• Membrane and Water Treatment
• /
• v.7 no.6
• /
• pp.555-571
• /
• 2016

Heavy metal contamination has attracted considerable attention during recent decades due to the potential risk brought about for human beings and the environment. Several adsorbent materials are utilized for the purification of contaminated water resources among which chitosan is considered as an appropriate alternative. Copper is a heavy metal contaminants found in several industrial wastewaters and its adsorption on porous and macroporous chitosan membranes is investigated in this study. Membranes are prepared by phase inversion and particulate leaching method and their morphology is characterized using SEM analysis. Batch adsorption experiments are performed and it is found that copper adsorption on macroporous chitosan membrane is higher than porous membrane. The iso-steric heat of adsorption was determined by analyzing the variations of temperature to investigate its effect on adsorption characteristics of macroporous chitosan membranes. Furthermore, desorption experiments were studied using NaCl and EDTA as eluants. The mechanism of copper adsorption was also investigated using XPS spectroscopy which confirms simultaneous occurrence of chelation and electrostatic adsorption mechanisms.

• Journal of Surface Science and Engineering
• /
• v.43 no.5
• /
• pp.217-223
• /
• 2010

For an application as templates of high performance with proper pore size and shape, porous anodic alumina films were prepared by anodization in oxalic acid, and formation behaviors of anodic alumina layer as well as dissolution process in acid solution have been investigated. The surface characteristics on anodic alumina layer were shown to be dependent on the fabrication parameters for anodization. For the dissolution behaviors of anodic alumina, the thickness of the barrier-type alumina layer decreased linearly with the rate of 0.98 nm/min in $H_3PO_4$ solution at $30^{\circ}C$. The changes of the anodic alumina layers were analyzed by SEM and TEM.

• Advances in nano research
• /
• v.8 no.2
• /
• pp.149-156
• /
• 2020

The present paper explores forced vibrational properties of porosity-dependent functionally graded (FG) cylindrical nanoshells exposed to linear-type or triangular-type impulse load via classical shell theory (CST) and nonlocal strain gradient theory (NSGT). Employing such scale-dependent theory, two scale factors accounting for stiffness softening and hardening effects are incorporated in modeling of the nanoshell. Two sorts of porosity distributions called even and uneven have been taken into account. Governing equations obtained for porous nanoshell have been solved through inverse Laplace transforms technique to derive dynamical deflections. It is shown that transient responses of a nanoshell are affected by the form and position of impulse loading, amount of porosities, porosities dispensation, nonlocal and strain gradient factors.

• Advances in nano research
• /
• v.5 no.4
• /
• pp.393-414
• /
• 2017

Forced vibration behavior of porous metal foam nanoplates on elastic medium is studied via a 4-variable plate theory. Different porosity distributions called uniform, symmetric and asymmetric are considered. Nonlocal strain gradient theory (NSGT) containing two scale parameters is employed for size-dependent modeling of porous nanoplates. The present plate theory satisfies the shear deformation effect and it has lower field variables compared with first order plate theory. Hamilton's principle is employed to derive the governing equations. Obtained results from Galerkin's method are verified with those provided in the literature. The effects of nonlocal parameter, strain gradient, foundation parameters, dynamic loading, porosity distributions and porosity coefficient on dynamic deflection and resonance frequencies of metal foam nanoscale plates are examined.

• Journal of the Optical Society of Korea
• /
• v.17 no.4
• /
• pp.300-304
• /
• 2013

Novel breakthrough random-hole optical fibers (RHOFs) are fabricated in a draw tower facility, by tapering an optical fiber preform packed with a silica powder mixture capable of producing air holes in situ at the high temperature of tens of hundreds in degrees Celsius. Structural and propagation characteristics of the porous RHOF are explained briefly. Experimental investigations of the invented RHOF are performed for pressure sensor applications. Remarkable results are obtained for the RHOF with desirable pressure sensitivity independent of temperature, as is required for harsh conditions as in oil reservoirs.

• Geomechanics and Engineering
• /
• v.17 no.2
• /
• pp.175-180
• /
• 2019

This research is concerned with post-buckling investigation of nano-scaled beams constructed from porous functionally graded (FG) materials taking into account geometrical imperfection shape. Hence, two types of nanobeams which are perfect and imperfect have been studied. Porous FG materials are classified based on even or uneven porosity distributions. A higher order nonlinear refined beam theory is used in the present research. Both perfect and imperfect nanobeams are formulated based on this refined theory. A detailed study is provided to understand the effects of geometric imperfection, pore distribution, material distribution and small scale effects on buckling of FG nanobeams.

• Advances in nano research
• /
• v.7 no.2
• /
• pp.135-143
• /
• 2019

The important effect of porosity on the mechanical behaviors of a continua makes it necessary to account for such an effect while analyzing a structure. motivated by this fact, a new two-step porosity dependent homogenization scheme is presented in this article to investigate the wave propagation responses of functionally graded (FG) porous nanobeams. In the introduced homogenization method, which is a modified form of the power-law model, the effects of porosity distributions are considered. Based on Hamilton's principle, the Navier equations are developed using the Euler-Bernoulli beam model. Thereafter, the constitutive equations are obtained employing the nonlocal elasticity theory of Eringen. Next, the governing equations are solved in order to reach the wave frequency. Once the validity of presented methodology is proved, a set of parametric studies are adapted to put emphasis on the role of each variant on the wave dispersion behaviors of porous FG nanobeams.

• Korean Journal of Metals and Materials
• /
• v.48 no.4
• /
• pp.326-334
• /
• 2010

Porous and net-shaped tantalum powder for a capacitor was formulated in a SHS (self-propagating high-temperature synthesis) process. However, this powder, which has weak strength among its particles and low flow ability, cannot be used for a capacitor. Therefore, this powder was sintered in a high-vacuum furnace to increase agglomeration to improve the flow ability, bonding strength among the particles, and shrinkage during pellet sintering. Finally, it was deoxidated with 2 wt% Mg powder to remove the increased surface oxygen that arose during the sintering process. The final product was analyzed in terms of its chemical and physical properties and was compared with a commercial powder used by a capacitor manufacturer.

• Advances in materials Research
• /
• v.11 no.4
• /
• pp.279-298
• /
• 2022

In this paper, the important novelty and the defining a physical phenomenon of the resent research is the development of nonlocal stress and strain parameters on the porous sandwich beam with functionally graded materials in the top and bottom face sheets.Also, various beam models including Euler-Bernoulli, Reddy and the generalized formulation of two-variable beam theories are obtained in this research. According to a nonlocal strain elasticity theory, the strain at a reference point in the body is dependent not only on the stress state at that point, but also on the stress state at all of the points throughout the body. Thus, the nonlocal stress-strain elasticity theory is defined that can be actual at micro/nano scales. It can be seen that the critical buckling load and transverse deflection of sandwich beam by considering both nonlocal stress-strain parameters is higher than the nonlocal stress parameter. On the other hands, it is noted that by considering the nonlocal stress-strain parameters simultaneously becomes the actual case.

• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2021.11a
• /
• pp.67-68
• /
• 2021

In this study, Repair mortar was prepared using CNT powder with improved dispersibility and its characteristics were analyzed. As a result of the experiment, the compressive strength and flexural strength were found to be at similar levels compared to Plain without CNT. In addition, as a result of the drying shrinkage test, it was found that the drying shrinkage amount was decreased due to the effect of CNT mixed into the porous material filling the internal pores of the repair mortar.. The Bond strength of the repair mortar was at a similar level regardless of whether CNT was added or not