• 제목/요약/키워드: nitrogen isotope

검색결과 143건 처리시간 0.026초

Improvement of Gate Dielectric Characteristics in MOS Capacitor by Deuterium-ion Implantation Process (중수소 이온 주입에 의한 MOS 커패시터의 게이트 산화막 절연 특성 개선)

  • Seo, Young-Ho;Do, Seung-Woo;Lee, Yong-Hyun;Lee, Jae-Sung
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • 제24권8호
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    • pp.609-615
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    • 2011
  • This paper is studied for the improvement of the characteristics of gate oxide with 3-nm-thick gate oxide by deuterium ion implantation methode. Deuterium ions were implanted to account for the topography of the overlaying layers and placing the D peak at the top of gate oxide. A short anneal at forming gas to nitrogen was performed to remove the damage of D-implantation. We simulated the deuterium ion implantation to find the optimum condition by SRIM (stopping and range of ions in matter) tool. We got the optimum condition by the results of simulation. We compare the electrical characteristics of the optimum condition with others terms. We also analyzed the electrical characteristics to change the annealing conditions after deuterium ion implantation. The results of the analysis, the breakdown time of the gate oxide was prolonged in the optimum condition. And a variety of annealing, we realized the dielectric property that annealing is good at longer time. However, the high temperature is bad because of thermal stress.

Allochthonous Organic Matter Contribution to Foodweb in Shingu Agricultural Researvoir after Rainfall Period (강우기 후 신구 농업용 저수지 먹이망에 미치는 외부기원 유기물의 영향 - 안정동위원소비 활용 -)

  • Kim, Min-Seob;Lee, Yeon-Jung;An, Kwang-Guk;Kim, Baik-Ho;Hwang, Soon-Jin;Shin, Kyung-Hoon
    • Korean Journal of Ecology and Environment
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    • 제47권1호
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    • pp.53-61
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    • 2014
  • The origin of particulate organic matter (POM) and food web structure were investigated in Shingu reservoir based on stable isotope analysis from pre-monsoon (July) to post-monsoon (September) 2007. According to the depth in Shingu reservoir, the $^{13}C$ and $^{15}N$ values of POM for pre-monsoon period were nonsignificant distinction, while it was significant variation after rainfall period. The ${\delta}^{13}C$ values of POM in premonsoon period ranged from -25.1‰ to -26.1‰ in whole water column, but the ${\delta}^{13}C$ values of POM in post-monsoon period showed relatively wide range between -23.2‰ and -27.5‰. The apparently lighter values (average -27.5‰) in near bottom water (7 m water depth) demonstrate that POM in high turbid water in post-monsoon period may be derived from the outside terrestrial plants (allochthonous) through heavy rainfall during the summer monsoon period. After rainfall period, $^{13}C$ and $^{15}N$ values of D. brachyurum showed -23.3‰ and 12.2‰, respectively, while B. longirostris showed -27.1% and 8.7%, respectively. It suggested that D. brachyurum mainly feed on POM in autochthonous organic matter pool, but B. longirostris mainly consumed POM in allochthonous organic matter pool after rainfall period. Carbon and nitrogen stable isotope ratios were markedly different among secondary consumers. The carp (C. carpio) and catfish (S. asotus) were in the higher trophic level and crucian carp (C. auratus) and mudfish (M. mizolepis) were in the lower trophic level. $^{13}C$ and $^{15}N$ values of Z. platypus didn't significantly changed between before and after rainfall period. But P. parva and C. auratus apparently changed the $^{13}C$ and $^{15}N$ values after rainfall period. It is suggested that P. parva and C. auratus seem to feed allochthonous food source while Z. platypus depend on autochthonous food source.

Natural 15N Abundances of Corn Treated with Urea and Composted Pig Manure in a Pot Experiment (요소와 돈분퇴비 시용에 따른 포트 재배 옥수수의 질소동위원소 자연존재비 차이)

  • Choi, Woo-Jung;Lee, Sang-Mo;Kim, Kyoung-Cheol;Kim, Pan-Gun;Yoo, Ji-Hyeok;Yoo, Sun-Ho
    • Korean Journal of Soil Science and Fertilizer
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    • 제34권4호
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    • pp.284-291
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    • 2001
  • To study whether N isotope composition (${\delta}^{15}N$) of crop reflects the kind of fertilizer (chemical or organic) applied to field, a pot experiment was conducted. Corn (Zea mays L.) was cultivated under greenhouse conditions for 70 days. Composted pig manure and urea were applied at 0 and 0 (C0U0), at 0 and 300 (COU2), at 300 and 0 (C2U0) and at 150 and $150kg\;N\;ha^{-1}$ (C1U1), respectively. The ${\delta}^{15}N$ values of composted pig manure and urea were + 13.9‰ and -2.3‰, respectively. The ${\delta}^{15}N$ values of whole parts (roots + stems + leaves + grains) were + 12.7, + 12.9, + 14.0 and + 13.0‰ for C0U0, C0U2, C2U0 and C1U1 treatments, and were not significantly affected by the application of isotopically different N sources (P<0.05). However, leaves or grains showed significantly (P<0.05) different ${\delta}^{15}N$ values between treatments. The ${\delta}^{15}N$ values of leaves and grains were + 14.3 and + 16.2‰ for C2U0, +13.2 and +13.9‰ for C0U0, +10.1 and + 12.6‰ for C1U1 and +10.1 and +12.4‰ for C0U2 treatments. The different ${\delta}^{15}N$ values of corn from the values of N sources (compost and urea) applied to soil showed that the ${\delta}^{15}N$ values of corn were affected not only by the isotope composition of N source, but also by N pool mixing and isotope fractionation accompanying N transformation. This study suggests that although the ${\delta}^{15}N$ values of crop are not identical to the ${\delta}^{15}N$ values of N sources applied to fields, the application of isotopically different N sources such as compost and chemical fertilizer may result in qualitative difference in ${\delta}^{15}N$ values of crop.

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Geochemical and Isotopic Study of the Kumho River (금호강 하천수의 지구화학 및 동위원소 연구)

  • Kim, Yeong-Kyoo;Nam, Eun-Kyung
    • Economic and Environmental Geology
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    • 제42권6호
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    • pp.527-539
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    • 2009
  • The Kumho River flows through volcanic and sedimentary rocks at upstream and downstream regions and also through industrial district including dyeing complex before it meets the Nakdong River, and as a result, many factors can influence the geochemistry of river water. The concentrations of dissolved ions generally increased as it flows downstream. The concentrations of cations are in the order of Ca>Na>Mg>K, and those of anions are $HCO_3$>$SO_4$>Cl>$NO_3$. These results show that the weathering of sandstone and shale containing carbonate including calcite caused the enrichment of Ca and $HCO_3$. At first 4 sampling sites, Si contents are relatively high mainly due to the weathering of silicate minerals of volcanic rocks. However, Na and $SO_4$ contents are higher at downstream sites due to the industrial and municipal sewage. Piper diagram also shows that the geochemical patterns changed from Ca-$HCO_3$ to Ca-Cl/Ca-$SO_4$ and Na-Cl/Na-$SO_4$ type. When comparing the samples collected in May and July, the concentrations of dissolved ions in July are generally lower than those in May, which indicates that dilution by precipitation played an important role. In July the relative concentration of Ca increased, indicating that Ca in soils probably from fertilizer were mixed into the river water by precipitation. The river waters are mainly from precipitation. The dissolved ions are mainly from weathering of carbonate minerals and pollutants from municipal sewage and discharged water from industrial complex. The composition of oxygen and deutrium isotope in July showed higher values, which is contrary to the amount effect, maybe due to Youngchon Dam. The nitrogen isotope showed lower values in July than those in May, which can be interpreted to indicate mixing of nitrate from soils and fertilizer in the cultivated land by the heavy rain. The isotope composition of nitrate increased downstream, indicating that the influence of sewage and animal manure also increased downstream.

Conservation and Scientific Analysis of Human Bone Excavated in Sabi Period of Baekje from Eungpyeong-ri, Buyeo (부여 응평리 출토 백제 사비기 인골 보존처리 및 과학적 분석)

  • KIM, Mijeong;LEE, Yunseop;CHO, Eunmin;PARK, Sujin;MOON, Minseong
    • Korean Journal of Heritage: History & Science
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    • 제55권1호
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    • pp.305-321
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    • 2022
  • The stone chamber tomb in Eungpyeong-ri, Buyeo, is a joint tomb that contains the bodies of two individuals. This paper investigates the relationship between the buried persons and the characteristics of the stone chamber tomb. Based on the geographical location, relics, and the excavated human bones, it was determined that the tomb was built during the Sabi Period of the Baekje Dynasty and that the buried individuals were most probably residents of high stature or government officials. To study the excavated bones, the remains were carefully collected and conservation was carried out. Before collecting samples from the human bones for the analytical research, the results of near-infrared analysis were used to collect the samples for the isotope analysis and DNA analysis. The most important issue when handling the excavation site was the reinforcing agent and the concentration of the agent used. In situations like this, Paraloid B-72 is the most suitable agent. When the shape of human bones was difficult to distinguish from the soil, conservation was performed using X-ray and CT imaging data. The same chemical used for the reinforcement of the site was used to complete a minimum level of conservation to the surface areas where the conservation treatment of removing foreign substances, the reinforcement areas, and bonded areas were carried out. The collagen yield from the sample obtained at selected position was 3.8% to 6.1%. The results of analyzing the stable isotopes of carbon and nitrogen found in the extracted collagen showed that the stable isotope ratios came out to δ13C -18.3‰±0.1‰, -19.0‰±0.1‰ for EBW and δ15N 10.7‰±0.5‰, 10.6‰±0.1‰ for EBE. It is believed the two individuals consumed small amounts of minor cereals, mainly from C3 plants, and protein was obtained from eating terrestrial animals. What's more, the deviations in data obtained from the two individuals were so small that it could be inferred that the individuals ate similar foods. Considering the preservation state of the sample, amplifying DNA for the DNA analysis would have been very difficult since the amount of surviving DNA was so deficient. For DNA analysis, it is anticipated that the results could be derived by applying improved extraction methods that will be developed in the future. In this research, any association between scientific analysis(DNA and stable isotope ratio) and near-infrared spectroscopy was difficult to establish. Further research is needed on the utilization of near-infrared analysis for gathering samples from human bones.

Isotopic Evidence for Ontogenetic Shift in Food Resource Utilization during the Migration of the Slipmouth Leiognathus nuchalis in Gwangyang Bay, Korea (광양만 주둥치(Leiognathus nuchalis)의 서식처 이동에 의한 먹이원 변동 파악을 위한 안정동위원소 분석기법 적용)

  • Choi, Bohyung;Jo, Hyunbin;Park, Kiyun;Kwak, Ihn-Sil
    • Korean Journal of Ichthyology
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    • 제32권2호
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    • pp.84-90
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    • 2020
  • We investigated carbon and nitrogen isotope ratios (δ13C and δ15N) of the slipmouth Leiognathus nuchalis to reveal the effects of body size, feeding strategy and spatial distribution on the food resource utilization during the migration in the Seomjin estuary and Gwangyang Bay. The δ13C values of L. nuchalis caught in the Seomjin estuary where the salinity is lower than 30 psu were much lower than those in the deep-bay area of Gwangyang Bay. Such a spatial heterogeneity in δ13C values of the L. nuchalis clearly indicates active feeding within the estuarine habitat. In contrast, the δ15N values of L. nuchalis showed a consistency among sites, indicating that this species occupies identical trophic level across the whole area. The slipmouth distributed throughout the bay area, reflecting its euryhaline characteristics. However, the distribution pattern appeared to be separated according to body size into smaller individuals in the low-saline estuary and larger ones in the deep bay. Overall results support the plastic feeding strategy of the slipmouth from zooplanktonic (estuarine habitat) to epibenthic (deep-bay habitat) feeder during the migration between estuarine to deep-bay habitats.

Usefulness of Biochemical Analysis for Human Skeletal Remains Assigned to the Joseon Dynasty in Oknam-ri Site in Seocheon, Korea (조선시대 인골에 대한 생화학적 분석의 유용성: 서천군 옥남리 회곽묘 출토 인골을 중심으로)

  • Kang, So-Yeong;Kwon, Eun-Sil;Moon, Eun-Jung;Cho, Eun-Min;Seo, Min-Seok;Kim, Yun-Ji;Jee, Sang-Hyun
    • Journal of Conservation Science
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    • 제26권1호
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    • pp.95-107
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    • 2010
  • Biochemical research was carried out on 4 human skeletal remains from historical lime-layered tombs assigned to the Joseon Dynasty in Oknam-ri, Seocheon. The preservation of femur was evaluated by stereoscopic microscopy and scanning electron microscopy. Most of specimens showed good histological preservation. The histological results proved to be a good potentiality for biochemical analysis using bio-molecules. The amelogenin gene and mitochondrial DNA (mtDNA) analyses revealed that three specimens perhaps have maternal consanguinity due to sharing with mtDNA haplogroup D4b1, and two specimens buried in the same tomb were a couple in Gatjaegol site. Carbon and nitrogen stable isotope analysis indicated that four deads diet were built around C3 plant as rice, barley, wheat and bean. In this study we characterized genetic and diet features from the social stratum who could make lime-layered tombs during period of the Joseon Dynasty. The results suggest that biochemical research using the human skeletal remains from the Joseon Dynasty has the great potential and reasonable value for archaeology, anthropology, and population genetics.

Intermediary Metabolism of Plasma Acetic Acid, Glucose and Protein in Sheep Fed a Rice Straw-based Diet

  • Alam, M.K.;Ogata, Y.;Sako, Y.;Al-Mamun, M.;Sano, H.
    • Asian-Australasian Journal of Animal Sciences
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    • 제23권10호
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    • pp.1333-1339
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    • 2010
  • The present study was conducted to determine plasma acetate, glucose and protein metabolism using dilution of isotopes [[1-$^{13}C$]Na acetate, [U-$^{13}C$]glucose and [1-$^{13}C$]leucine (Leu)] in sheep fed rice straw (Oriza japonica L.). Four sheep were assigned to either rice straw (RS-diet) or mixed hay (MH-diet) with a crossover design. Nitrogen (N) intake and N digestibility were lower (p = 0.002 and p = 0.02, respectively) for RS-diet than MH-diet, but N retention did not differ (p>0.10) between the diets. Concentrations of rumen acetate tended to be lower (p = 0.07), and propionate was higher (p = 0.02) for RS-diet than MH-diet. Concentrations of plasma lactate, non-esterified fatty acids, Leu and ${\alpha}$-ketoisocaproic acid did not differ (p>0.10) between the diets, but plasma glucose and urea concentrations were lower (p = 0.01 and p = 0.003, respectively) for RS-diet than MH-diet. Turnover rate of plasma acetate did not differ (p = 0.39) between the diets, and plasma glucose and Leu turnover rates were numerically lower (p = 0.15 and p = 0.14, respectively) for RS-diet than MH-diet. Whole body protein synthesis and degradation did not differ (p>0.10) between the diets. Thus it can be concluded that the intermediary metabolism of acetate, glucose and protein on rice straw is comparable to mixed hay in sheep.

East Asian Monsoon History as Indicated by C/N Ratios and ${\delta}^{13}C$ Evidence from the Estuarine Tidal Flat Sediments in the West Coast of Korea (서해안 염하구 습지 퇴적물의 지화학적 분석 (C/N 및 ${\delta}^{13}C$)에 기반한 동아시아 몬순 변동 연구)

  • Park, Jung-Jae;Shin, Young-Ho
    • Journal of the Korean Geographical Society
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    • 제45권5호
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    • pp.541-552
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    • 2010
  • Geochemical and physical investigations such as ${\delta}^{13}C$ isotope ratio, carbon/nitrogen (C/N) ratio, magnetic susceptibility (MS), and particle size analyses were carried out on the estuarine tidal flat sediments from the west coast of Korea in order to reconstruct the East Asian summer monsoon variability during the late Pleistocene and Holocene Our results indicated that the summer monsoon probably peaked around 7,700-7,800 yr BP and then started to decline about 7,400 yr BP in the Korean peninsular, and that the monsoon was relatively weak between 24,000-24,500 yr BP but relatively strong between 18,500-19,500 yr BP during the Last Glacial Maximum. Our estuarine geochemical data have proven to be valuable as a new proxy for detecting the shifts in monsoon strength. This new evidence will be helpful, especially for Korean paleoenvironmental studies with few proxy data archives.

Food web structure in a $Salix$ $subfragilis$ dominated wetland in Hangang estuary using stable isotopes and fatty acid biomarkers

  • Han, Dong-Uk;Yang, Dong-Woo;Lee, Eun-Joo;Park, Sang-Kyu
    • Animal cells and systems
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    • 제16권2호
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    • pp.162-171
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    • 2012
  • We investigated food webs of a $Salix$ $subfragilis$-dominated wetland in the Janghang wetland in the Hangang estuary, which is very close to the Demilitarized Zone, along the west coast of Korea. Our study focused on understanding sesarmine crab ($Sesarma$ $dehaani$)-related food webs in a $S.$ $subfragilis$ forest. For our study, we used carbon and nitrogen stable isotopes and fatty acid biomarkers. We collected samples of plants, animals, and detrital sediment from four quadrats ($5{\times}5m^2$) set in the $S.$ $subfragilis$ community. Samples were collected from September 2006 to June 2009, except during the winter hibernation period of $S.$ $dehaani$. In the wet season, the sediment showed relatively high ${\delta}^{13}C$ and low ${\delta}^{15}N$ signatures compared with relatively low ${\delta}13C$ and high ${\delta}15N$ signatures in the dry season. Mature $S.$ $dehaani$ appeared to feed on fresh leaves and other carbon sources, such as immature individuals or fish, in addition to detrital sediment, which appeared to be the main carbon source for immature crabs. Principal component analysis of fatty acid biomarkers of $S.$ $dehaani$ showed a clear difference between immature individuals (10-30 mm) and mature ones (larger than 30 mm), indicating that the main food source for immature crabs was detrital sediment, whereas mature crabs foraged plants in addition to consuming detrital sediment. On the basis of our results from stable isotope and fatty acid analyses, mature $S.$ $dehaani$ appeared to feed on detrital sediment and fresh leaves of $S.$ $subfragilis$ in summer in addition to engaging in cannibalism of immature individuals.