• Title/Summary/Keyword: non-chemical control

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A Study on Characterization and Modeling of Shallow Trench Isolation in Oxide Chemical Mechanical Polishing

  • Kim, Sang-Yong;Chung, Hun-Sang
    • Transactions on Electrical and Electronic Materials
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    • v.2 no.3
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    • pp.24-27
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    • 2001
  • The end point of oxide chemical mechanical polishing (CMP) have determined by polishing time calculated from removal rate and target thickness of oxide. This study is about control of oxide removal amounts on the shallow trench isolation (STI) patterned wafers using removal rate and thickness of blanket (non-patterned) wafers. At first, it was investigated the removal properties of PETEOS blanket wafers, and then it was compared with the removal properties and the planarization (step height) as a function of polishing time of the specific STI patterned wafers. We found that there is a relationship between the oxide removal amounts of blanket and patterned wafers. We analyzed this relationship, and the post CMP thickness of patterned wafers could be controlled by removal rate and removal target thickness of blanket wafers. As the result of correlation analysis, we confirmed that there was the strong correlation between patterned and blanket wafer (correlation factor: 0.7109). So, we could confirm the repeatability as applying for STI CMP process from the obtained linear formula. As the result of repeatability test, the differences of calculated polishing time and actual polishing time was about 3.48 seconds. If this time is converted into the thickness, then it is from 104 $\AA$ to 167 $\AA$. It is possible to be ignored because process margin is about 1800 $\AA$.

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OBSERVER-BASED INPUT-OUTPUT LINEARIZATION CONTROL OF A MULTIVARIABLE CONTINUOUS CHEMICAL REACTOR

  • Mohamed, Bouhamida;Bachir, Daaou;Abdellah, Mansouri;Mohammed, Chenafa
    • Journal of the Korean Mathematical Society
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    • v.49 no.3
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    • pp.641-658
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    • 2012
  • The goal of this paper is to develop a nonlinear observer-based control strategy for a multi-variables continuous stirred tank reactor (CSTR). A new robust nonlinear observer is constructed to estimate the whole process state variables. The observer is coupled with a nonlinear controller, designed based on the input-output linearization for controlling the concentration and reactor temperature. The closed loop system is shown to be globally asymptotically stable based on Lyapunov arguments. Finally, computer simulations are developed for showing the performance of the proposed controller.

The Effect of Chemical Treatments on Biodeterioration of Stone Cultural Properties

  • Kim, Gwang Hoon;Klotchkova, Tatiana A.;Suh, Man-Cheol
    • Korean Journal of Environmental Biology
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    • v.19 no.2
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    • pp.101-105
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    • 2001
  • The biodeterioration with blue-green algae has been studied since 1997 up to 2000 in the tomb of King Mooryong in Kongiu, Korea. Biodeterioration in the tomb initially started from the formation of micro-organismic biofilm that had been suggested to make minor changes on the stone surface. This study revealed that the biofilm formed by microorganisms could result in permanent damages on stone cultural properties. The application of a chemical, 'K2Ol', developed by the author successfully removed fouling of biofilm on the surfaces of stone cultural properties. When small pieces of granite stone were embedded in the solution to study the side effects of the chemicals for a period of three months, the mechanical stability was 0.97 compared to control and there was no change in color. Biodeterioration is one of the most harmful factors that decrease the value of stone cultural properties but it may be treated with a development of proper chemicals.

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Current Status on the Occurrence and Management of Disease, Insect and Mite Pests in the Non-chemical or Organic Cultured Apple Orchards in Korea (무농약 유기재배 사과원의 병해충 발생과 관리 실태)

  • Choi, Kyung-Hee;Lee, Dong-Hyuk;Song, Yang-Yik;Nam, Jong-Chul;Lee, Soon-Won
    • Korean Journal of Organic Agriculture
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    • v.18 no.2
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    • pp.221-232
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    • 2010
  • During 2005~2009, current status on the occurrence and the management of the major disease, insect and mite pests were investigated in the non-chemical or organic cultured apple orchards in Korea. Numbers of certified organic or non-chemical apple orchards increased from 14 in 2005 to 78 in 2008. Severe damages on leaves and fruits were caused by the several diseases such as marssonina blotch, bitter rot, white rot, sooty blotch and flyspeck, and the several insect pests such as apple leaf-curling aphid, woolly apple aphid, oriental fruit moth and peach fruit moth on the almost certified organic or non-chemical pest control orchards. About 10 and 18 environmental-friendly materials were used to control diseases and insect or mite pests, respectively. But, lime sulfur and bordeaux mixture to diseases and machine oil, plant oil mixed with egg yolk, and pheromone mating disruptions to insect pests were effective under the adequate conditions.

An Experimental Study on the Improvement of Microscopic Machinability of Glass using the Discharging Peak Control Techniques in the Electrochemical Discharge Machining Technologies

  • Chang, In-Bae;Kim, Nam-Hyeock;Kim, Byeong-Hee;Kim, Heon-Young
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2002.10b
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    • pp.315-316
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    • 2002
  • Electrochemical discharge machining is a very recent technique for non-conducting materials such as ceramics and glasses. ECDM is conducted in the NaOH solution and the cathode electrode is separated from the solution by $H_2$ gas bubble. Then the discharge is appeared and the non-conductive material is removed by spark and some chemical reactions. In the ECDM technology, the $H_2$ bubble control is the most important factor to stabilize the discharging condition. In this paper, we proposed the discharge peak monitoring/ discharging duty feedback algorithms for the discharge stabilization and the feasibility of this algorithm is verified by various pattern machining in the constant preload conditions for the cathode electrode.

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An Experimental Study on the Improvement of Microscopic Machinability of Glass using the Discharging Peak Control Techniques in the Electrochemical Discharge Machining Technologies

  • Chang, In-Bae;Kim, Nam-Hyeock;Kim, Byeong-Hee;Kim, Heon-Young
    • KSTLE International Journal
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    • v.3 no.2
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    • pp.95-100
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    • 2002
  • Electrochemical discharge machining is a very recent technique for non-conducting materials such as ceramics and glasses. ECDM is conducted in the NaOH solution and the cathode electrode is separated from the solution by H$_2$ gas bubble. Then the discharge is appeared and the non-conductive material is removed by spark and some chemical reactions. In the ECDM technology, the H$_2$ bubble control is the most important factor to stabilize the discharging condition. In this paper we proposed the discharge peak monitoring/discharging duty feedback algorithms fur the discharge stabilization and the feasibility of this algorithm is verified by various pattern machining in the constant preload conditions for the cathode electrode.

Changes of Root Yield and Paeoniflorin Content affected by Harvesting Times in Peony(Paeonia lactiflora) (작약(芍藥) 수확시기(收獲時期)에 따른 수량(收量) 및 Paeoniflorin 함량(含量)의 변화(變化))

  • Kim, Ki-Jae;Park, So-Deuk;Park, Chun-Hong;Shin, Jong-Hee;Kim, Jae-Cheol;Choi, Boo-Sull
    • Korean Journal of Medicinal Crop Science
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    • v.8 no.1
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    • pp.58-63
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    • 2000
  • Changes of yield and paeoniflorin content according to chemical control and harvest time were investigated. Peonies were harvested after four years from planting. Disease and pest control method was applied normally in first year. From second year to forth year we set two blocks and controlled them differently. In one, peonies were withered early under non-control condition. In the other which was controlled by spraying chemicals four time a year, top part withering was delayed. Harvest was taken four times top part withering was delayed. Harvest was taken four times: Jul. 25, Aug. 25, Sep. 25, and Oct. 25. In non-chemical, at harvest of Jul. 25, paeoniflorin content was highest and dry root weight was 1,126kg/10a which was little less than 1,177kg/10a of Aug. 25. In chemical control, dry root yield of Oct. 25. showed an increase of 33% over that of Jul. But paeoniflorin content in root at Oct. was lower than at Jul. or Aug. For high qualities and harvest yields of peony root, chemical control is necessary to maintain top part to late in Oct.

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New Materials Based Lab-on-a-Chip Microreactors: New Device for Chemical Process

  • Kim, Dong-Pyo
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2012.05a
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    • pp.51-51
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    • 2012
  • There is a growing interest in innovative chemical synthesis in microreactors owing to high efficiency, selectivity, and yield. In microfluidic systems, the low-volume spatial and temporal control of reactants and products offers a novel method for chemical manipulation and product generation. Glass, silicon, poly(dimethylsiloxane) (PDMS), and plastics have been used for the fabrication of miniaturized devices. However, these materials are not the best due to either of low chemical durability or expensive fabrication costs. In our group, we have recently addressed the demand for economical resistant materials that can be used for easy fabrication of microfluidic systems with reliable durability. We have suggested the use of various specialty polymers such as silicon-based inorganic polymers and fluoropolymer, flexible polyimide (PI) films that have not been used for microfluidic devices, although they have been used for other areas. And inexpensive lithography techniques were used to fabricate Lab-on-a-Chip type of microreactors with differently devised microchannel design. These microreactors were demonstrated for various synthetic reactions: liquid, liquid-gas organic chemical reactions in heterogeneous catalytic processes, syntheses of polymer and non-trivial inorganic materials. The microreactors were inert, and withstand even harsh conditions, including hydrothermal reaction. In addition, various built-in microstructures inside the microchannels, for example Pd decorated peptide nanowires, definitely enhance the uniqueness and performance of microreactors. These user-friendly Lab-on-a-Chip devices are useful alternatives for chemist and chemical engineer to conventional chemical tools such as glass.

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The Function of Multiple Pribnow Box on the Aerobic-Anaerobic Switch Control of aeg-46.5 Gene Expression

  • Gang, In O;Jeong, Yeon Ju;Choe, Mu Hyeon
    • Bulletin of the Korean Chemical Society
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    • v.22 no.8
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    • pp.903-908
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    • 2001
  • The gene aeg-46.5, which is expressed under anaerobic condition, has putative triple -10 regions and four transcription start sites. The mRNA transcription level and its start point change depending on the aerobic/anaerobic growth condition. RNA polymerase and its regulatory proteins must choose which of three -10 region to use. The putative triple 10 region was mutated to make only one of them function with consensus -10 region sequence (TATAAT) and the other two as non-functional region. The results show that the second and third -10 regions are used for the aerobic/anaerobic expression. The third -10 region is responsible for the high aerobic to anaerobic switch ratio. This suggests that only the last two of the putative triple -10 region have functions on aeg-46.5 gene expression switch control. The phenotype of the mutated promoter was tested in the wild type cell and narL - cell. The results indicate that the control by NarL is independent from the selection of -10 region. The expression patterns on multi-copy plasmids and on single-copy chromosome were compared. These results show that the aerobic/anaerobic switch control of aeg-46.5 is through the choice of -10 region. The mechanism of choosing different -10 region remains to be seen.

Study for the Standardization and Comparison by Processed Morindae Radix (파극천(巴戟天) 포제방법(?製方法)에 따른 품질표준화 연구)

  • Lee, Hye-Won;Chun, Jin-Mi;Lee, A-Yeong;Kim, Ho-Kyoung
    • The Korea Journal of Herbology
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    • v.20 no.4
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    • pp.133-140
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    • 2005
  • Objectives : We have been used many herbal medicines after processing to improve the effect, decrease toxicity and side-effect, and change property. We have studied the physico-chemical change and HPLC pattern of Morindae Radix by means of processing method. Methods : This study was investigated the contents of loss on drying, residue on ignition, residue on acid insoluble ignition, 50% ethanol extract and HPLC pattern of Morindae Radix(Morinda officinalis How.) by processed and non-processed. We have conducted Morindae Radix and Damnacanthi Radix which is circulated in herbal medicine market by forgery. Processed Morindae Radix was prepared by heating of added to salt(SP), liquor(LP) and Glycyrrhizae Radix solution(GP) for 20-40 minutes. Results and Conclusions : From this analysis, we found that the content of 50% ethanol extract was increased by processing method. And we were detected distinguishable marker of processed and non-processed from Morindae Radix(Morinda officinalis How.) by HPLC pattern analysis.

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