• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 2005.10a
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• pp.105-108
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• 2005

Sliding wear mechanism of a high nitrogen austenitic 18Cr-18Mn-2Mo-0.9N steel has been investigated. Dry sliding wear tests of the steel were carried out at various loads of 1N-10N under a constant sliding speed condition of 0.15m/s against AISI 52100 bearing steel balls. Solution $(1050^{\circ}C)$ and isothermal aging $(900^{\circ}C)$ heat treatments were performed on the steel and the effect of the heat treatments on the wear were investigated. Wear rates of the solution-treated steel specimen remained low until 5N, and then increased abruptly at loads above 5N. The rates of isothermally aged specimens were low and increased gradually with the applied load. Worn surfaces, their cross sections, and wear debris of the steel specimens were examined with a scanning electron microscopy. Phases of the heat-treated specimen and the wear debris were identified using XRD. Phases transformed underneath the sliding track during the wear were investigated and analyzed using TEM. Effects of the phase transformation during the wear and $Cr_2N$ precipitates formed during the isothermal aging on the wear of the austenitic steel were discussed.

• Korean Journal of Soil Science and Fertilizer
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• v.27 no.3
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• pp.232-237
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• 1994

Field microplot(D 20cm, 1 85cm) experiment filled with Bonryang sandy loam soil(Typic Udifluvents) was conducted to obtain quantitative information on the movement of applied nitrogen under different soil moisture regimes and ladino clover cultivation. Urea applied to the soil was quickly transformed into $NH_4$-N which was slowly to $NO_3$-N which governed the downward movement of inorganic N applied in the soil. Downward movement of inorganic nitrogen was relatively slow in the early growing stages of ladino clover when $NH_4$-N form was the major inorganic nitrogen in the soil. In the later growing stages when $NO_3$-N was the major form, inorganic nitrogen moved rapidly with soil water. Favorable soil moisture condition increased downward movement and plant uptake of inorganic nitrogen. In the non irrigated bare soil 92% of applied nitrogen was leached downwards out of the microplots at the final harvest. Under the non-irrigated condition 57% of applied nitrogen was taken up by plants and 37% of nitrogen remained in the soil 5.5 months after sowing. Nitrogen uptake by plants in the microplots irrigated at 0.2 bar was 4.03g/microplot at the final harvest, which was more than the amount of nitrogen applied.

• YAKHAK HOEJI
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• v.38 no.6
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• pp.673-676
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• 1994

The each nitrogen site of ifosfamide metabolite isophosphoramide mustard was synthesized with isotope enriched nitrogen. $Gylcine-^{15}N$ was converted to $2-chloroethylamine-^{15}N$ hydrochloride which was then reacted with phenyl dichlorophosphate to provide $N,N'-bis(2-chloroethyl)phosphordiamidic-^{15}N_2$ acid phenylester(50%, $PhO(O)^{15}N(CH_2CH_2Cl_2)$. Catalytic hydrogenation of this phenyl ester followed by the addition of cyclohexylamine (CHA) provided $IPM-^{15}N$ as the CHA salt(70%).

• Molecules and Cells
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• v.23 no.1
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• pp.72-79
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• 2007

Demand for low-input sustainable crop cultivation is increasing to meet the need for environment-friendly agriculture. Consequently, developing genotypes with high nutrient use efficiency is one of the major objectives of crop breeding programs. This study was conducted to identify QTLs for traits associated with physiological nitrogen use efficiency (PNUE). A recombinant inbred population (DT-RILs) between Dasanbyeo (a tongil type rice, derived from an indica ${\times}$ japonica cross and similar to indica in its genetic make-up) and TR22183 (a Chinese japonica variety) consisting of 166 $F_8$ lines was developed and used for mapping. A frame map of 1,409 cM containing 113 SSR and 103 STS markers with an average interval of 6.5 cM between adjacent marker loci was constructed using the DT-RILs. The RILs were cultivated in ordinary-N ($N-P_2O_5-K_2O=100-80-80kg/ha$) and low-N ($N-P_2O_5-K_2O=50-80-80kg/ha$) (100 kg/ha) conditions. PNUE was positively correlated with the harvest index and grain yield in both conditions. Twenty single QTLs (S-QTLs) and 58 pairs of epistatic loci (E-QTLs) were identified for the nitrogen concentration of grain, nitrogen concentration of straw, nitrogen content of shoot, harvest index, grain yield, straw yield and PNUE in both conditions. The phenotypic variance explained by these S-QTLs and E-QTLs ranged from 11.1 to 44.3% and from 16.0% to 63.6%, respectively. The total phenotypic variance explained by all the QTLs for each trait ranged from 35.8% to 71.3%, showing that the expression of PNUE and related characters depends signify- cantly upon genetic factors. Both S-QTLs and E-QTLs may be useful for marker-assisted selection (MAS) to develop higher PNUE genotypes.

• Membrane and Water Treatment
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• v.15 no.2
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• pp.59-66
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• 2024

This study evaluated the performance of a membrane aerated biofilm reactor (MABR) for nitrogen removal from a high-strength ammonia nitrogen-containing wastewater. The experimental setup consisted of four compartments that are sequentially anaerobic and aerobic to achieve complete nitrogen removal. The last compartment of the reactor setup contained a membrane bioreactor (MBR) to reduce sludge production in the system and to obtain a better-quality effluent. Continuous experiment over a period of 47 days showed that MABR exhibited excellent NH₄⁺-N removal efficiency (99.5%) compared to the control setup without MABR (56.5%). The final effluent NH₄⁺-N concentration obtained in the MABR was 2.99±1.56 mg/L. In contrast to NH₄⁺-N removal, comparable TOC removal values in the MABR and the control reactor (99.2% and 99.3%, respectively) showed that air supply through MABR is much more critical for denitrification than for organic removal. Further study to understand the effect of air supply rate and holding pressure on NH₄⁺-N removal in MABR revealed that an increase in both these parameters positively impacted reactor performance. These parameters are related to oxygen supply to the biofilm formed over the membrane surface, which in turn influenced NH₄⁺-N removal in MABR. Among the two different strategies to control biofilm over the membrane surface, results showed that scouring for a duration of 10 min on a weekly basis, along with mixing air supply, could be an effective method.

• Korean Chemical Engineering Research
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• v.61 no.4
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• pp.604-610
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• 2023

The nitrogen reduction reaction (NRR), which produces NH₃ by reducing N₂ under ambient conditions, is attracting attention as a promising technology that can reduce energy consumption in industrial processes. We investigated the adsorption behaviors at various active sites on the Ni (100) surface, which is widely used among catalytic metal surfaces capable of adsorbing and activating N₂, based on density-functional theory calculations. We also investigated two N₂ adsorption structures, so-called end-on and side-on structures. We find that for the end-on case, N₂ is adsorbed on a top site, and the reaction proceeded in a distal pathway, while for the side-on case, N₂ is adsorbed on a bridge site, and the reaction proceeded with enzymatic pathway. Finally, this study provides insight into the adsorption of metal catalyst surfaces for the NRR reactions based on the calculated Gibbs free energy profiles of the thermodynamically most favorable pathways.

• Korean Journal of Plant Resources
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• v.11 no.2
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• pp.119-123
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• 1998

Effects of elevated CO2 and temperature on nitrogen (N) uptake , leaf N concentration, N partitioning , N use efficiency (NUE) and grain yield of pot and field grown rice (Oryza sativa. L.cv. Chukwangbyeo) under canopy-like conditions were studied over three years. Rice plants were grown in pots and in the field in temperature gradient chambers containing either ambient(350ppm) or elevated CO2 concentrations (690 or 650ppm) in conbination with either four or seven temperature regimes ranging form ambient temperature(AT) to AT plus 3$^{\circ}C$. There were three N supplies 94g or 6g m-2 to 20g or 48g m-2.Elevated CO2 increased N uptake in field-grown rice ; the magnitude of this effect was thelargest (+15%) at the highest N level. However, in pot-grown rice, N uptake was suppressed with the effect was the largest at high N levels. Leaf N concentration declined at elevated CO2 mainly due to a decrease in N partitiioning to the leaf blades. Air temperature had little effect on the N parameters mentioned previously, wherease NUE for spikelet production declined rapidly with increased temperature irrespective of CO2 concentration. The response of the biomass to elevated CO2 varied with N level, with the greatest response at 20g N m-2 (+30%) . At AT, where high temperature-induced sterility was generally not observed, elevated CO2 increased yield. However, the magnitude of this effect varied greatly (2-39%) with N level, and was mainly dependent on the magnitude of the increase in spikelet number.

• Korean Journal of Soil Science and Fertilizer
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• v.47 no.1
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• pp.59-65
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• 2014

Generally, nitrogen (N) fertilization higher than the recommended dose is applied during vegetable cultivation for increasing in productivity. However, excessive N application rate beyond plant requirement could cause adverse environmental impact such as nitrate leaching and nitrous oxide emission. In this experiment, the impacts of N fertilization was studied on nitrous oxide ($N_2O$) emission to standardize the optimum fertilization level for minimizing of $N_2O$ emission as well as most of the crop productivity. Herein, we assessed the $N_2O$ emission in the flat upland soil which was cultivated with different N application rates on red pepper for 3 years (2010~2012). $N_2O$ emission was measured in chemical N fertilizer amounts 0 (N 0), 95 (N 0.5), 190 (N 1.0), $380(N_2.0)kgha^{-1}$ by using the abnormal shape chamber closed repeating three times. In average for 3 years, the total $N_2O$ emissions of each treatment in field of soybean were 2.110 (N 0), 3.165 (N 0.5), 5.039 (N 1.0), and $7.228(N_2.0)kgN_2Oha^{-1}yr^{-1}$, respectively. And then the primary regression between nitrogen fertilizer amount and the total $N_2O$ emission was showed as y = 0.0138x + 2.0942 ($r^2=0.9885$), and an average of the emission factor was $EF_1$ 0.0148(0.0118~0.0191) $N_2O-NkgN^{-1}kg^{-1}$ from 2010 to 2012. The result was a little higher than the emission default of the IPCC 1996 Guideline ($EF_1$ 0.0125) when the results are converted into $N_2O$ emission factor.

• Korean Journal of Soil Science and Fertilizer
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• v.24 no.3
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• pp.171-176
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• 1991

Field experiment was conducted to investigate the seasonal change in inorganic nitrogen content in grassland soil profile after urea application. Urea was applied at the levels of 0 (0N), 14 (14N), and 28 (28N) Kg N per 10a. Soil samples were taken at every 20 cm interval upto 100 cm soil depth in spring (May 26), summer (July 27), and autumn (October 18) and analysed for total and inorganic nitrogen ($NH_4-N$ and $NO_3-N$). The results obtained are as follows ; 1. In spring, the $NH_4-N$ content of ON treatment was higher than $NO_3-N$ content both in surface and subsoil. The urea application increasing both $NH_4-N$ and $NO_3-N$ contents in the surface soils and these contents decreased with soil depth. 2. In summer, increase in urea application rate elevated the $NO_3-N$ content in soil profile of 0 to 100cm and the content reached upto 42 ppm in the 28N treatment. 3. The seasonal difference in $NH_4-N$ content between summer and autumn was insignificant throughout soil profile. Soil $NO_3-N$ content in autumn were 7 and 14 ppm for 14N and 28N respectively, showing very low values compared with that of summer. 4. The ratio of inorganic nitrogen to total nitrogen increased with soil depth and with urea application rates.

• Journal of the Korean Society for Heat Treatment
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• v.10 no.1
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• pp.30-39
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• 1997

After changing the heat treating atmosphere of nitrogen gas, argon gas and vacuum, the nitrogen contents, microstructural changes, hardness and corrosion resistance of 0.25wt.%N alloyed super duplex stainless steel have been investigated in the temperature range from $1050^{\circ}C$ to $1350^{\circ}C$. The nitrogen content showed to be increased up to 0.36wt.% after heat treating the specimen in nitrogen gas at $1200^{\circ}C$, while the decrement of nitrogen content in vacuum atmosphere was shown down to 0.03wt.% at $1350^{\circ}C$. After heat treating in the mixed gas atmosphere of argon and nitrogen at $1250^{\circ}C$, the surface ${\gamma}$ phase existed as ${\alpha}+{\gamma}$ phase increased with increasing nitrogen gas content. The ${\gamma}$ single phase appeared at the surface above $80%N_2$ gas, while the surface ${\alpha}$ single phase was shown below $20%N_2$ gas. When heat treating the specimen in nitrogen gas at $1050^{\circ}C$, the hardness of austenite phases increased above Hv 40 at the surface layer compared to the hardness of the core parts, while decrement of denitriding effect caused to the hardness nearly unchanged between surface and the core parts after heat treating in vacuum atmosphere. The surface ${\gamma}$ single phase specimen showed superior corrosion resistance than the surface ${\alpha}$ single phase specimen. The surface ${\alpha}$ phase existed in the ${\alpha}+{\gamma}$ microstructure showed higher corrosion resistance after heat treating in the nitrogen gas atmosphere than the ${\alpha}$ phase heat treated in the argon gas and vacuum atmosphere.