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http://dx.doi.org/10.14478/ace.2021.1039

A Study on the Preparation of Ternary Transition Metal Coated-Dimensionally Stable Anode for Electrochemical Oxidation  

Park, Jong-Hyeok (Department of Civil, Environmental, and Biomedical Engineering, The Graduate School, Sangmyung University)
Choi, Jang-Uk (Department of Green Chemical Engineering, College of Engineering, Sangmyung University)
Park, Jin-Soo (Department of Civil, Environmental, and Biomedical Engineering, The Graduate School, Sangmyung University)
Publication Information
Applied Chemistry for Engineering / v.32, no.4, 2021 , pp. 409-416 More about this Journal
Abstract
Dimensionally stable electrodes are one of the important components in electrochemical water treatment processes. In the manufacturing of the dimensionally stable electrodes, the type of metal catalyst coated on the surface of the metal substrate, the coating and sintering methods substantially influence their performance and durability. In this study, using Ir-Ru-Ta ternary metal coating, various electrodes were prepared depending on the coating method under the same pre-treatment and sintering conditions, and its performance and durability were studied. As a coating method, brush and spray coating were used. As a result, the reduction in the amount of catalyst ink was achieved because more amount of metal could be coated for the electrode using spraying with the same amount of catalyst ink. In addition, the spray_2.0_3.0 electrode prepared by a specific spray coating method shows the phenomenon of cracking and the uniform coating of the ternary metal on the surface of the coating layer, and results in a high electrochemically active specific surface area, and the decomposition performance of 4-chlorophenol was superior to the other electrodes. However, it was found that there was no significant difference in durability depending on the coating method.
Keywords
Dimensionally stable anode; Brushing; Spraying; Electrochemical oxidation; Non-degradable organic material;
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1 S. Kumar, S. Singh, and V. C. Srivastava, Electro-oxidation of nitrophenol by ruthenium oxide coated titanium electrode: Parametric, kinetic and mechanistic study, Chem. Eng. J., 263, 135-143 (2015).   DOI
2 M. Yousefpour and A. Shokuhy, Electrodeposition of TiO2-RuO2-IrO2 coating on titanium substrate, Superlattices Microstruct., 51(6), 842-853 (2012).   DOI
3 M. Panizza, L. Ouattara, E. Baranova, and C. Comninellis, DSA-type anode based on conductive porous p-silicon substrate, Electrochem. Commun., 5(4), 365-368 (2003).   DOI
4 G. F. Lee and J. Morris, Kinetics of chlorination of phenol-chlorophenolic tastes and odors, Int. J. Air Wat. Poll, 6, 419-431 (1962).
5 J. De Coster, W. Vanherck, L. Appels, and R. Dewil, Selective electrochemical degradation of 4-chlorophenol at a Ti/RuO2-IrO2 anode in chloride rich wastewater, J. Environ. Manage., 190, 61-71 (2017).   DOI
6 M. Seo, S. Cho, S. Lee, J. Kim, Y. H. Kang, and S. Uhm, A study on the highly effective treatment of spent electroless nickel plating solution by an advanced oxidation process, Appl. Chem. Eng., 26(3), 270-274 (2015).   DOI
7 A. R. Zeradjanin, N. Menzel, P. Strasser, and W. Schuhmann, Role of water in the chlorine evolution reaction at RuO2-based electrodes-understanding electrocatalysis as a resonance phenomenon, ChemSusChem, 5(10), 1897-1904 (2012).   DOI
8 E. Turro, A. Giannis, R. Cossu, E. Gidarakos, D. Mantzavinos, and A. Katsaounis, Electrochemical oxidation of stabilized landfill leachate on DSA electrodes, J. Hazard. Mater., 190(1-3), 460-465 (2011).   DOI
9 Y. J. Choe, J. B. Ju, and S. H. Kim, An electro-fenton system using magnetite coated one-body catalyst as an electrode, Appl. Chem. Eng., 29(1), 117-121 (2018).   DOI
10 A. Buthiyappan, A. R. Abdul Aziz, and W. M. A. Wan Daud, Recent advances and prospects of catalytic advanced oxidation process in treating textile effluents, Rev. Chem. Eng., 32(1), 1-47 (2016).   DOI
11 M.-J. Park, T.-S. Lee, M. Kang, and C.-B. Han, The effect of pre-treatment methods for the life time of the insoluble electrodes, J. Korean Soc. Environ. Eng., 38(6), 291-298 (2016).   DOI
12 R. Chen, V. Trieu, A.R. Zeradjanin, H. Natter, D. Teschner, J. Kintrup, A. Bulan, W. Schuhmann, and R. Hempelmann, Micro-structural impact of anodic coatings on the electrochemical chlorine evolution reaction, Phys. Chem. Chem. Phys., 14(20), 7392-7399 (2012).   DOI
13 C. A. Martinez-Huitle and E. Brillas, Decontamination of waste-waters containing synthetic organic dyes by electrochemical methods. An updated review, Appl. Catal. B: Environ., 166, 105-145 (2009).   DOI
14 H. T. Luu, D. N. Minh, and K. Lee, Effects of advanced oxidation of penicillin on biotoxicity, biodegradability and subsequent biological treatment, Appl. Chem. Eng., 29(6), 690-695 (2018).   DOI
15 Q. Zhou, W. Li, and T. Hua, Removal of organic matter from landfill leachate by advanced oxidation processes: A review, Int. J. Chem. Eng., 2010, 27532 (2010).
16 J. Kim, C. Kim, S. Kim, and J. Yoon, A review of chlorine evolution mechanism on dimensionally stable anode (DSA®), Korean Chem. Eng. Res., 53(5), 531-539 (2015).   DOI
17 F. Amano, Y. Furusho, and Y. M. Hwang, Amorphous iridium and tantalum oxide layers coated on titanium felt for electrocatalytic oxygen evolution reaction, ACS Appl. Energy Mater., 3(5), 4531-4538 (2020).   DOI
18 S.-R. Park and J.-S. Park, An updated review of recent studies on dimensionally stable anodes, J. Korean Electrochem. Soc., 23(1), 1-10 (2020)   DOI
19 F. C. Moreira, R. A. R. Boaventura, E. Brillas, and V. J. P. Vilar, Electrochemical advanced oxidation processes: A review on their application to synthetic and real wastewaters, Appl. Catal. B: Environ., 202, 217-261 (2017).   DOI
20 A. T. Marshall and R. G. Haverkamp, Nanoparticles of IrO2 or Sb-SnO2 increase the performance of iridium oxide DSA electrodes, J. Mater. Sci., 47(3), 1135-1141 (2012).   DOI
21 T. O. Kwon, B. B. Park, J. S. Moon, and I. S. Moon, Destruction of acetic acid using various combinations of oxidants by an advanced oxidation processes, Appl. Chem. Eng., 18(4), 314-319 (2007).
22 S. H. Lee, J. W. Choi, and H. S. Lee, A study on the formation of OH radical by metal-supported catalyst in ozone-catalytic oxidation process, Appl. Chem. Eng., 29(4), 432-439 (2018).   DOI
23 D.-S. Kim and Y.-S. Kim, A study on the preparation of the dimensionally stable anode (DSA) with high generation rate of oxidants(I), J. Environ. Sci., 18(1), 49-60 (2009).
24 S. Moon, Anodic oxidation treatment methods of metals, J. Korean Inst. Surf. Eng., 51(1), 1-10 (2018).   DOI
25 S. Trasatti, Electrocatalysis in the anodic evolution of oxygen and chlorine, Electrochim. Acta, 29(11), 1503-1512 (1984).   DOI
26 J. D. Park and H. S. Lee, Removal characteristics of dichloroacetic acid at different catalyst media with advanced oxidation process using ozone/catalyst, Appl. Chem. Eng., 20(1), 87-93 (2009).
27 Y. Yavuz and A. S. Koparal, Electrochemical oxidation of phenol in a parallel plate reactor using ruthenium mixed metal oxide electrode, J. Hazard. Mater., 136(2), 296-302 (2006).   DOI
28 R. Chauhan, V. C. Srivastava, and A. D. Hiwarkar, Electrochemical mineralization of chlorophenol by ruthenium oxide coated titanium electrode, J. Taiwan Inst. Chem. Eng., 69, 106-117 (2016).   DOI
29 S. B. Lee and K. S. Yoo, Preparation of TiO2 particles using binary ionic liquids for photocatalysis, Appl. Chem. Eng., 23(4), 405-408 (2021).
30 T. Reier, M. Oezaslan, and P. Strasser, Electrocatalytic oxygen evolution reaction (OER) on Ru, Ir, and Pt catalysts: A comparative study of nanoparticles and bulk materials, ACS Catal., 2(8), 1765-1772 (2012).   DOI
31 A. Tiwari, A. Shukla, D. Tiwari, S. S. Choi, H. G. Shin, and S. M. Lee, Titanium dioxide nanomaterials and its derivatives in the remediation of water: Past, present and future, Appl. Chem. Eng., 30(3), 261-279 (2019).   DOI
32 C. Wang and P. Tian, Further electrochemical degradation of real textile effluent using PbO2 electrode, J. Electrochem. Sci. Technol. (2021).
33 M. D. Hossain, C. M. Mustafa, and M. M. Islam, Effect of deposition parameters on the morphology and electrochemical behavior of lead dioxide, J. Electrochem. Sci. Technol., 8(3), 197-205 (2017).   DOI