• 제목/요약/키워드: nitrogen ($N_2$)

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Effects of Nitrogen Sources and C/N Ratios on the Lipid-Producing Potential of Chlorella sp. HQ

  • Zhan, Jingjing;Hong, Yu;Hu, Hongying
    • Journal of Microbiology and Biotechnology
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    • 제26권7호
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    • pp.1290-1302
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    • 2016
  • Microalgae are being researched for their potential as attractive biofuel feedstock, particularly for their lipid production. For maximizing biofuel production, it is necessary to explore the effects of environmental factors on algal lipid-producing potential. In this study, the effects of nitrogen (N) sources (NO2-N, NO3-N, urea-N, NH4-N, and N-deficiency) and carbon-to-nitrogen ratios (C/N= 0, 1.0, 3.0, and 5.0) on algal lipid-producing potential of Chlorella sp. HQ were investigated. The results showed that for Chlorella growth and lipid accumulation potential, NO2-N was the best amongst the nitrogen sources, and NO3-N and urea-N also contributed to algal growth and lipid accumulation potential, but NH4-N and N-deficiency instead caused inhibitory effects. Moreover, the results indicated that algal lipid-producing potential was related to C/N ratios. With NO2-N treatment and carbon addition (C/N = 1.0, 3.0, and 5.0), total lipid yield was enhanced by 12.96-20.37%, but triacylglycerol (TAG) yields decreased by 25.52-94.31%. As for NO3-N treatment, carbon addition led to a 17.82-57.43%/25.86-82.67% reduction of total lipid/TAG yields. When NH4-N was used as the nitrogen source, total lipid/TAG yields were increased by 46.67-113.33%/28.99-74.76% with carbon addition. The total lipid/TAG yields of urea-N treatment varied with C/N ratios. Overall, the highest TAG yield (TAG yield: 38.75 ± 5.21 mg/l; TAG content: 44.16 ± 4.35%) was achieved under NO2-N treatment without carbon addition (C/N = 0), the condition that had merit for biofuel production.

질소구배에 따른 대두개체군의 생장 및 일차생산성 (Effect of Nitrogen Applications on the Growth and Primary Production of Soybean Population)

  • Song, Seung-Dal;Seung-Won Yu
    • The Korean Journal of Ecology
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    • 제3권1_2호
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    • pp.11-16
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    • 1980
  • 무시비구, 질소시비구(6.67gN/$m^2$) 및 과질소비구(13.34gN/$m^2$)의 질소구배처리에 따른 대두개체군의 생육과정별 제 생장해석적특징 및 일차생산성을 비교검토하였다. 질소시비구 및 과질소시비구에서는 대조구에 비해 8~10배의 순질소흡수율과 비교적 높은 생산성 및 최대 LAI의 도달이 2주정도 빨리 나타났고 SLA의 증가를 보였으나, 근립의 형성은 1/3~1/4의 감소를 보였다. 그러나, H, F/C, T/R, RGR, NAR, 및 CGR 등 생장해석적특징에는 큰 유의차가 없었다.

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질소 시비 구배에 따른 묵밭의 식물 군집 반응 (Response of Old-field Plant Community to an Experimental Nitrogen Gradient)

  • Lee, Kyu-Song;Joon-Ho Kim
    • The Korean Journal of Ecology
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    • 제19권4호
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    • pp.341-351
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    • 1996
  • In order to elucidate the differences in early successional development among similary aged old-fields having different soil nitrogen (N), caused by the land use history before at abandonment, the response of plant community along an experimental nitrogen gradient (control plot (No), plot NI with 5.8g $N/m^2$, plot N2 with 11.7g $N/m^2$ and plot N3 with 23.3g $N/m^2$) was investigated in a five-year-old abandoned field. Although the N content in soil among treatments was similar at the end of the growing season, N concentrations in plant tissue increased with the amount of N supplied. These results suggest that almost all the N contained in N-enriched soil might be absorbed by plants during the growing season after N supply. Vegetation tended to grow vigorously by nitrogen supply, and the standing biomass increased significantly in plots NI and N2 . Species richness of plants, especially of annuals and perennials, was more reduced than the control plot, and the species diversity was also reduced by N supply. The importance value (IV) of species by N supply differed in each species along the position on the successional sere: Artemisia princeps var. orientalis as the dominant species in this old-field decreased slightly; annuals as the earlier successional species decreased clearly along nitrogen gardients; Erigeron annuals as the earlier successional species and as a strong competitor with Artemisia princeps var. orientalis had the highest IV by small N supply; Miscanthus sinensis and Rubus crataegifolius as the later successional species increased by large N supply. These results suggest that old-fields with high soil N might show the structural and functional characteristics of the earlier successional stages, but community composition in those old-fields might be changed more quickly from the sarlier successional species than the later successional species.

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Nitrogen mustard류의 합성에 관한 연구 (Studies on the synthesis of nitrogen mustard derivatives)

  • 채동규;천문우;채건
    • 약학회지
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    • 제13권4호
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    • pp.139-143
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    • 1969
  • In order to diminish the side effects of nitrogen mustard on cancertherapy, alkyl and heterocyclic radicals were introduced to nitrogen mustard base. The prepared new nitrogen mustard derivtives are N-bis($\beta$-chloroethyl)-2-furamide, 5-nitro-N-bis($\beta$-chloroethyl)-2-furamide and N-bis($\beta$-chloroethyl) ortamide hydrochloride.

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Visible-photoresponsive Nitrogen-Doped Mesoporous TiO2 Films for Photoelectrochemical Cells

  • Bae, Jae-Young;Yun, Tae-Kwan;Ahn, Kwang-Soon;Kim, Jae-Hong
    • Bulletin of the Korean Chemical Society
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    • 제31권4호
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    • pp.925-928
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    • 2010
  • Nitrogen-doped $TiO_2$ ($TiO_2$:N) nano-particles with a pure anatase crystalline structure were successfully synthesized through the hydrolysis of $TiCl_4$ in an ammonia aqueous solution. The samples were characterized using X-ray diffraction (XRD), transmission electron microscopy (TEM), $N_2$-sorption, and UV-vis diffuse reflectance spectra (UV-vis DRS) techniques. The absorption edge of nitrogen-doped $TiO_2$ shifted into the visible wavelength region. The photoelectrochemical (PEC) performances were investigated for the $TiO_2$ mesoporous electrodes doped with different nitrogen concentrations. The $TiO_2$:N electrodes exhibited much higher PEC responses compared to the pure $TiO_2$ electrode because of the significantly enhanced visible-photoresponsibility of the $TiO_2$:N electrodes.

Effects of nitrogen gas flushing in comparison with argon on rumen fermentation characteristics in in vitro studies

  • Park, KiYeon;Lee, HongGu
    • Journal of Animal Science and Technology
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    • 제62권1호
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    • pp.52-57
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    • 2020
  • In rumen in vitro experiments, although nitrogen gas (N2) flushing has been widely used, its effects on rumen fermentation characteristics are not clearly determined. The present study is the first to evaluate the effects of N2 flushing on rumen fermentation characteristics in in vitro batch culture system by comparing with new applicable non-metabolizable gas: argon (Ar). The rumen fluid was taken from two Korean native heifers followed by incubation for 3, 9, 12, and 24 h with N2 or Ar flushing. As a result, in all incubation time, N2 flushing resulted in higher total gas production than Ar flushing (p < 0.01). Additionally, in N2 flushing group, ammonia nitrogen was increased (p < 0.01). However, volatile fatty acids profiles and pH were not affected by the flushing gases (p > 0.05). In conclusion, the present study demonstrated that N2 flushing can influence the rumen nitrogen metabolism via increased ammonia nitrogen concentration and Ar flushing can be used as a new alternative flushing gas.

부분질산화와 혐기성 암모늄산화를 이용한 돈사폐수처리 (Piggery Waste Treatment using Partial Nitritation and Anaerobic Ammonium Oxidation)

  • 황인수;민경석;이영옥
    • 한국물환경학회지
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    • 제22권4호
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    • pp.599-604
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    • 2006
  • Nitrogen removal with the combined SHARON (Single reactor system for high ammonium removal over nitrite)ANAMMOX (Anaerobic ammonium oxidation) process using the effluent of ADEPT (Anaerobic digestion elutriated phased treatment) slurry reactor with very low C/N ratio for piggery waste treatment was investigated. For the preceding SHARON reactor, ammonium nitrogen loading and removal rate were $0.97kg\;NH_4-N/m^3_{reactor}/day$ and $0.68kg\;NH_4-N/m^3_{reactor}/day$ respectively. In steady state, bicarbonate alkalinity consumption for ammonium nitrogen converted to $NO_2-N$ or $NO_3-N$ was 8.4 gram per gram ammonium nitrogen. The successive ANAMMOX reactor was fed with the effluent from SHARON reactor. The loading and removal rate of the soluble nitrogen defined as the sum total of $NH_4-N$, $NO_2-N$ and $NO_3-N$ in ANAMMOX reactor were $1.36kg\;soluble\;N/m^3_{reactor}/day$ and $0.7kg\;soluble\;N/m^3_{reactor}/day$, respectively. The average $NO_2-N/NH_4-N$ removal ratio by ANAMMOX was 2.41. Fluorescence in situ hybridization (FISH) analysis verified that Candidatus Kuenenia stuttgartiensis were dominate, which means that they played an important role of nitrogen removal in ANAMMOX reactor.

팔당호의 질소거동과 수지 (The Nitrogen Behavior and Budget in Lake Paldang)

  • 이장호;박혜경;이규;김은미
    • 한국물환경학회지
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    • 제26권1호
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    • pp.71-80
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    • 2010
  • We studied the nitrogen behavior and budget of Lake Paldang from March to December 2008. The particulate nitrogen (PN) concentrations ranged from 7 to 13% of the total nitrogen concentration (TN) in the stream inflows, the downstream outflow, and the lake water. The nitrate nitrogen ($NO_3-N$) concentration ranged from 67 to 78% of the TN. In the three rivers of Lake Paldang, Gyeongan River (In3 site) had the highest average of the TN, 5.037 mgN/L, but North Han River (In2 site) had the lowest average TN, 1.683 mgN/L. South Han River (In1 site) had the average TN of 2.399 mgN/L. In the dam discharge, TN showed the average 2.063 mgN/L. In the lake water, L4 site (Gyeongan River area) had the highest average TN, 3.781 mgN/L, but L3 site (North Han River) had the lowest average TN, 1.587 mgN/L. Total input of nitrogen loads to Lake Paldang was about 30,875 ton/year in 2008. Inflow rivers contributed 30,643 ton/year (South Han River: 18,111 ton/year (59%), North Han River: 11,333 ton/year (37%), and Gyeongan River: 1,199 ton/year (4%)). The atmospheric deposition had 135 ton/year, the nitrogen release from the bottom sediments had 88 ton/year, and macrophytes had 9 ton/year. Total output of nitrogen loads from Lake Paldang was about 31,256 ton/year. The downstream from dam contributed 29,877 ton/year, and the sediment deposition was 1,379 ton/year.

BACC를 이용한 축산폐수의 암모니아성 질소 및 유기물의 제거 II. COD/N비가 질소 및 유기물 제거에 미치는 영향 (Removal of Ammonia Nitrogen and Organics from Piggery Wastewater Using BACC Process-II. Effect of COD/N on Removal of NItrogen and Organics)

  • 성기달;류원률;김인환;조무환
    • KSBB Journal
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    • 제16권2호
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    • pp.140-145
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    • 2001
  • To treat piggery wastewater containing refractory compounds including nitrogen, physical treatments using zeolite and biological processes were investigated. In biogical treatment, the removal efficiencies of organics and nitrogen in bioreador using BACC (Biological Activated Carbon Cartridge) media filled with granule activated carbon were examined. The best removal efficiencies achieved for TKN and COD(sub)cr were 82% and 53% respectively, when zeolite dosage was 300 g/L. Specific nitrogen removal ability was 3.2 mg/g at a zeolite dosage of 50 g/L, whereas specific nitrogen removal ability was 1.8 mg/g at a zeolite dosage of 300 g/L. The increased of C/N ratio resulting from the removal of nitrogen using zeolite led to an increase in removal efficiency of organics. As C/N ratio was increased to 2.0, 2.44 and 6.58 at a HRT of 48 hours in a BACC bioreactor, removal efficiencies of COD(sub)cr were increased to 53.5%, 57.4% and 80.6%. The removal efficiency of wastewater using a zeolite dosage of 399 g/L was increased by 27.1% compared to that of control treatment.

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고온 가스질화 된 STS 430 스테인리스강의 냉간 가공성에 미치는 항온변태 열처리 시간 변화의 영향 (Effect of Isothermal Transformation Heat-treatment Time on Cold Workability of STS 430 Stainless Steel after High Temperature Gas Nitriding)

  • 김정민;현양기;송상우;김기동;손영호;성장현
    • 열처리공학회지
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    • 제27권1호
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    • pp.15-22
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    • 2014
  • This study is to investigate the phase changes and cold workability after isothermal transformation at $780^{\circ}C$ by using the high temperature gas nitrided (HTGN) STS 430 ferritic stainless steel specimens. The phase diagram of STS 430 steel obtained by calculation showed that the phase appeared at $1100^{\circ}C$ showed as ${\alpha}+{\gamma}{\rightarrow}{\gamma}{\rightarrow}{\gamma}+Cr_2N{\rightarrow}{\gamma}+Cr_2N+CrN$ with increasing nitrogen concentration. Also, the transformation of ${\gamma}{\rightarrow}Cr_2N$ during heat treatment isothermally at $780^{\circ}C$, nitrogen pearlite with lamellar type was fully formed at the nitrogen permated surface layer for 10 hrs. However, this transformation was not completed for 1 hr, resulting nitrogen pearlite plus martensite. The cold rolled specimen of isothermally transformed at $780^{\circ}C$ for 10 hrs after high temperature gas nitriding decreased the layer thickness of nitrogen pearlite inducing the deformation of hard $Cr_2N$ phase. the dissolution rate of $Cr_2N$ phase increased rapidly with increasing cold rolling ratio. Specimens with the microstructure of nitrogen pearlite (isothermally transformed at $780^{\circ}C$ for 10 hrs) were possible to cold rolling without crack formation. However, the mixed structures of nitrogen pearlite + martensite (isothermally transformed at $780^{\circ}C$ for 1 hr) were impossible to cold deformation without cracking.