• 제목/요약/키워드: nitrogen defect

검색결과 53건 처리시간 0.023초

첨가제와 소결분위기가 $SnO_2$ 요업체의 치밀화에 미치는 영향 (Effects of Sintering Atmosphere and Dopant Addition on the Densifcation of $SnO_2$ Ceramics)

  • 정재일;김봉철;장세홍;김정주
    • 한국세라믹학회지
    • /
    • 제34권12호
    • /
    • pp.1221-1226
    • /
    • 1997
  • The effects of sintering atmosphere and dopant addition on the behavior of densification and grain growth of SnO2 ceramics were investigated with consideration of defect chemistry. CoO and Nb2O5 were chosen as dopants, and oxygen and nitrogen were used for controlling of sintering atmospheres. With the decrease of oxygen partial pressure, densification was depressed due to evaporation of SnO2 ceramics. In the case of SnO2 sintering, the addition of CoO, which produced oxygen vacancy in SnO2 ceramics, led to acceleration of densification and grain growth. On the contrary, when Nb2O5 as a dopant producing Sn vacancy was added to SnO2 ceramics, densification and grain growth were simultaneously retarded. As results, it was conformed that diffusion of oxygen ions was rate determinant in densification and grain growth of SnO2 ceramics.

  • PDF

Catalytic Effects of Heteroatom-doped Graphene Nanosheets on the Performance of Li-O2 Batteries

  • Bae, Youngjoon;Lim, Hee-Dae;Yun, Young Soo;Kang, Kisuk
    • Journal of Electrochemical Science and Technology
    • /
    • 제5권2호
    • /
    • pp.49-52
    • /
    • 2014
  • Graphene nanosheets (GNS), nitrogen-doped graphene nanosheets (N-GNS), and sulfur-doped graphene nanosheets (S-GNS) were successfully synthesized, and their catalytic effects on the oxygen reduction reaction (ORR) in $Li-O_2$ batteries were compared. The S-GNS electrode exhibited the highest ORR catalytic activity, resulting in enhanced discharge capacity and power capability. We attributed the enhanced ORR catalytic activity to the increased defect sites on graphene.

분위기 변화에 따른 반도성 $BaTiO_3$ 전기적 특성 연구 (Studies on the Electrical Properties of Semiconducting $BaTiO_3$ by Changing Sintering Atmosphere)

  • 최기영;한응학;박순자
    • 한국세라믹학회지
    • /
    • 제28권3호
    • /
    • pp.179-188
    • /
    • 1991
  • The semiconducting BaTiO3 ceramics used in this study were sintered in the reducing atomosphere(hydrogen gas) and neutral atmosphere(nitrogen gas), then were heat-treated in air to vary defect concentrations. In this experiment, the correlations between the composition analysis and electrical characteristics of these samples were investigated. When the BaTiO3 ceramics were sintered in N2 atmosphere, it was observed that the Ba contents near the interface were lower than that of the grain center, and these samples showed superior PTCR effects. From analysis of the resistivities of grains and grain boundaries by CIRM(Complex Impedance Resonance Method), it was confirmed that the PTCR effects were caused by the resistivity of grain boundaries. And from measurement of the capacitance at each temperature, the samples sintered in N2 atmosphere show the increase of room temperature resistance and the decrease of capacitance as a result of the increase of the charge depletion layers. This phenomenon agrees well with the cation deficiencies in the analytical results.

  • PDF

Progress in Si crystal and wafer technologies

  • Tsuya, Hideki
    • 한국결정성장학회지
    • /
    • 제10권1호
    • /
    • pp.13-16
    • /
    • 2000
  • Progress in Si crystal and wafer technologies is discussed on single crystal growth, wafer fabrication, epitaxial growth, gettering, 300 mm and SOI. As for bulk crystal growth, the mechanism of grown-in defects (voids) formation, the succes of grown-in defect free crystal growth technology and nitrogen doped crystal are shown. New wafer fabrication technologies such as both-side mirror polishing and etchingless process have been developed. The epitaxial growth of SiGe/Si heterostructure for high speed bipolar device is treated. Gettering technology under low temperature process such as RTP is important, and also it is shown that IG effect for Ni could be predicted using computer simulation of precipitate density and size. The development of 300 mm wafer and SOI has made progress steadily.

  • PDF

YAG상 첨가 탄화규소-질화규소 복합재료의 기계적 특성 (Mechanical Properties of Silicon Carbide-Silicon Nitride Composites Sintered with Yttrium Aluminum Garnet)

  • 이영일;김영욱;최헌진;이준근
    • 한국세라믹학회지
    • /
    • 제36권8호
    • /
    • pp.799-804
    • /
    • 1999
  • Composites of SiC-Si3N4 consisted of uniformly distributed elongated $\beta$-Si3N4 grains and equiaxed $\beta$-SiC grains were fabricated with $\beta$-SiC,. $\alpha$-Si3N4 Al2O3 and Y2O3 powders. By hot-pressing and subsequent annelaing elongated $\beta$-Si3N4 grains were grown via$\alpha$longrightarrow$\beta$ phase transformation and equiaxed $\beta$-Si3N4 composites increased with increasing the Si3N4 content owing to the reduced defect size and enhanced crack deflection by elongated $\beta$-Si3N4 grains and the grain boundary strengthening by nitrogen incorporation. Typical flexural strength and fracture toughness of SiC-40 wt% Si3N4 composites were 783 MPa and 4.2 MPa.m1/2 respectively.

  • PDF

Ga$_2$O$_3$ 나노벨트의 성장기구 (The Growth Mechanism of Ga$_2$O$_3$ Nanobelt)

  • 이종수;박광수;성만영;김상식
    • 대한전기학회논문지:전기물성ㆍ응용부문C
    • /
    • 제51권9호
    • /
    • pp.408-412
    • /
    • 2002
  • Ga$_2$O$_3$ nanobelts were synthesized from mechanically ground GaN powders with a thermal annealing in a nitrogen atmosphere. The nanobelts are with the range of about 10~200nm width and 10~50nm thickness. The nanobelt, growing along the direction perpendicular to the (010) plane and enclosed by (101) and (101) facets, shows no defect and no dislocation.

Ab initio Study for Electronic Property and Ferromagnetism of (Cu, N, or F)-codoped ZnO

  • Kang, Byung-Sub;Chae, Kwang-Pyo
    • Journal of Magnetics
    • /
    • 제17권3호
    • /
    • pp.163-167
    • /
    • 2012
  • The effects on the ferromagnetism of the O or Zn defect in Cu-doped ZnO with the concentration of 2.77-8.33% have been investigated by the first-principles calculations. The Cu doping in ZnO was calculated to be a kind of p-type ferromagnetic half-metals. When the Zn vacancy exists in Cu-doped ZnO, the Cu magnetic moment increases, while for the O vacancy it is reduced. It is noticeable that the ferromagnetic state was originated from the hybridized O(2p)-Cu(3d)-O(2p) chain formed through the p-d coupling. The carrier-mediated ferromagnetism by nitrogen or fluorine does not depend on their concentration.

Magnetic, Magneto-Optical, and Transport Properties of Ordered and Disordered 3d-Transition Metal Aluminide Films

  • Lee, Y.P.;Kim, K.W.;Rhee, J.Y.;Kudryavtsev, Y.V.
    • 한국진공학회지
    • /
    • 제7권s1호
    • /
    • pp.1-6
    • /
    • 1998
  • The influence of the order-disorder structural transition on the magnetic and mageto-optical, and transport properties of Fe-Al and Co-Al alloy films has been investigated. The disordered states in the alloy films were prepared by vapor quenching deposition on glass substrates cooled by liquid nitrogen. The experimental study of the magento-optical properties of the ordered and disordered Fe-Al and Co-Al alloy films has been carried out in 1.05-5.0 eV energy range at room temperature. The transport properties have been measured in 2-300K temperature range with and without magnetic field of 0.5T. The influence of the order-disorder structural transition on the magnetic and magneto-optical properties was discussed by using the effective medium approximation and the structural defect approach. That on the temperature dependence of the resistivity was analyzed in a framework of the partial localization of the electronic states and the variable range hopping conductivity.

  • PDF

청정도 가스 이송용 재료의 특성과 전해연마에 관한 연구 (A Study on the Characteristics of Electro Polishing and Utility Materials for Transit High Purity Gas)

  • 이종형;박신규;양성현
    • 한국산업융합학회 논문집
    • /
    • 제7권3호
    • /
    • pp.259-263
    • /
    • 2004
  • In the manufacture progress of LCD or semiconductor, there are used many kinds of gas like erosion gas, dilution gas, toxic gas as a progress which used these gas there are required high puritize to increase accumulation rate of semiconductor or LCD materials work progress of semiconductor or LCD it demand many things like the material which could minimize metallic dust that could be occured by reaction between gas and transfer pipe laying material, illumination of the surface, emition of the gas, metal liquation, welding etc also demand quality geting stricted. Material-Low-sulfur-contend (0.007-0010), vacuum-arc-remelt(VAR), seamless, high-purity tubing material is recommend for enhance welding lower surface defect density All wetted stainless steel surface must be 316LSS elecrto polishinged with ${\leq}0.254{\mu}m$($10.0{\mu}in$) Ra average surface finish, $Cr/Fe{\geq}1.1$ and $Cr_2O_3$ thickness ${\geq}25{\AA}$ From the AES analytical the oxide layer thickness (23.5~36 angstroms silicon dioxide equivalent) and chromum to iron ratios is similar to those generally found on electropolished stainless steel., molybdenum and silicon contaminants ; elements characteristic of stainless steel (iron, nickel and chromium); and oxygen were found on the surface Phosphorus and nitrogen are common contaminants from the electropolish and passivation steps.

  • PDF

Liquid Crystal Alignment Effects on Nitrogen-doped Diamond like Carbon Layer by Ion Beam Alignment Method

  • Han, Jeong-Min;Choi, Sung-Ho;Kim, Byoung-Yong;Han, Jin-Woo;Kim, Jong-Hwan;Kim, Young-Hwan;Hwang, Jeoung-Yeon;Lee, Sang-Keuk;Ok, Chul-Ho;Seo, Dae-Shik
    • Transactions on Electrical and Electronic Materials
    • /
    • 제8권1호
    • /
    • pp.46-50
    • /
    • 2007
  • We have studied the nematic liquid crystal (NLC) alignment effects on a nitrogen-doped diamond-like carbon (NDLC) thin film layer with ion beam irradiation. The pretilt angle for NLC on the NDLC surface with ion beam exposure was observed below 1 degree. Also, we had the good LC alignment characteristics on the NDLC thin films with ion beam exposure of 1800 eV. In thermal stability experiments, the alignment defect of the NLC on the NDLC surface with ion beam irradiation above annealing temperature of $250^{\circ}C$ can be observed. Therefore, the good thermal stability and LC alignment for NLC by ion beam aligned NDLC thin films can be achieved.