• Bulletin of the Korean Chemical Society
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• 제32권2호
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• pp.510-514
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• 2011

Photodissociation dynamics of allyl alcohol ($H_2C$=CH-$CH_2OH$) has been investigated at 205 - 213 nm along the UV absorption band by measuring rotationally-resolved laser-induced fluorescence spectra of OH radicals. Observed energy partitioning of the available energy among products at all photon energies investigated was similar and the barrier energy for OH production is about 574.7 kJ/mol from the OH yield measurements. The potential energy surfaces for the $S_0$, $T_1$, and $S_1$ excited states along the dissociation coordinate were obtained by ab initio quantum chemical calculations. The observed energy partitioning was successfully modeled by the "barrier-impulsive model" with the reverse barrier and the geometry obtained by the calculated potential energy surfaces. The dissociation takes place on the $T_1$ excited state potential energy surface with an energy barrier in the exit channel and a large portion of the photon energy is distributed in the internal degrees of freedom of the polyatomic products.

• 한국전산구조공학회논문집
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• 제36권6호
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• pp.371-380
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• 2023

지진취약도를 산정하기 위해서는 목표 부지의 특성을 제대로 표현할 수 있는 입력 지진파의 산정이 중요하다. 본 논문에서는 국내외 강진 및 중‧약진 지역에서의 입력 지진파에 대한 단자유도 모델의 지진취약도를 분석하였다. 분석을 위한 첫 번째 단계로, 국외 강진 기록 중 근/원거리에서 측정한 2개의 입력 지진파 세트와 국내 중·약진 지역 특성에 적합한 입력 지진파 2개의 세트, 총 4개의 입력 지진파 세트를 선정하였다. 대상 구조물로는 3가지 고유주기에 대한 비선형 단자유도 모델을 적용하였고, 취약도 분석을 위해 증분동적해석을 이용하였다. 또한, 4가지 손상 상태를 정의하고, 손상 상태 각각에 대해 4가지 입력 지진파 세트의 고유주기별 지진취약도 결과를 제시하였다.

• 한국의류산업학회지
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• 제12권1호
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• pp.21-30
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• 2010

The purpose of this study is to research the symbolistic values of western beards' style in the twentieth century. Namely, it is to consider the relationship between social-cultural factors and aesthetic meanings of western beards' style. The contents are, firstly, studying the conception and the types of beard. A beard is the hair that grows on a person's chin, cheeks, neck, and the area above the upper lip. At the World Beard & Moustache Championships, there are moustache category (natural, english, hungarian, dali, fu manchu, freestyle), beard category (natural, musketeer, goatee, sideburns, freestyle), and full beard category (natural, garibaldi, verdi, van dyck, freestyle), Secondly, this paper is continued by researching the history of beard from the ancient to the present day, and thirdly, analyzing political dictatorship, social resistance and expression of personality, religious dignity, related with the change of world situation, the formation of postmodern anti-culture and pop-culture, and the coexistence of traditional culture. There are long and bushy full beards in some religions like Hinduism, Judaism and Islam. The meanings of their beards are purity, life and holiness. The beards of some politicians symbolize dictatorship. Namely, the chaplin of Hitler, the moustache of Hussein and the musketeer of Castro express strong power and charisma. In 1950s'-70s' subcultures, Hipsters' goatee, Bikers' horseshoe, Beat generations' goatee and Hippies' natural represent the lack of adaptability and social resistance. Also, the celebrities and artists like Ronald Colman, Clark Gable, Don Johnson, George Clooney, and Salvador Dali express freedom, personality, and taste with beards. For that matter, the symbolistic values of beards' style in the twentieth century are the religious dignity, the political dictatorship, the social resistance and the expression of personality. Today the beards' style is one of fashion items as well as a symbol of masculinity, customs and classes.

• Bulletin of the Korean Chemical Society
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• 제14권6호
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• pp.713-717
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• 1993

The crystal structure of the potassium salt of penicillin V has been studied by the X-ray crystallographic methods. Crystal data are as follows; potassium 3,3-dimethyl-7-oxo-6-phenoxyacetoamido-4-thia-1- azabicyclo[3.2.0]-heptane-2${\alpha}$-carboxylate, $K^+{\cdot}C_{16}H_{18}N_2O_5S^-$, $M_r$= 388.5, triclinic, Pl, a= 9.371 (1), b= 12.497 (2), c= 15.313 (2) ${\AA},\;{\alpha}= 93.74\;(2),\;{\beta}=99.32\;(1),\;{\gamma}=90.17\;(1)^{\circ},\;V=1765.7\;(2)\;{\AA}^3$, Z=4, $D_m=1.461\;gcm^{-1},\;{\lambda}(Cu\;K{\alpha})=1.5418\;{\AA},\;{\mu}=40.1\;cm^{-1}$, F(000)=808, T=296 K. The structure was solved by the heavy atom and difference Fourier methods with intensity data measured on an automated four-circle diffractometer. The structure was refined by the full-matrix least-squares method to a final R= 0.081 for 3563 observed $[I_0{\geq}2{\sigam}(I_0)]$ reflections. The four independent molecules assume different overall conformations with systematically different orientations of the phenyl groups although the penam moieties have the same closed conformations. There are intramolecular hydrogen bonds between the exocyclic amide nitrogen and phenoxy oxygen atoms. The penam moiety is conformationally very restricted although the carboxyl and exocyclic amide groups apparently have certain rotational degrees of freedom but the phenyl group is flexible about the ether bond despite the presence of the intramolecular N-H${\cdots}$O hydrogen bond. There are complicated pseudo symmetric relationships in the crystal lattice. The penam moieties are related by pseudo 20.5 screw axes and the phenyl groups by pseudo centers of symmetry. The potassium ions, related by both pseudo symmetries, form an infinite zigzag planar chain parallel to the b axis. Each potassium ion is coordinated to seven oxygen atoms in a severely distorted pentagonal bipyramid configuration, forming the infinite hydrophilic channels which in turn form the molecular stacks. Between these stacks, there are only lipophilic interactions involving the phenyl groups.

• Steel and Composite Structures
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• 제30권1호
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• pp.31-46
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• 2019

In the present study, the various dynamic properties of MWCNT embedded fiber reinforced polymer uniform and tapered composite (MWCNT-FRP) plates are investigated. Various configurations of a tapered composite plate with ply-drop off and uniform composite plate have been considered for the development of the finite element formulation and experimental investigations. First order shear deformation theory (FSDT) has been used to derive the kinetic and potential energy equations of the hybrid composite plates by including the effect of rotary inertia, shear deformation and non-uniformity in thickness of the plate. The governing equations of motion of FRP composite plates without and with MWCNT reinforcement are derived by considering a nine- node rectangular element with five degrees of freedom (DOF) at each node. The effectiveness of the developed finite element formulation has been demonstrated by comparing the natural frequencies and damping ratio of FRP composite plates without and with MWCNT reinforcement obtained experimentally. Various parametric studies are also performed to study the effect of CNT volume fraction and CNT aspect ratio of the composite plate on the natural frequencies of different configurations of CNT reinforced hybrid composite plates. Further the forced vibration analysis is performed to compare the dynamic response of the various configurations of MWCNT-GFRP composite plate with GFRP composite plate under harmonic excitations. It was observed that the fundamental natural frequency and damping ratio of the GFRP composite plate increase approximately 8% and 37% respectively with 0.5wt% reinforcement of MWCNT under CFCF boundary condition. The natural frequencies of MWCNT-GFRP hybrid composite plates tend to decrease with the increase of MWCNT volume fraction beyond 2% due to agglomeration of CNT's. It is also observed that the aspect ratio of the CNT has negligible effect on the improvement of dynamics properties due to randomly orientation of CNT's.

• 한국가스학회지
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• 제18권1호
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• pp.68-74
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• 2014

본 연구에서는 헬멧의 충격응답을 분석하기 위한 단순진동모델을 제시하였다. 실제 헬멧 설계 및 검증과정에서 사용하는 데이터에 기반을 두고 단자유도 진동모델을 채택하였다. 충격에 의한 과도진동응답을 산출하여, 헬멧의 감쇠, 고유진동수, 충돌속도와 같은 인자들이 헬멧의 충격응답에 미치는 영향을 고찰하였다. 최대 G-가속도는 감쇠가 증가함에 따라 감소하였고, 감쇠비가 0.6 이상이 되면 최대 가속도의 값은 변화가 없었다. 고유진동수와 충돌속도에 관하여는 선형적으로 증가하였다. 두부 상해기준(Head Injury Criterion, HIC) 과 최대가속도의 관계도 제시하였다. 본 연구에서의 해석모델이 고품질 경량화 헬멧의 설계과정에서 경제성 제고에 활용될 수 있기를 기대한다.

• 한국소음진동공학회:학술대회논문집
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• 한국소음진동공학회 1994년도 추계학술대회논문집; 한국종합전시장, 18 Nov. 1994
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• pp.35-39
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• 1994

One of the important characteristics of the response of nonlinear systems is the existence of subharmonic resonances. When some conditions in parameter space are satisfied. It is possible even in the presence of damping for a periodically excited nonlinear system to possess a response which is the combination of a contribution at the excitation frequency and a component at the system natural frequency. The system natural frequency being a submultiple of the excitation frequency implies that the resulting response is a subharmonic oscillation. In general, there also co-exists, for the system, a response at the excitation frequency, and initial conditions determine which of the steady-state responses is achieved in an experiment or a numerical simulation. In single-degree-of-freedom systems with harmonic excitation, depending on the type of the nonlinearity, e.g., cubic or quadratic the frequency of subharmonic response is respectively, one-third or one-half of that of the excitation frequency. Although subharmonic resonance is one of the principal characteristics of a nonlinear system the subharmonic responses of structures in the presence of internal resonances have been studied very rarely. In this work, we consider subharmonic responses in the two-mode approximation of the plate equations. It is assumed that the two modes are in one-to-one internal resonance. Constant and periodic steady-state solutions of the averaged equations are studied. Finally, the results of direct time integration of the original equations of motion are presented and compared with those obtained from the averaged equations.

• 한국해양공학회지
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• 제23권5호
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• pp.1-8
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• 2009

This paper is a continuation of the recent development on Hermite-based divergence free element method and deals with a non-isothermal fluid flow thru the buoyancy driven flow in a square enclosure with temperature difference across the two sides. The basis functions for the velocity field consist of the Hermite function and its curl while the basis functions for the temperature field consists of the Hermite function and its gradients. Hence, the number of degrees of freedom at a node becomes 6, which are the stream function, two velocities, the temperature and its x and y derivatives. This paper presents numerical results for Ra = 105, and compares with those from a stabilized finite element method developed by Illinca et al. (2000). The comparison has been done on 32 by 32 uniform elements and the degree of approximation of elements used for the stabilized finite element are linear (Deg. 1) and quadratic (Deg. 2). The numerical results from both methods show well agreements with those of De vahl Davi (1983).

• 한국의상디자인학회지
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• 제7권1호
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• pp.77-84
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• 2005

The purpose of this study is to know on the changes characteristics of eye brow forms of the wester women. A facial image which people recognize contents on changes of image according to various eye brow changes on the face. Various changes of image were seen by length, angle and thickness of eye brow types. The ancient Egyptians used antimony powder to blacken their brows huge black lines. In medieval times, women shaved both their eye brows and their hairlines to give a pure look. The early nineteenth century, brows were untweezed and natural. In the 1920s, when women started paying attention to their faces and their freedom, brows were tweezed, narrowed. In the 1930s, the idealized faces of Jean Harlow, Marlene Dietrich and Greta Garbo - narrow tracery of drawn on brows. The eyebrows is filled various shape of the 1950s. In the 1970s, the Disco Decade of Dreadful tastes, women were at their tweezers again, manicuring their brows. Brooke Shields's natural-looking brow would be an example of the 1980s. In the 1990s, the eyebrow designed by superstar makeup artists who determined the look of fashion model and screen star.

• 대한화학회지
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• 제22권6호
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• pp.380-385
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• 1978

진공미량저울을 사용하여 Spheron 6 위에서 o-크실렌의 여러 온도에서의 흡착등온곡선을 얻고 이들로 부터 BET 방법을 써서 흡착분자 단면적을 구하였다. 이 단면적의 값은 $-15^{\circ}C$까지에서는 변화가 없었고 -15와 $-14^{\circ}C$ 사이에서 갑자기 변하여 $-14^{\circ}C$ 이상의 온도에서는 다시 일정한 값을 유지하였다. 이 결과는 $-15^{\circ}C$ 보다 낮은 온도에서는 촘촘히 쌓인 편재흡착이 일어나고 $-14^{\circ}C$ 이상의 온도에서는 벤젠고리를 중심으로한 하나의 회전자유도를 얻는 것으로 생각된다.