• Economic and Environmental Geology
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• v.42 no.5
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• pp.501-507
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• 2009

Ordered single-walled hollow aluminogermanate (ALGE) nano-balls(NBs) and nano-tubes(NTs) have been self-assembled from the ALGE precursors having an Al/Ge ratio of 1.33 using simple pH-control. The hollow ALGE NBs with average monodisperse diameters of 5 nm and chemistry of Al/Ge=1.5~1.6 were formed through structural assembly in the ALGE solution (Al/Ge=1.33) highly basified to pH=13(Na/Al=28~30) and followed by immediate acidification to pH=9. When the basified solution(pH=13) were acidified to pH=4, ALGE S-NTs (Short-fiber nano-tubes) with diameters of 3.3 nm, 15~20 nm in length, and chemistry of Al/Ge=2.6~2.8 were successfully synthesized. Whereas the solution was basified to pH=9, and subsequently acidified to pH=4, L-NTs(Long-fiber nano-tubes) with >100 nm in length were synthesized for the first time. The self-assembly of the hollow NBs, S-NTs, and L-NTs form the ALGE precursors can be explained by the degree of $H^+$-dissociation of the -Ge-OH inner surfaces, which was controlled by amount of $Na^+$ and pH conditions of ALGE precursor solutions. This results indicate that target forms of ALGE nanomaterials can be synthesized by simple pH controls.

• Bulletin of the Korean Chemical Society
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• v.29 no.2
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• pp.389-392
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• 2008

High purity carbon nano fibers/tubes (CNF/Ts) which contain 97% pure graphitic carbon are prepared by a new catalytic method. These carbon nano fibers/tubes are ready to use without any further purification. The striking feature of this method is the production of carbon nano fibers/tubes of narrow distribution range. The developed catalytic method also produces pure hydrogen. An additional advantage of this catalytic method is that catalyst can be reused without reactivation. Ni:Cu catalyst system is embodied into SCHOTT-DURAN filter disc of large pore size (40-100 mm). Due to the production of hydrogen in the reaction catalyst stability is enhanced and deactivation process is considerably slowed down.

• Carbon letters
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• v.8 no.3
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• pp.184-190
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• 2007

Carbon Nano Tubes could be either metallic or semi-conducting in nature, depending on their diameter. Its photocatalytic behavior has given an impetus to use it as an anti-microbial agent. More than 95% Escherichia coli and Staphylococcus aureus bacteria got killed when exposed to Carbon Nano Tubes for 30 minutes in presence of sunlight. Carbon Nano Tubes are supposed to have smooth surface on to which it accumulates positive charges when exposed to light. The surface that is non illuminated has negative charge. At the cellular level microorganisms produce negative charges on the cell membrane, Therefore damaging effect of multi walled carbon nano tubes (exposed to light) on the microorganisms is possible. In this paper, photo catalytic killing of microbes by multi walled carbon nano tubes is reported. Killing was due to damage in the cell membrane, as seen in SEM micrographs. Moreover biochemical analysis of membrane as well as total cellular proteins by SDS PAGE showed that there was denaturation of membrane proteins as well as total proteins of both the microbes studied. The killed microbes that showed a decrease in number of protein bands (i.e. due to breaking down of proteins) also showed an increase in level of free amino acids in microbes. This further confirmed that proteins got denatured or broken down into shorter units of amino acids. Increased level of free amino acids was recorded in both the microbes treated with multi walled carbon nano tubes and sunlight.

• 한국신재생에너지학회:학술대회논문집
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• 2009.11a
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• pp.549-552
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• 2009

Methane hydrate is crystalline ice-like compounds which formed methane gas enters within water molecules composed cavity at specially temperature and pressure condition, and water molecule and each other from physically-bond. $1m^3$ hydrate of pure methane can be decomposed to the maximum of $172m^3$ at standard condition. If these characteristics of hydrate are reversely utilized, natural gas is fixed into water in the form of hydrate solid. Therefore the hydrate is considered to be a great way to transport and store natural gas in large quantity. Especially the transportation cost is known to be 18~24% less than the liquefied transportation. However, when methane hydrate is formed artificially, the amount of consumed gas is relatively low due to a slow reaction rate between water and methane gas. In this study, for the better hydrate reaction rate, there is make nano fluid using ultrasonic dispersion of carbon nano tube. and then, Experiment with hydrate formation by nano fluid and methane gas reaction. The results show that when the carbon nano tubes of 0.004 wt% was added to pure water, the amount of consumed gas was about 300% higher than that in pure water and the hydrate formation time decreased.

• Steel and Composite Structures
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• v.33 no.5
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• pp.653-661
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• 2019

In this paper aeroelastic behavior of 3-phase nano-composite beam-plate with double delaminations is investigated. It is tried to study the effect of carbon nano-tubes (CNTs) on critical flutter pressure of reinforced damaged nano-composite structures. In this case, the CNTs are appending to the polymer matrix uniformly. The Eshelby-Mori-Tanaka model is used to obtain the effective material properties of 3-phase nano-composite beam-plate. To investigate the aeroelastic behavior of delaminated beam-plate subjected to supersonic flow, it is assumed that the damaged segments are forced to vibrate together. The boundary conditions and auxiliary conditions at edges of delaminated segments are used to predict critical flutter pressure. The influence of CNTs and different delamination parameters such as delamination length, axial position and its position through thickness are investigated on critical flutter pressure.

• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 2006.09b
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• pp.1211-1212
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• 2006

The electrophoretic deposition process of Ni nano-particles was employed for self-repairing of heat exchanger tubes. For electrophoretic deposition of Ni nano-particles on pitted Ni alloy specimen, a constant electric field of 100 V $cm^{-1}$ was applied to the specimen for 180 s in Ni-dispersed solution. It was found that as electrophoretic deposition proceeded, the size of the pit remarkably decreased due to the agglomeration of Ni nano-particles at the pit. This strongly suggests that the electrophoretic mobility of the charged particles is larger for the pit with a higher current value rather than outer surfaces with a lower current value.

• Structural Engineering and Mechanics
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• v.68 no.2
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• pp.203-213
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• 2018

This paper presents a study of geometric nonlinear forced vibration of carbon nano-tubes (CNTs) reinforcement composite plates on nonlinear elastic foundations. The plate is bonded with piezoelectric layers. The von Karman geometric nonlinearity assumptions with classical plate theory are employed to obtain the governing equations. The Galerkin and homotopy perturbation method (HPM) are utilized to investigate the effect of carbon nano-tubes volume fractions, large amplitude vibrations, elastic foundation parameters, piezoelectric applied voltage on frequency ratio and primary resonance. The results indicate that the carbon nano-tube volume fraction, applied voltage and elastic foundation parameters have significant effect on the hardening response of carbon nanotubes reinforced composite (CNTRC) plates.

• Korean Chemical Engineering Research
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• v.55 no.6
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• pp.771-777
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• 2017

Adsorption characteristics of Eosin Y dye by carbon nano tubes (CNTs) were examined through batch experiments. CNTs used in the study had specific surface area of $106.9m^2/g$, porosity volume of $1.806cm^3/g$, and porosity diameter of $163.2{\AA}$, respectively. Adsorption experiments were carried out as function of contact time, initial solution pH (2~10), dye concentration (100, 150 and 200 mg/L), adsorbent dose (0.05~1.0 g) and temperature (293, 313 and 333 K). The adsorption was favoured at lower pHs and temperatures. Adsorption data were well described by the Langmuir model. The adsorption process followed the pseudo-second order kinetic model. The adsorption capacity decreased with increase in temperature. The results of the intraparticle diffusion model suggested that film diffusion and particle diffusion were simultaneously occured during the adsorption process. Thermodynamic studies suggested the spontaneous and endothermic nature of adsorption of Eosin Y dye onto CNTs.

• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 2003.10a
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• pp.95-96
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• 2003

Titanium carbide nano-tube and fibers were synthesized by self-propagating high temperature synthesis (SHS) method. The average diameters of the nano-tubes and nano-fibers are about 100 and 20 nm in diameter, respectively. the non-stoichiometric numbers of the titanium carbide determined by neutron diffractometry were 0.87 and 0.94.

• Journal of the Korean Society for Precision Engineering
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• v.22 no.9 s.174
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• pp.49-59
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• 2005

This paper describes a development of the extrusion process and estimation of the weldability for multi cell tubes used to cooling system of automobiles. A study on extrusion process is performed through the 3D FE simulation in non-steady state and extrusion experimentation. Also, nano-indentation test is employed to estimate the weldability of tubes. Especially, An evaluation of the weldability using the nano-indentation is accomplished as compared with nano-hardness in welded part and in the others. Finally, the pattern of the mandrel defection is investigated according to shapes of the porthole and/or chamber.