• Title/Summary/Keyword: nanocomposite materials

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Airtightness performance evaluation of ultra-high performance concrete using polymer coating materials (그래핀을 활용한 폴리머 도막재료의 물리적 특성 평가)

  • Lee, Hyun Seung;Kim, Kang Min;Yoon, Seob;Seo, Tae Suk
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.11a
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    • pp.257-258
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    • 2023
  • In this study, it was conducted to improve the physical properties of VAE polymer matrix used as a coating material. A nanocomposite was manufactured using graphene as a reinforcing agent based on a VAE matrix. As a result, improvements in tensile strength, adhesion strength, and porosity were confirmed.

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Computational analysis of molecular dynamics results in a fuzzy stability system

  • C.C. Hung;T. Nguyen;C.Y. Hsieh
    • Advances in Computational Design
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    • v.9 no.1
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    • pp.53-71
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    • 2024
  • Owing to these mechanical properties, carbon nanotubes have the potential to be employed in many future devices and nanostructured materials. As an example, high Young modulus accompanied by their low density, makes them a good choice for reinforcing material in composites. Therefore, we empathize and manually derive the results which shows the utilized lemma and criterion are believed effective and efficient for aircraft structural analysis of composite and nonlinear scenarios. To be fair, the experiment by numerical computation and calculations were explained the perfectness of the methodology we provided in the research.

Effect of Ambient Temperature on Insulation Lifetime of Inverter Surge Resistant Enameled Wire Prepared with Organic/Inorganic Hybrid Nanocomposite

  • Park, Jae-Jun
    • Transactions on Electrical and Electronic Materials
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    • v.17 no.3
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    • pp.163-167
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    • 2016
  • Inverter surge resistant enameled wire was prepared with an organic/inorganic hybrid nanocomposite, and the effect of ambient temperature on the insulation lifetime of the enameled wire in the form of twisted pair was studied by a withstanding voltage tester. The organic polymer was Polyesterimide-polyamideimide (EI/AI) and the inorganic material was a Nano-sized silica (average particle size : 15 nm). The enamel thickness was 50 μm and the ambient temperature was 100, 150, 200, and 250, respectively. Transmission electron microscopy (TEM) observation showed that Nano-sized Silica were evenly dispersed in EI/AI. There were many air gaps in a twisted pair, therefore, when voltage was applied to the twisted pair, enamel erosion took place in the air gap area because of partial discharge accordi, ng to Paschen’s law. As ambient temperature increased, insulation lifetime decreased according to Arrhenius relationship, which was explained by the increasing mobility of polymer chains in EI or AI. And insulation breakdown voltage value at 10 kHz was 1,864.5 sec (31.1 min), which is 1.9 times higher than at 20 kHz, 981.6 sec (16.4 min).

Fabrication of Carbon Microcapsules Containing Silicon Nanoparticles-Carbon Nanotubes Nanocomposite for Anode in Lithium Ion Battery

  • Bae, Joon-Won;Park, Jong-Nam
    • Bulletin of the Korean Chemical Society
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    • v.33 no.9
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    • pp.3025-3032
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    • 2012
  • Carbon microcapsules containing silicon nanoparticles (Si NPs)-carbon nanotubes (CNTs) nanocomposite (Si-CNT@C) have been fabricated by a two step polymerization method. Silicon nanoparticles-carbon nanotubes (Si-CNT) nanohybrids were prepared with a wet-type beadsmill method. A polymer, which is easily removable by a thermal treatment (intermediate polymer) was polymerized on the outer surfaces of Si-CNT nanocomposites. Subsequently, another polymer, which can be carbonized by thermal heating (carbon precursor polymer) was incorporated onto the surfaces of pre-existing polymer layer. In this way, polymer precursor spheres containing Si-CNT nanohybrids were produced using a two step polymerization. The intermediate polymer must disappear during carbonization resulting in the formation of an internal free space. The carbon precursor polymer should transform to carbon shell to encapsulate remaining Si-CNT nanocomposites. Therefore, hollow carbon microcapsules containing Si-CNT nanocomposites could be obtained (Si-CNT@C). The successful fabrication was confirmed by scanning electron microscopy (SEM) and X-ray diffraction (XRD). These final materials were employed for anode performance improvement in lithium ion battery. The cyclic performances of these Si-CNT@C microcapsules were measured with a lithium battery half cell tests.

Effect of Reactive Diluents on the AC Electrical Treeing in Epoxy/Nanosilicate Systems

  • Park, Jae-Jun
    • Transactions on Electrical and Electronic Materials
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    • v.15 no.2
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    • pp.77-80
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    • 2014
  • The effect of reactive diluents on the ac electrical treeing in epoxy/nanosilicate systems was studied, in a needle-plate electrode geometry. Diglycidyl ether of bisphenol A (DGEBA) type epoxy was used as a base resin, and layered silicate was used as a nano-sized filler. Polyglycol (PG) or 1,4-butanediol diglycidyl ether (BDGE) was introduced as a reactive diluent to the DGEBA/nanosilicate system, in order to decrease the viscosity of the nanocomposite system. PG acted as a flexibilizer, and BDGE acted as a chain extender, after the curing reaction. To measure the treeing propagation rate, a constant alternating current (ac) of 10 kV/4.2 mm (60 Hz) was applied to the specimen, in a needle-plate electrode arrangement, at $30^{\circ}C$ of insulating oil bath. When 10 kV/4.2 mm (60 Hz) was applied, the treeing propagate rate in the DGEBA system was $1.10{\times}10^{-3}$ mm/min, and that in the DGEBA/PG system was $1.05{\times}10^{-3}$ mm/min. As 1.5 wt% of nanosilicate was added to the DGEGA/PG system, the propagation rate was $0.33{\times}10^{-3}$ mm/min. This meant that the nano-sized layered silicates would act as good barriers to treeing propagation. The effect of chlorine content was also studied, and it was found that chlorine had a bad effect on the electrical insulation property of the epoxy system.

Large deformation analysis for functionally graded carbon nanotube-reinforced composite plates using an efficient and simple refined theory

  • Bakhti, K.;Kaci, A.;Bousahla, A.A.;Houari, M.S.A.;Tounsi, A.;Adda Bedia, E.A.
    • Steel and Composite Structures
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    • v.14 no.4
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    • pp.335-347
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    • 2013
  • In this paper, the nonlinear cylindrical bending behavior of functionally graded nanocomposite plates reinforced by single-walled carbon nanotubes (SWCNTs) is studied using an efficient and simple refined theory. This theory is based on assumption that the in-plane and transverse displacements consist of bending and shear components in which the bending components do not contribute toward shear forces and, likewise, the shear components do not contribute toward bending moments. The material properties of SWCNTs are assumed to be temperature-dependent and are obtained from molecular dynamics simulations. The material properties of functionally graded carbon nanotube-reinforced composites (FG-CNTCRs) are assumed to be graded in the thickness direction, and are estimated through a micromechanical model. The fundamental equations for functionally graded nanocomposite plates are obtained using the Von-Karman theory for large deflections and the solution is obtained by minimization of the total potential energy. The numerical illustrations concern the nonlinear bending response of FG-CNTRC plates under different sets of thermal environmental conditions, from which results for uniformly distributed CNTRC plates are obtained as comparators.

Temperature-dependent nonlocal nonlinear buckling analysis of functionally graded SWCNT-reinforced microplates embedded in an orthotropic elastomeric medium

  • Barzoki, Ali Akbar Mosallaie;Loghman, Abbas;Arani, Ali Ghorbanpour
    • Structural Engineering and Mechanics
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    • v.53 no.3
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    • pp.497-517
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    • 2015
  • In this study, nonlocal nonlinear buckling analysis of embedded polymeric temperature-dependent microplates resting on an elastic matrix as orthotropic temperature-dependent elastomeric medium is investigated. The microplate is reinforced by single-walled carbon nanotubes (SWCNTs) in which the equivalent material properties nanocomposite are estimated based on the rule of mixture. For the carbon-nanotube reinforced composite (CNTRC) plate, both cases of uniform distribution (UD) and functionally graded (FG) distribution patterns of SWCNT reinforcements are considered. The small size effects of microplate are considered based on Eringen's nonlocal theory. Based on orthotropic Mindlin plate theory along with von K$\acute{a}$rm$\acute{a}$n geometric nonlinearity and Hamilton's principle, the governing equations are derived. Generalized differential quadrature method (GDQM) is applied for obtaining the buckling load of system. The effects of different parameters such as nonlocal parameters, volume fractions of SWCNTs, distribution type of SWCNTs in polymer, elastomeric medium, aspect ratio, boundary condition, orientation of foundation orthtotropy direction and temperature are considered on the nonlinear buckling of the microplate. Results indicate that CNT distribution close to top and bottom are more efficient than those distributed nearby the mid-plane for increasing the buckling load.

Insulation Breakdown Characteristics of Inverter Surge Resistant Enameled Wire Prepared with Organic/Inorganic Hybrid Nanocomposite

  • Park, Jae-Jun;Shin, Seong-Sik;Lee, Jae-Young;Han, Se-Won;Kang, Dong-Pil
    • Transactions on Electrical and Electronic Materials
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    • v.16 no.4
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    • pp.190-193
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    • 2015
  • Insulation breakdown characteristics of an inverter surge resistant enameled wire were investigated in a twisted pair prepared with organic/inorganic hybrid nanocomposite. Organic polymer was polyesterimide-polyamideimide (EI/AI) and inorganic material was a nano-sized silica. The enamel thickness was 50 μm and the diameters of enameled copper wires were 0.75, 1.024, and 1.09 mm, respectively. There were many air gaps in a twisted pair. Therefore, when the voltage was applied to the twisted pair, enamel erosion took place in the air gap area because of partial discharge according to Paschen’s law. The insulation lifetime of the hybrid wire (HW) was 41,750 sec, which was 515.4 times more than the 81 sec of EI/AIW. In addition, the shape parameter of HW was 2.58, which was 3.4 times higher than 0.75 of EI/AIW.