• Title/Summary/Keyword: nitrogen ratio

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Effects of Fermented Leachate of Food Waste (FLFW) and Temperature on Nutrient Removal in Sequencing Batch Reactor

  • Roh, Sung-Hee;Chun, Young-Nam;Lee, Sook-Young;Cheong, Hyeon-Sook;Lee, Jae-Wook;Kim, Sun-Il
    • Environmental Engineering Research
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    • v.13 no.3
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    • pp.155-161
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    • 2008
  • This study examined effects of the fermented leachate of food waste (FLFW) on nitrogen and phosphorous removal for domestic wastewater containing a low carbon-to-nitrogen (C/N) ratio in sequencing batch reactor (SBR). When the FLFW was not supplied in the process, release of phosphorus and excessive intake was not observed at both anaerobic and aerobic stages. On the other hand, when the FLFW was gradually added, active release of phosphorus and intake of phosphorus was noticed at an anaerobic stage and aerobic stage, respectively, resulting in improved phosphorus removal efficiency. The removal efficiency of nitrogen and phosphorus was increased from 75% and 37% (R-1, control test) to 97% and 80% (R-4, the highest substrate ratio test), respectively. In addition, although activity of the nitrogen oxidizing microorganisms was reduced when the reaction temperature was decreased to $10^{\circ}C$, the phosphorus removal efficiency was shown to increase with the addition of FLFW, indicating an independence from temperature. Overall, this study suggests that an efficient nutrients removal process can be successfully employed into a SBR when the FLFW is added to a wastewater which has a low C/N ratio.

Removal of Nitrate Nitrogen for Batch Reactor by ZVI Bipolar Packed Bed Electrolytic Cell (영가철 충진 회분식 복극전해조에 의한 질산성 질소 제거)

  • Jeong, Joo Young;Park, Jeong Ho;Choi, Won Ho;Park, Joo Yang
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.31 no.2B
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    • pp.187-192
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    • 2011
  • Nitrate nitrogen is common contaminant in groundwater aquifers, its concentration is regulated many countries below 10 mg/L as N (As per WHO standards) in drinking water. An attempt was made to get optimal results for the treatment of nitrate nitrogen in groundwater by conducting various experiments by changing the experimental conditions for ZVI bipolar packed bed electrolytic cell. From the experimental results it is evident that the nitrate nitrogen removal is more effective when the reactor conditions are maintained in acidic range but when the acidic environment changes to alkaline due to the hydroxide formed during the process of ammonia nitrogen there by increasing the pH reducing the hydrogen ions required for reduction which leads to low effectiveness of the system. In the ZVI bipolar packed bed electrolytic cell, the packing ratio of 0.5~1:1 was found to be most effective for the treatment of nitrate nitrogen because ZVI particles are isolated and individual particle act like small electrode with low packing ratio. It is seen that formation of precipitate and acceleration of clogging incrementally for packing ratio more than 2:1, decreasing the nitrate nitrogen removal rate. When the voltage is increased it is seen that kinetics and current also increases but at the same time more electric power is consumed. In this experiment, the optimum voltage was determined to be 50V. At that time, nitrate nitrogen was removed by 94.9%.

Estimating soils properties using NIRS to assess amendments in intensive horticultural production

  • Pena, Francisco;Gallardo, Natalia;Campillo, Carmen Del;Garrido, Ana;Cabanas, Victor Fernandez;Delgado, Antonio
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.1615-1615
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    • 2001
  • During the past ten years, Near Infrared Spectroscopy has been successfully applied to the analysis of a great variety of agriculture products. Previous works (Morra et al., 1991; Salgo et al., 1998) have shown the potential of this technology for soil analysis, estimating different parameters just with one single scan. The main advantages of NIR applications in soils are the speed of response, allowing the increase of the number of samples analysed to define a particular soil, and the instantaneous elaboration of recommendations for fertilization and soil amendment. Another advantage is to avoid the use of chemical reagents at all, being an environmentally safe technique. In this paper, we have studied a set of 129 soil samples selected from representative glasshouse soils from Southern Spain. The samples were dried, milled, and sieved to pass a 2 mm sieve and then analysed for organic carbon, total nitrogen, inorganic nitrogen (nitrate ammonium), hygroscopic humidity, pH and electrical conductivity in the 1:1 extract. NIR spectra of all samples were obtained in reflectance mode using a Foss NIR Systems 6500 spectrophotometer equipped with a spinning module. Calibration equations were developed for seven analytical parameters (ph, Total nitrogen, organic nitrogen, organic carbon, C/N ratio and Electric Conductivity). Preliminary results show good correlation coefficients and standard errors of cross validation in equations obtained for Organic Carbon, Organic Nitrogen, Total Nitrogen and C/N ratio. Calibrations for nitrates and nitrites, ammonia and electric conductivity were not acceptable. Calibration obtained for pH had an acceptable SECV, but the determination coefficient was found very poor probably due to the reduced range in reference values. Since the estimation of Organic Carbon and C/N ratio are acceptable NIIRS could be used as a fast method to assess the necessity of organic amendments in soils from Mediterranean regions where the low level of organic matter in soils constitutes an important agronomic problem. Furthermore, the possibility of a single and fast estimation of Total Nitrogen (tedious determination by modifications of the Kjeldahl procedure) could provide and interesting data to use in the estimation of nitrogen fertilizer rates by means of nitrogen balances.

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A Study of the Simultaneous Nitrification and Denitrification in a Single Bioreactor (단일 반응기를 이용한 동시 질산.탈질에 관한 연구)

  • Park, Jong-Il;Lee, Tae-Jin
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.2
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    • pp.220-228
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    • 2007
  • In this study, effective simultaneous nitrification and denitrification reaction was accomplished in a completely mixed single bioreactor. As the important factors on the reaction, optimal DO concentration and effective range of influent C/N ratio was investigated with the synthetic wastewater. Experimental results show that stable nitrogen removals were accomplished with 0.5 mg/L DO concentration and over 7 C/N ratio. Nitrogen removal efficiency of the real municipal wastewater was low with 0.5 mg/L DO concentration because of its low C/N ratio. The increment of the C/N ratio at the inflow of the municipal wastewater with addition of external carbon source (glucose) over 7(up to 14) shows over 70% nitrogen removal in the single bioreactor.

Removal of Organic and Nutrients in Fish Market Wastewater using Sequencing Batch Reactor (SBR) (SBR공정을 이용한 수산물 위판장 폐수에서 유기물 및 질소 제거)

  • Kim, Sung-Ju;Lee, Dae-Hee;Park, Hung-Suck
    • Journal of Korean Society on Water Environment
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    • v.23 no.1
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    • pp.46-51
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    • 2007
  • This research work aims at treating saline wastewater generated from a fish market using four Sequencing Batch Reactors (SBR) operated under different conditions. The effect of C/N ratio (3, 6) and salt concentration (0.5~2%) on organic and nitrogen removal was studied. The synthetic wastewater prepared with glucose ($C_6H_{12}O_6$) as the primary carbon source along with ammonium chloride ($NH_4Cl$) was used in the three reactors. The fill, anoxic, aeration, settle and draw conditions were 2 hr, 4 hr, 4 hr and 2 hr respectively. The fourth reactor was operated at different conditions to investigate the practical feasibility of SBR application to handle fish market wastewater generated in Ulsan city that had fluctuating loading characteristics. Though the unacclimated sludge was initially affected by the salt concentration, the acclimated sludge removed 95% of the organics irrespective of the NaCl concentration and C/N ratio. However, the removal of nitrogen was affected more by C/N ratio than the salt concentration. While handling fish market wastewater, though the organic and nitrogen loading rate were varying between $0.009{\sim}0.259gCOD_{OH}/gVSS/day$ and 0.005~0.034 gN/gVSS/day, the effluent concentrations were far less than the effluent standard of $120mgCOD_{OH}/L$ and 60 mgN/L respectively, except when loading rates were fluctuating and 4 times higher than the average.

A Study on the Development of a Cryogenic Air Separation Unit to Produce High Purity Nitrogen (고순도 질소생산용 초저온 공기분리장치 개발 연구)

  • 용평순;문흥만;이성철
    • Progress in Superconductivity and Cryogenics
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    • v.3 no.1
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    • pp.69-73
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    • 2001
  • For developing the cryogenic air separation unit, it requires some technology such as basic process design. equipment design and manufacturing based on the cryogenic physical properties and separation theory. In this study, we developed a process and equipment for producing high purity nitrogen which has the production capacity of 1600N㎥/h under 1 ppm $O_2$ and $H_2O$. Also we found that the number of theoretical plate(NTP) of distillation column was 44 and maximum nitrogen recovery ration of this process was 42% from the process simulation. The performance test was also carried out for the nitrogen recovery ratio and equipment efficiency. The results showed that the optimum nitrogen recovery was 41% and the maximum equipment efficiency was attained.

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$\delta^{15}$N Analysis for Interpretation of Nitrogen pollution Source and Contribution in Agricultural Watersheds (농촌유역의 질소 오염원과 기여도 해석을 위한 $\delta^{15}$N 분석(지역환경 \circled1))

  • 홍영진;권순국
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 2000.10a
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    • pp.513-518
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    • 2000
  • It has been acknowledged that fertilizer, natural soil nitrogen and animal waste, municipal waste have different mass ratio of nitrogen which is presented as a symbol of $\delta^{15}$N. and that the values of $\delta^{15}$N for fertilizer and natural soil nitrogen and animal waste are placed less than +5$\textperthousand$ and higher than +10$\textperthousand$, respectively. thus, Nitrogen pollution sources and contribution can be interpreted in watershed through $\delta^{15}$N analysis and then, analysis is performed with Kjeldhl-Dumas method. In this study, The values of $\delta^{15}$N are between +1.46$\textperthousand$ and +8.97$\textperthousand$, and the nitrate concentration is placed less than 3.31mg/L and higher than 0.19mg/L, respectively. Thus, this watershed is noncontamination area at the present time. But as a result of $\delta^{15}$N, contribution of natural soil nitrogen be discovered in this watershed, presently.

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Li+- and H+-Exchanged Low-Silica X Zeolite as Selective Nitrogen Adsorbent for Air Separation

  • Kim, Jin-Bae
    • Bulletin of the Korean Chemical Society
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    • v.24 no.12
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    • pp.1814-1818
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    • 2003
  • $Li^+$ and $H^+$ co-exchanged LSXs (Li-H-LSX) with various ratios of $Li^+$ and $H^+$ were prepared, and those adsorption characteristics of nitrogen and oxygen were compared with Li-Na-LSX and Li-Ca-LSX. Li-H-LSX showed higher nitrogen capacity and selectivity than that of Li-Na-LSX in the wide range of Li-exchanged ratio. The nitrogen capacity of Li-Ca-LSX was slightly higher than that of fully Li- or Ca-exchanged LSX (Li- LSX or Ca-LSX). However, Li-Ca-LSX showed low nitrogen/oxygen adsorption selectivity until the Li content reached about 80%, which was a tendency near that of Ca-LSX.

Growth and Physical Characteristics of Crystalline Carbon Nitride Films Using Penning-type Source Sputerring System (페닝 소스 스퍼터링 장치를 이용한 결정성 질화탄소막의 성장 및 물리적 특성)

  • Lee, Sung-Pil;Chowdhury, Shaestagir
    • Journal of Sensor Science and Technology
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    • v.9 no.3
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    • pp.248-255
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    • 2000
  • Penning type sputtering system which has two opposed targets was implemented and the physical characteristics of the deposited carbon nitride films were investigated. When argon ratio was reduced and nitrogen ratio was increased in the sputtering gas mixture, Fe was less sputtered. The grain size of grown carbon nitride films was distributed from $150{\AA}$ to $250{\AA}$. As nitrogen partial pressure increases, growth rate and nitrogen incorporation in the film increases.

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Effects of Dietary Lamb and Beef Meat on the Growth and Protein Utilization in Rats (양고기와 쇠고기의 식이가 흰쥐의 성장과 단백질 이용성에 미치는 영향)

  • 박선희
    • Journal of Nutrition and Health
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    • v.24 no.1
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    • pp.20-29
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    • 1991
  • This study was carried out to compare the protein quality of lamb and beef meat. by feeding to growing rats. Sixty weanling rats, 30 males and 30 females, were blocked into 12 groups(6 gruops of males and 6 groups of females). They were fed casein. beef, or lamb as a protein source at two levels, 6 and 15%, for 5 weeks. The amount of food intake. food efficiency ratio, protein efficiency ratio. body weight gain. and the weights of skeletal muscles and liver were measured. Nitrogen retention, protein content in the liver and skeletal muscles, and the levels of protein and cholesterol in the serum were also assayed. Summarzing the results, there were no significant differences between lamb and beef on the growth and nitrogen utilization in the rats fed same percentage of protein diet. However. rats fed 15% protein diet showed significantly higher growth rate than those fed 6%. Therefore, it can be concluded that lamb is as good a protein food as beef in terms of protein quality.

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