• Title/Summary/Keyword: nitrogen species

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Optical Emission Studies of a Plume Produced by Laser Ablation of a Graphite Target in a Nitrogen Atmosphere

  • Park, Hye-Sun;Nam, Sang-Hwan;Park, Seung-Min
    • Bulletin of the Korean Chemical Society
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    • v.25 no.5
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    • pp.620-624
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    • 2004
  • Optical emission studies were performed to investigate thermal and dynamical properties of a plume produced by laser ablation of a graphite target in a nitrogen atmosphere. Experimental spectra of $C_2(d^3{\Pi}_g{\to}a^3{\Pi}_u$, ${\Delta}_V$=1) and CN ($B^2{\Sigma}^+{\to}X^2{\Sigma}^+,{\Delta}_V=0)$ were simulated to obtain the vibrational and rotational temperatures of the electronically excited species at various laser fluences and distances from the target. The spectroscopic temperatures of both molecules were found to be nearly independent of the laser fluence. The temperature of CN molecules was peaked in the middle of the plume while that of $C_2$decreased with increase in the distance. At a given distance, the temperature of CN molecules was clearly higher than that of $C_2$.

Selection of Nitrate-nonutilizing Mutants of Hypoxylon atropunctatum, A Fungal Pathogen on Oak Species

  • Chun, Se-Chul;Fenn, P.
    • The Plant Pathology Journal
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    • v.16 no.5
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    • pp.247-251
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    • 2000
  • Latent infections of healthy-appearing oaks of Hypoxylon atropunctatum complicates field studies by interfering with inoculation experiments to follow pathogenesis, fungal development and reproduction of this canker rot fungus. Mutants with unique and easily scorable phenotypes would be useful for inoculation studies. There is a broad range in the capacity of wild-type isolates to utilize nitrate as a sole nitrogen sources. Several types of nitrate-nonutilization mutants (nit1, Nit3, NitM) were selected from nitrate-utilizing wild-type isolates. Also, a few mutants of Hypoxylon atropunctatum were selected that could only grow poorly on basal medium supplemented with various nitrogen sources and even on yeast extract agar. These unknown mutants need to be characterized further. Nit mutants of Hypoxylon atropunctatum were readily selected, grew well and were recovered after inoculation into oak stems. These results suggest that nit mutants could be useful for inoculation studies in trees that contain latent infections.

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Study on the Hygienical Test of Fermented Sea Fishes. (젓갈류의 위생학적 검사에 관한 연구)

  • Lee Jong Tae
    • Journal of environmental and Sanitary engineering
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    • v.3 no.1 s.4
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    • pp.9-18
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    • 1988
  • This investigation was carried out to find out the biological contamination, nitrogen compounds, physical and chemical test in fermented sea fishes. 60 species sample were collected from farm village, fishing village and free markets, its hygienical test period is taken about two years. The examined results obtained are as in bollow. 1. $hNO_3,\;HNO_2,\;NH_3-N$ was detected whole samples. 2. Some fermented sea fishes was showed under the exhortation quality. 3. Nitrogen compound really produce N-Nitrosoamine. 4. The amine compounds are caused of cancer and malignant disease. 5. All container, storaged method, processing method and delivery method are must be improve. 6. It is neccessary to do instruction for fermented sea fishes really meaning and attain to a fixed standardization.

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Ecology of Azotobacter in Bamboo Forest Soil (죽림토양의 azotobacter 생태)

  • 최영길
    • Korean Journal of Microbiology
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    • v.13 no.1
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    • pp.1-23
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    • 1975
  • This experiment was designed to elucidate the environmental factors in rhizosphers of bamboo forest that affect the distribution and the population size of Azotobacter, and also to estimate the annual productivities of nitrogen fixed by Azotobacter species. The results of this experiment can be summarized as follows ; The rhizosphere of bamboo forest contained high free sugars as of 3-8 times more than non-rhizosphere (Bacon, 1968), and the contents of organic matter and amino acids of that are reltively higher than this. Because of high content of potassium, average of soil pH is near at 7.0. As above-mentioned enviromental factors, the population sizes of Actinomycetes, general fungi, general bacteria and Azotobacters are larger than those of non-rhizosphere and the ofllowings are general fungi and general bacteria by turns. Azotobacter is dependent upon the antagonistic Actinomycetes. The main carbon source for Azotobacter in nitrogn flxation at the rhizosphere was glucose and minors were fructose, maltose and sucrose by turns. Annual gains of nitrogen by Azotobacters in soil of bamboo forest within 10cm from surface are estimated as of 88.94 kg/ha at site A, 60.4kg/ha at site B and 67.38kg/ha at site C, respectively.

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Effects of Transverse Magnetic Field on Laser-produced Carbon Plasma Plume in Nitrogen Atmosphere

  • Nam, Sang-Hwan;Ko, Min-Jung;Lee, Mi-Ae;Park, Hye-Sun;Song, Jae-Kyu;Park, Seung-Min
    • Bulletin of the Korean Chemical Society
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    • v.28 no.5
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    • pp.767-771
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    • 2007
  • By adopting a time-resolved optical emission spectrometry, we have investigated the effects of transverse magnetic field on C2 and CN molecules produced by laser ablation of a graphite target in nitrogen atmosphere. We found that the spectroscopic temperatures of both species, obtained via simulation of the optical emission spectra, as well as their emission intensities from the electronically excited states increased significantly in the presence of a magnetic field. The cyclotron radii and frequencies for electrons and ions were estimated to explain the increase in the number of collisions in the laser-produced carbon plasma plume under a magnetic field.

Reduction of Lean VOC Emission by Reforming with a Rotating Arc Plasma and Combustion with a Turbulent Partially-Premixed Flame (난류 부분예혼합화염과 로테이팅 아크 플라즈마를 이용한 난연성 유증기의 연소처리)

  • Ahn, Taekook;Lee, Daehoon;Park, Sunho
    • Journal of the Korean Society of Combustion
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    • v.22 no.1
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    • pp.23-31
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    • 2017
  • Large-scale fuel tanks emit massive amount of hardly-combustible VOC mixtures which are light hydrocarbon species in dilution with nitrogen and carbon dioxide. We have developed a lab-scale burner to combust those VOC mixtures by use of a turbulent partially-premixed flame as a pilot flame. For a higher HC treatment ratio, the mixture gases were reformed by a rotating arc plasma device. The results showed that the nitrogen mole fraction and the injecting speed of the VOC mixture influence on the performance of the burner. It was also found that the size of the pilot flame and the power supplied to the plasma device determine the overall HC treatment ratio and the concentrations of CO and NOx in the exhaust gas.

Rhodium(I) Complexes of 1,1$^\prime$-Bis(diphenylphosphino)-ferrocene as Efficient Catalysts in Regioselective Hydrogenation of Polynuclear Heteroaromatic Compounds

  • Kim, Tae-Jeong;Lee, Kyu-Chul
    • Bulletin of the Korean Chemical Society
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    • v.10 no.3
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    • pp.279-282
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    • 1989
  • Two rhodium(I) complexes of the types [Rh(BPPF)(NBD)]$ClO_4$ (10) and [Rh(BPPF)$Cl]_2$ (11) (BPPF = 1,1'-bis(diphenylphosphino)-ferrocene) have been prepared and investigated as catalysts for the regioselective hydrogenation of polynuclear heteroaromatic nitrogen and sulfur compounds such as quinoline (1), acridine (2), phenanthridine (3), 7,8-benzoquinoline (4), benzothiophene (5), isoquinoline (6), indole (7), pyridine (8), and thiophene (9). Both complexes 10 and 11, except for the cases of indole (7) and mononuclear heteroaromatics 8-9, are very efficient in the selective reduction under quite mild hydrogenation conditions to give the corresponding saturated nitrogen and sulfur heterocyclic analogues of 1-6 in fast conversion rates and in excellent yields. Relative rate studies revealed that the reduction depends significantly on the steric and electronic effects of the substrates. Of the two complexes 10-11, the dimeric species 11 gives faster reaction rates in all cases studied.

Dynamics of the Plant Community Structure and Soil Properties in the Burned and Unburned Areas of the Mt. Ch’olye-san (초례산의 산화지와 비산화지의 식물군집구조 및 토양성분의 동태)

  • Sim, Hak-Bo;Woen Kim
    • The Korean Journal of Ecology
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    • v.19 no.5
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    • pp.417-430
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    • 1996
  • This study was conducted to investigate the developmental process of plant community during the secondary succession and the dynamics of soil properties in the burned and unburned areas of Mt. Ch’oly-san. Owing to the forest fire occurred on April, 1989, the red pine(Pinus densiflora) forest and its floor vegetation were burned down. The floristic composition of burned and unburned areas were composed of 53 and 49 species of vascular plants, respectively. The dominant species based on SDR4 of the burned sites were lespedeza cyrtobotrya (89.62), Miscanthus sinensis var. purpurascens (62.50), and Carex humilis (58.73), Quercus serrata (43.33). In contrast, Pinus densiflora (83.56), Lespedeza cyrtobotrya (55.57), Miscanthus sinensis var. purpurascens (51.88) and Carex humilis (50.41) were dominant in the unburned area. The biological spectra showed the $H-D_1-R_5-e$ type in both the burned and unburned areas. The indices of similarity ($CC_S$) between the two areas were 0.74. Degree of succession (DS) was 604 in the burned area and 802 in the unburned area. From these facts, it is assumed that the succession is rapidly progressing because of the recovery of vegetation. The species diversity ($\={H}$) and evenness index(C) in the burned and unburned areas were 0.15 and 0.18, respectively. Red pine tree did not resprout after scorch by the forest fire, but Lespedeza, Quercus, Rhododendron, Albizzia, and Zanthoxylum resprouted from the roots and trunks after the forest fire. It seems that these species are the fire-resistant species. Soil properties such as soil pH, content of organic matter, available phosphous, total nitrogen, tatal carbon, exchangeable potssium, sodium, calcium, and magnesium increased due to forest fire. These results suggest the intensity of forest fire in the study area was relatively weak. Monthly changes of soil properties were of little significance except for some cases.

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The Change of Physiological Characteristics as Water Purification Capability by Native Aquatic Plants (자생수생식물의 수질 정화에 따른 생리활성 변화)

  • 한승원;방광자;이욱주
    • Journal of the Korean Institute of Landscape Architecture
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    • v.32 no.3
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    • pp.43-50
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    • 2004
  • This study looked into the water quality improvement effect of reed (Phragmites communis), bur reed (Sparaganium stoloniferum), Alisma canaliculatum, and Hydrocharis dubia in order to develop native hydrophytes suitable to natural-type wetlands for ecological restoration. The result confirms that the concentration of wastewater was lowered in most plants indicating a possibility in wastewater treatment. Among four species, reed (Phragmites communis) and bur reed (Sparaganium stoloniferum) were most effective in removing a majority of contaminants. Considering that reed (Phragmites communis) is a species that has been used most often among hydrophytes, bur reed (Sparaganium stoloniferum), which is a native species in Korea, showed equivalent level of outstanding effect. In the physiological and growing activity and its relations to water quality improvement effect, each species appeared differently. Reed (Phragmites communis) and bur reed (Sparaganium stoloniferum) were best also in physiological and growing activity. In the case of Hydrocharis dubia, growth was strong in polluted water environment but its physiological activity was poor, indicating that it was under stress. The growth and physiological activity of Alisma canaliculatum were also poor, indicating that it too is being stressed. However, measuring organic contents in the plants of each species shows that the organic contents of Alisma canaliculatum was high. Alisma canaliculatum is a species effective in removing pollutants in water, although it is under stress. A unique phenomenon in removing water pollution with plants is that each species removed different pollutants. In the case of Alisma canaliculatum, which was relatively poor in removing pollution, it was remarkable in reducing nitrogen and phosphorus. Hydrocharis dubia was also effective in eliminating floating matter.

Biodiversity, Spore Density and Root Colonization of Arbuscular Mycorrhizal Fungi at Expressway Cut-slopes in Korea

  • Lee, Kyung Joon;Lee, Kyu Hwa;Tamolang-Castillo, Evangeline;Budi, Sri Wilarso
    • Journal of Korean Society of Forest Science
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    • v.98 no.5
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    • pp.539-547
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    • 2009
  • This study was conducted to investigate the arbuscular mycorrhizal fungal biodiversity, spore density and root colonization in relation to site ages at expressway cut-slopes in Korea. Stabilization of exposed surface involved soil amendments and spraying seed mixture of turf grasses and/or nitrogen-fixing shrub species. Eighteen sites were selected with varying ages (2 to 16 years). Soil samples collected in October from each site were analyzed for fungal diversity and spore counts. Fine root samples from the plants were assayed for fungal colonization. Of the total 37 plants inspected in the sites, 26 species had endomycorrhizal colonization with an average root colonization rate of 18%, and with a range from 1 to 67%. The average endomycorrhizal colonization rate of initially introduced Festuca arundinacea which became the most dominant grass in later stage showed 22.8%, while that of Lespedeza bicolor which became the most dominant woody species were 21.6%. Naturally-invading Robinia pseudoacacia showed higher colonization rate in the old sites. Although site age did not show significant effects on fungal diversity, the root colonization rates of initially introduced plants decreased with the site aging, while those of invading plants increased with aging of the sites. The soil chemical properties, pH, N, and P contents, were negatively correlated with spore density, root colonization and endomycorrhizal species diversity. A total of forty arbuscular mycorrhizal fungal species in seven genera were identified. Of the 40 species, Acaulospora lacunosa, Glomus aggregatum, Glomus constrictum, Scutellospora erythropa, and Acaulospora spinosa were the five most dominant species in the decreasing order.