰에 의한 도시 지역 도로퇴적물의 중금속 특성 및 적정 관리방안)

  • Kim, Do Gun
    • Land and Housing Review
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    • v.13 no.3
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    • pp.125-140
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    • 2022
  • Road Deposited Sediment (RDS) is the solids formed from the wear of road, wear of vehicles, exhausts, and the input of the emissions from various sources out of the roads. RDS is seriously polluted by organic matter, nutrients, and metals. RDS plays an important role as the sink and the transport medium of the associated pollutants because RDS can be carried to the adjacent water system via stormwater runoff. In this regard, the heavy metals in RDS were investigated based on the publications. The contents of the metals in RDS were highly variable. The concentration of Cr, Ni, Cu, Fe, Zn, As, Cd, and Pb in urban RDS in various regions was in a range of 3.16-3,410, 1.15-1,382, 20.2-9,069, 2,980-124,853, 81-2,550, 2.3-214, 0.19-21.3, and 15.21-1,125 mg/kg, respectively. The anthropogenic enrichment of the metals in RDS was confirmed by the high concentration of Cu, Zn, Cd, and Pb. The contents of the metals were higher in industrial and traffic areas than in residential areas, while they were generally increased with decreasing particle size. It is believed that this study's results would contribute to quantifying the metals' load via RDS and establishing control strategies.

Structural and Photocatalytic Properties of TiO2 Thin Film Coated Glass Beads (유리알에 코팅된 TiO2 박막의 구조 및 광촉매 특성)

  • Ji Eun, Jeong;Chang-Yong, Lee
    • Applied Chemistry for Engineering
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    • v.34 no.1
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    • pp.30-35
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    • 2023
  • The glass bead surface was coated using a TiO2 sol, after which dry-treated (TB) and calcined (TBc) samples were prepared. Photocatalytic degradation of methylene blue and toluene, as well as characterization of the TiO2 thin films, were carried out. The TiO2 thin film of the TB sample had the same shape as the sponge foam, according to FE-SEM, XPS, and FTIR analyses, and contained both amorphous and crystalline TiO2. On the other hand, crystalline TiO2 was mainly present in the TiO2 thin film of the TBc sample, and needle-shaped particles and tiny ones were mixed. The adsorption capacity for methylene blue and the degradation rate of the TBc sample were less than 10 % compared with those of the TB sample, and the adsorption capacity and degradation rate of the TBc sample decreased similarly as the amount of TiO2 coating increased. The amount of toluene adsorption for the TBc sample (46 mg/g) was smaller than that of the TB sample with the same coating amount, but the degradation rate was similar. In the case of the TB sample, the degradation rate for toluene decreased less than the adsorption capacity as the amount of TiO2 coating increased. This result is considered to be because, in the non-calcined TB sample, the active site reduction of the crystalline particles occurred less and the specific surface area of the amorphous texture decreased as the amount of TiO2 coating increased.

Behavioral Change of Workers who completed Experiential Safety Training (체험식 안전교육 이수 근로자의 행동 변화 연구)

  • Choonhwan, Cho
    • Journal of the Society of Disaster Information
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    • v.19 no.1
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    • pp.161-172
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    • 2023
  • Safety education delivered to construction workers in a lecture manner has limitations in concentration and immersion, so delivery power and interest are low. In order to improve unstable behavior through education and prevent safety accidents, it is necessary to change the paradigm to hands-on education. Purpose: Experiential safety education aims to contribute to preventing accidents for construction workers by quickly recognizing risks, improving emergency response skills, and verifying the effectiveness of pre- and post-learning. Method: Based on a survey of workers who experienced the same work environment as the actual construction site, an opinion survey on the pre- and post-safety experience education and a variable measurement tool were planned, and a research hypothesis was established. Results: The Bayesian theory and MC simulation analysis were used to analyze the structural equation model, and the change in construction worker behavior was confirmed through the intended safety (A), non-experiential education in the sub-area of anxiety (B), average, standard deviation, and minimum and maximum values. Conclusion: The effect of education and industrial accidents are reduced only when construction workers are motivated to participate.