• Title/Summary/Keyword: nitrate model

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Experimental detemination of Half-Saturation Coefficient for Nitrifying Bacteria by Infinite Dilution Method (무한희석법(無限稀釋法)을 이용한 질산화(窒酸化) 미생물(微生物) 반포화계수(半飽和係數) 결정(決定)에 관한 실험적(實驗的) 연구(硏究))

  • Lee, Byong-Hee
    • Journal of Korean Society of Water and Wastewater
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    • v.12 no.1
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    • pp.62-69
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    • 1998
  • To remove nitrogen from wastewater, ammonia nitrogen has to be oxidized to nitrate nitrogen before denitrification reaction which converts nitrate nitrogen to nitrogen gas. In order to understand nitrification, several mathematical models had been proposed and Monod type model has been accepted internationally. Since Monod type model consists of maximum substrate utilization rate, substrate concentration and half-saturation coefficient, these values have to be addressed before using Monod type model. Several experimental procedures to determine half-saturation coefficient have been developed, however, Infinite dilution method was known to be time saving procedure. In this study, the mathematical equations and experimantal procedures for Infinite dilution method are presented and this method is used to determine half-Saturation coefficient for nitrifying bacteria. As results, Infinite dilution method is proved that this coefficient can be determined within 8 hours and the values of half-saturation coefficient has a range of 0.728 and $0.455gNH_4{^+}-N/m^3$ and the average has $0.580gNH_4{^+}-N/m^3$ through 5 sets of experiments.

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Quantifying nitrogen source contribution ratios using stable isotope method: Application of Bayesian mixing model (안정동위원소를 이용한 하천에서의 질소오염원 기여율 정량화: Bayesian 혼합모델의 적용)

  • Nam, Tae-Hui;Ryu, Hui-Seoung;Kang, Tae-Woo;Han, Yeong-un;Kim, Jihyun;Lee, Kyounghee;Hwang, Soonhong;Kim, Kyunghyun
    • Journal of Korean Society on Water Environment
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    • v.35 no.6
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    • pp.510-519
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    • 2019
  • The 'Stable Isotope Analysis in R' (SIAR), one of the Bayesian mixing models for stable isotopes, has been proven to be useful for source apportionment of nitrates in rivers. In this study, the contribution ratios of nitrate sources were quantified by using the SIAR based on nitrogen and oxygen stable isotope measurements in the Yeongsan River. From the measurements, it was found that the values of δ15N-NO3 and δ18O-NO3 ranged from -8.2 ‰ to +13.4 ‰ and from +2.2 ‰ to +9.8 ‰, respectively. We further analyzed the contribution ratios of the five nitrate sources by using the SIAR. From the modeling results, the main nitrate source was found to be soil N (29.3 %), followed by sewage (26.7 %), manure (19.6 %), chemical fertilizer (17.9 %) and precipitation (6.3 %). From the results, it was found that the anthropogenic sources, i.e., sewage, manure and chemical fertilizer contribute 64.2% of the total nitrate inflow from the watershed. Due to the significant correlation of δ15N-NO3 and lnNO3- in this study, the fractionation factors reflecting the biogeochemical processes of stable isotope ratios could be directly obtained. This may make the contribution ratios obtained in this study more precise. The fractionation factors were identified as +3.64 ± 0.91 ‰ for δ15N-NO3 (p<0.01) and -5.67 ± 1.73 ‰ for δ18O-NO3(p<0.01), respectively, and were applied in using the SIAR. The study showed that the stable isotope method using the SIAR could be applied to quantitatively calculate the contribution ratios of nitrate sources in the Yeongsan River.

Investigations of Ferroelectric Polarization Switching in Potassium Nitrate Composite Films

  • Kumar, Neeraj;Nath, Rabinder
    • Transactions on Electrical and Electronic Materials
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    • v.15 no.2
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    • pp.60-65
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    • 2014
  • This article explains the experimental results of ferroelectric polarization switching (FPS) of potassium nitrate ($KNO_3$) with different polymers such as polyvinylidene fluoride (PVDF) and polyvinyl fluoride (PVF) using simple melt-press techniques. To analyze the ferroelectric polarization switching in potassium nitrate ($KNO_3$) composite films at room temperature, we applied the Ishibashi and Takagi theory (based on Avrami model) to the switching current transient. To investigate the dimensionality of domain growth, the ferroelectric polarization switching current (FPS current) was observed from the square - wave bipolar signals across a resistance of $0.1k{\Omega}$ in series with the composite films. The existence of a switching current transient pulse confirmed the ferroelectricity and indicated the stability of the ferroelectric phase (phase III) of $KNO_3$ at room temperature. Polarization hysteresis (P-E) characteristics supported the prominent features of ferroelectric polarization switching in the composite films at room temperature.

BIOCHEMICAL MODEL AND MECHANISM FOR ACINETOBACTER NITRITE INHIBITION

  • Lee, Chan-Won;Weon, Seung-Yeon
    • Environmental Engineering Research
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    • v.10 no.1
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    • pp.22-30
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    • 2005
  • Nitrite accumulation is not unusual in batch processes such as sequencing batch reactor (SBR) with high-strength of ammonium or nitrate wastewaters. A possible mechanism of nitrite inhibition on Acinetobacter was depicted in a biochemical model, which the protonated species, nitrous acid form of nitrite, affects proton relating transport at the proton-pumping site crossing the cell membrane under unlimited carbon and phosphorus conditions. This effect exerts inhibition of phosphorylation under aerobic condition and yields low APT/ADP ratio, consequently decrease poly-P synthesis and phosphorus uptake from outside the cell in the model.

Assessments of Nitrate Budget by Currents and Biogeochemical Process in the Korea Strait based on a 3D Physical-Biogeochemical Coupled Model (3차원 물리-생지화학 결합 모델을 이용한 대한해협 주변의 해류와 생지화학적 요인에 의한 질산염 유출입 평가)

  • TAK, YONG JIN;CHO, YANG KI
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.27 no.1
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    • pp.1-16
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    • 2022
  • Nitrate (NO3-) plays an important role in aquaculture and ecosystems in the Korea Strait. Observational data propose that ocean currents are crucial to NO3- budget in the Korea Strait. However, assessment of budget by currents and biogeochemical processes has not yet been investigated. This study examines seasonal and spatial variations in NO3- budget by currents and biological processes in the Korea Strait from 2011 to 2019 using a physical-biogeochemical coupled model. Model results suggest that current-driven net supply of NO3- is consumed by uptake of phytoplankton in the Korea Strait. Advective influx is driven by the Tsushima warm current and the influx by the Jeju warm current is approximately one third of it. All of the influxes are transported out to the East Sea through the Korea Strait, of which two third passes through the western channel and the rest through the eastern channel. Annual mean NO3- net transport show that currents supply NO3- year round except for January, but the budget by biogeochemical processes consumes it every season except for winter.

Optimization of the Medium Composition for Heteropolysaccharide-7 Production by Beijerinckia indica L3 Using Response Surface Methodology (표면반응방법을 이용한 Beijerinckia indica L3에 의한 PS-7 생산 최적화)

  • Ra, Chae-Hun;Kim, Ki-Myong;Hoe, Pil-Woo;Choi, Mi-Ran;Kim, Sung-Koo
    • Journal of Life Science
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    • v.18 no.2
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    • pp.162-166
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    • 2008
  • The production of heteropolysaccharide-7 (PS-7) by Beijerinckia indica (B. indica L3) was evaluated in shaker flask culture. The medium optimization was studied using response surface methodology (RSM). A five-level three-factor central composite design was employed to determine the maximum PS-7 yield at optimum levels for whey lactose, glucose and ammonium nitrate contents. The validity of the model could be determined by the regression coefficient, $R^2$. The values of $R^2$ were 0.72, 0.64 and 0.85 in PS-7, DCW and viscosity, respectively. The optimal medium combinations of whey lactose, glucose and ammonium nitrate concentrations on the PS-7 production were whey lactose (2%), glucose (1 %) and ammonium nitrate 5 mM, respectively. The result indicated that PS-7 production was affected significantly by the addition of glucose to whey lactose based on medium and C/N ratio.

Influence of Nitrite and Ascorbic Acid on N-Nitrosamine Formation during Fermentation of Salted Anchovy (멸치젓 숙성중 아질산염과 아스코르브산이 N-Nitrosamine의 생성에 미치는 영향)

  • 김정균;이수정;성낙주
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.26 no.4
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    • pp.606-613
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    • 1997
  • The changes of contents in trimethylamine oxide nitrogen(TMAO-N), trimethylamine nitrogen(TMA-N), dimethylamine nitrogen(DMA-N), nitrite nitrogen(nitrite-N), nitrate nitrogen(nitrate-N) and the effect on the formation of N-nitrosamine(NA) during fermentation were investigated with salted anchovy added different amounts of sodium nitrite, sodium nitrate and ascorbic acid, respectively. When the sodium nitrite was added in salted anchovy, the contents of nitrite-N was decreased during fermentation . Whereas the formation of N-nitrosodimethylamine(NDMA ) was increased . Contents of TMAO-N was decreased, while TMA-N and DMA-N were increased during fermentation in all samples. Addition of ascorbic acid inhibited the formation of NDMA significantly. The formation of NDMA was inhibited by 81.3% at the concentration of 130mM as compared with non-added the control group. The aqueous model system was used for the evaluation of ascorbic acid(inhibitor) or thiocyanate (promoter) on the formation of NDMA using salt-fermented anchovy added with sodium nitrite. The optimum pH on the formation of NDMA was shown to be 3.8, and ascorbic acid inhibited the formation of NDMA whereas thiocyanate promoted. NDMA was not detected in the salt-fermented anchovy (control sample). However it is a possibility to form carcinogenic NDMA in stomach if both saltfer-mented anchovy and the materials contained abundant nitrite or nitrate were took in.

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Designing a Subsurface Drainage System: A Trade-Off Between Environmental Sustainability and Agricultural Productivity (유공암거 배수 구성: 환경지속가능성과 농업생산성 사이의 균형)

  • Kim, Kyung-Min;Jeong, Wu-Seong;Bhattarai, Rabin;Jeong, Han-Seok
    • Journal of The Korean Society of Agricultural Engineers
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    • v.64 no.3
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    • pp.53-61
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    • 2022
  • This study evaluated the impacts of subsurface drainage design, i.e., spacing and depth, on agricultural productivity and environmental sustainability in two tile-drained fields (Sites A and E) under a corn-soybean rotation in the Midwestern United States. A calibrated and validated Root Zone Water Quality Model (RZWQM) was used to simulate Nitrate-N (nitrogen) losses to tile drainage and crop yields of 30 tile spacing and depth scenarios over 24 years (1992-2015). Our results presented that the narrower and deeper the tile drains are placed, the greater corn yield and Nitrate-N losses, indicating that the subsurface drainage design may cause a trade-off between agricultural productivity and environmental sustainability. The simulation results also presented that up to about 255.7% and 628.0% increase in Nitrate-N losses in Sites A and E, respectively, far outweigh the rate of increase in corn yield up to about 1.1% and 1.6% from the adjustment of tile spacing and depth. Meanwhile, the crop yield and Nitrate-N losses according to the tile configuration differed depending on the field, and the soybean yield presented inconsistent simulation results, unlike the corn yield, which together demonstrate the heterogeneous characteristic of agro-environmental systems to a subsurface drainage practice. This study demonstrates the applicability of agricultural systems models in exploring agro-environmental responses to subsurface drainage practices, which can help guide the introduction and installation of tile systems into farmlands, e.g., orchards and paddy fields, in our country.

Biodegradation Kinetics of Nonylphenol Ethoxylates by Pseudomonas sp. (Pseudomonas sp.에 의한 Nonylphenol Ethoxylates의 Kinetics)

  • 김수정;이종근;이상준
    • Journal of Environmental Science International
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    • v.2 no.4
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    • pp.271-278
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    • 1993
  • Optimal biodegradation kinetics models to the initial nonylphenol ethoxylates-30 concentration were investigated and had been fitted by the linear regression. Microorganisms capable of degrading nonylphenol ethoxylates-30 were isolated from sewage near Ulsan plant area by enrichment culture technique. Among them, the strain designated as EL-10K had the highest biodegradability and was identified as Pseudomonas from results of taxonomical studies. The optimal conditions for the biodegradation were 1.0 g/ι of nonylphenol ethoxylates-30 and 0.02 g/ι of ammonium nitrate at pH 7.0 and 3$0^{\circ}C$. The highest degradation rate of nonylphenol ethoxylates-30 was about 89% for 30 hours incubation on the optimal condition. Biodegradation data were fit by linear regression to equations for 3 kinetic models. The kinetics of biodegradation of nonylphenol ethoxylates was best described by first order model for 0.1 $\mu\textrm{g}$/ι nonylphenol ethoxylates-30 ; by Monod no growth model and Monod with growth model for 0.5 $\mu\textrm{g}$/mι and 1.0, 5.0 $\mu\textrm{g}$/mι, respectively.

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Source Apportionment of Fine Particle $PM_{2.5}$ in Beijing, China

  • Zhang, Yuanhang;Zhu, Xianlei;Zeng, Limin;Wang, Wei
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2003.11a
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    • pp.216-225
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    • 2003
  • Fine particles with aerodynamic diameter less than 2.5 ${\mu}m$ (PM2.5) were collected from three sites in Beijing during April, August, and November 2000 and January 2001. After chemical components in samples are analyzed, a chemical mass balance (CMB) receptor model using PARs as tracers is applied to quantify the source contributions to PM2.5 in Beijing. The results show that the major sources are coal combustion, fugitive dust, vehicle exhaust, secondary sulfate and nitrate, and organic matter while biomass burning and construction dust contribute only a small fraction. In addition, source inventory in Beijing is used to determine the primary source contributions. The two methods result in comparable results. Source apportionment at three sampling sites presents similar contributions to PM2.5 although the sites are far away from each other. However, distinct seasonal pattern is presented for the source contributions from coal combustion, fugitive dust, biomass burning, secondary sulfate and nitrate.

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