• Advances in nano research
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• v.12 no.1
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• pp.49-63
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• 2022

Nanocatalysts are usually used in the synthesis of petrochemical products, fine chemicals, biofuel production, and automotive exhaust catalysis. Due to high activity and stability, recyclability, and cost-effectiveness, nanocatalysts are a key area in green chemistry. On the other hand, water as a common by-product or undesired element in a range of nanocatalyzed processes may be promoting the deactivation of catalytic systems. The advancement in the field of hydrophobicity in nanocatalysis could relatively solves these problems and improves the efficiency and recyclability of nanocatalysts. Some recent developments in the synthesis of novel nanocatalysts with tunable hydrophilic-hydrophobic character have been reviewed in this article and followed by highlighting their use in catalyzing several processes such as glycerolysis, Fenton, oxidation, reduction, ketalization, and hydrodesulfurization. Zeolites, carbon materials, modified silicas, surfactant-ligands, and polymers are the basic components in the controlling hydrophobicity of new nanocatalysts. Various characterization methods such as N2 adsorption-desorption, scanning and transmission electron microscopy, and contact angle measurement are critical in the understanding of hydrophobicity of materials. Also, in this review, it has been shown that how the hydrophobicity of nanocatalyst is affected by its structure, textural properties, and surface acidity, and discuss the important factors in designing catalysts with high efficiency and recyclability. It is useful for chemists and chemical engineers who are concerned with designing novel types of nanocatalysts with high activity and recyclability for environmentally friendly applications.

• Advances in nano research
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• v.15 no.2
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• pp.113-128
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• 2023

The advancement of theoretical research has numerous challenges, particularly with regard to the modeling of structures, in contrast to experimental investigation of the mechanical behavior of complex systems. The main objective of this investigation is to provide an analytical analysis of the static problem of a new generation of composite structure, namely, functionally graded FG graphene reinforced composite GRC coated plates/shells. A complex power law function is used to define the material's graduation. Investigations are conducted on Hardcore and Softcore coated FG plates/shells. The virtual work approach is used to perform the equilibrium equations, which are then solved using the Galerkin technique to account for various boundary conditions. With reliable published articles, the presented solution is validated. The effects of hardcore and softcore distributions, gradation indexes, and boundary conditions on the buckling, bending deflection and stresses of FG GRC-coated shells are presented in detail. Obtained results and the developed procedure are supportive for design and manufacturing of FG-GRC coated plates/shells in several fields and industries e.g., aerospace, automotive, marine, and biomedical implants.

• Advances in nano research
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• v.14 no.2
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• pp.127-139
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• 2023

This paper studies the free vibration behavior of bi-dimensional functionally graded (BFG) nanobeams subjected to arbitrary boundary conditions. According to Eringen's nonlocal theory and Hamilton's principle, the underlying equations of motion have been obtained for BFG nanobeams. Moreover, the variable substitution method is utilized to establish the structure's state-space differential equations, followed by forming the dynamic stiffness matrix based on state-space differential equations. In order to compute the natural frequencies, the current study utilizes the Wittrick-Williams algorithm as a solution technique. Moreover, the nonlinear vibration frequencies calculated by employing the proposed method are compared to the frequencies obtained in previous studies to evaluate the proposed method's performance. Some illustrative numerical examples are also given in order to study the impacts of the nonlocal parameters, material property gradient indices, nanobeam length, and boundary conditions on the BFG nanobeam's frequency. It is found that reducing the nonlocal parameter will usually result in increased vibration frequencies.

• Journal of the Semiconductor & Display Technology
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• v.21 no.4
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• pp.1-5
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• 2022

We presented a micro hemi-sphere structure flexible film to improve the external quantum efficiency (EQE) in OLEDs. The micro hemi-sphere flexible film was fabricated with breath figure (BF) method and replica process. At 45 mg/mL of concentration, the size of the hemi-spheres was approximately 6.2 ㎛ were obtained which are the most circular shape. So, it was possible to yield the best performance with an improvement of 33 % in the EQE and the widest viewing angle ranging from 0° to 70°. As a result, the hemi-sphere film's size and distribution seem to play important roles in enhancing the EQE in OLEDs. Furthermore, the flexible hemi-sphere film based on polymeric materials could offer an effective, large-scale, mass-produced product and a simple process and approach to achieve high efficiency in flexible OLEDs.

• Advances in nano research
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• v.14 no.6
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• pp.541-555
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• 2023

The extensive use of polymeric matrix composites in the athletic sector may be attributed to its high strength-to-weight ratio, production economy, and a longer lifespan than conventional materials. This study explored the impact of carbon nanotubes on the properties of different composite field sports equipment components. The test specimens were fabricated using the compression molding technique. The insertion of carbon nanotubes increases mechanical properties related to the process parameters to account for an improvement in the stick sections' overall performance. The dynamic response of functionally graded reinforced nanocomposite wire structure is examined in this paper on the bases of high-order hyperbolic beam theory lined to the size-dependent nonclassical nonlocal theory under the external mechanical load due to the physical activities. Finally, the impact of different parameters on the stability of nanocomposite structures is discussed in detail.

• Advances in nano research
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• v.13 no.4
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• pp.351-368
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• 2022

Recently, promising structural technologies like multi-function, ultra-load bearing capacity and tailored structures have been put up for discussions. Finite Element (FE) modelling is probably the best-known option capable of treating these superior properties and multi-domain behavior structures. However, advanced materials such as Functionally Graded Material (FGM) and nanocomposites suffer from problems resulting from variable material properties, reinforcement aggregation and mesh generation. Motivated by these factors, this research proposes a unified shape function for FGM, nanocomposites, graded nanocomposites, in addition to traditional isotropic and orthotropic structural materials. It depends not only on element length but also on the beam's material properties and geometric characteristics. The systematic mathematical theory and FE formulations are based on the Timoshenko beam theory for beam structure. Furthermore, the introduced element achieves C1 degree of continuity. The model is proved to be convergent and free-off shear locking. Moreover, numerical results for static and free vibration analysis support the model accuracy and capabilities by validation with different references. The proposed technique overcomes the issue of continuous properties modelling of these promising materials without discarding older ones. Therefore, introduced benchmark improvements on the FE old concept could be extended to help the development of new software features to confront the rapid progress of structural materials.

• Advances in nano research
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• v.15 no.4
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• pp.329-337
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• 2023

Wearing the right sportswear is one of the essential points in exercising, which is mainly neglected. Sportswear should be suitable for the ambient temperature and not cause more heat or cold in the athlete's body. On the other hand, increased sweating and blood circulation during exercise should not cause fatigue or heatstroke in the athlete. Nanotechnology has grown significantly in the field of producing more efficient equipment in the field of sports. The increase in demand in sports for complete sports equipment has revealed the necessity of using the highest quality materials in this sector. In the world of championship sports, a minor change in equipment can lead to significant changes in causing failure and victory. Since the sole is the most critical part of sports shoes, with the introduction of nanotechnology and nanocomposites, it is possible to help athletes rush and increase their sense of calm and satisfaction. Using nanocomposites in the soles of shoes can improve some of their characteristics, prevent the smell and sweat of shoes, and induce water repellency in these shoes. In this research, titanium dioxide (TiO₂) nanocomposite, along with cellulose, has been used to create antibacterial and hydrophobic properties in the soles of sports shoes. The synthesized nanocomposite has been synthesized using the least amount of chemicals, which shows this method's easy and cost-effective synthesis.

• Journal of the Korean institute of surface engineering
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• v.57 no.2
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• pp.71-85
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• 2024

This article provides an overview of Raman spectroscopy and its practical applications for surface analysis of semiconductor processes including real-time monitoring. Raman spectroscopy is a technique that uses the inelastic scattering of light to provide information on molecular structure and vibrations. Since its inception in 1928, Raman spectroscopy has undergone continuous development, and with the advent of SERS(Surface Enhanced Raman Spectroscopy), TERS(Tip Enhanced Raman Spectroscopy), and confocal Raman spectroscopy, it has proven to be highly advantageous in nano-scale analysis due to its high resolution, high sensitivity, and non-destructive nature. In the field of semiconductor processing, Raman spectroscopy is particularly useful for substrate stress and interface characterization, quality analysis of thin films, elucidation of etching process mechanisms, and detection of residues.

• Advances in nano research
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• v.16 no.1
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• pp.27-40
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• 2024

This work is the first of its kind to integrate Mindlin's theory with analytical methods in order to produce an exact solution to a specific vibration issue as well as a bending problem involving a nanoplate that is supported by a viscoelastic foundation. The plate is exposed to the simultaneous effects of a compressive load in the plate plane and a force operating perpendicular to the plane of the nanoplate. In addition, the flexoelecity effect is included into the plate. The strain gradient component is taken into consideration while calculating the plate equilibrium equation using the nonlocal theory and Hamilton's principle. The free vibration and static responses of the nanoplate seem to be both real and imaginary components because of the appearance of the viscoelastic drag coefficient of the viscoelastic foundation. This study also shows that when analyzing the mechanical response for nanostructure, taking into account the flexoelectricity effect and the influence of the nonlocal parameter, the results will be completely different from the case in which this parameter is ignored. This indicates that it is vital to take into consideration the effects of nonlocal parameters on the nanosheet structure while also taking into consideration the effect of flexoelectricity.

• Corrosion Science and Technology
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• v.23 no.1
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• pp.41-53
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• 2024

Titanium alloy is gaining attention in the medical industry due to its excellent biocompatibility and osteoconductivity. However, the natural oxide film on the titanium surface is insoluble, resulting in inadequate bone adhesion. Therefore, it is necessary to optimize the contact between biological tissues and implant surfaces, and alter the chemical composition and morphological characteristics of the implant surface. In this study, the anodization method was applied to titanium surface treatment to form a uniform and robust oxide film. Subsequently, a chemical process, pore-widening, was employed to change the morphological characteristics of the oxide film. The concentration of the pore-widening solution was varied at 2, 4, 6, and 8 wt% and the process time was set at 30 and 60 minutes. As the concentration of the pore-widening solution increased the pore diameter of the oxide film increased. Notably, at 6 wt% for 60 minutes, the oxide film exhibited a coexistence of pillars and pores. Based on this, it was determined that surface roughness increased with higher concentration and longer process time. Additionally, the presence of pillars and pores structures maximized hydrophilicity. This study provides insights into enhancing the surface properties of titanium for improved performance in medical implants.