• Title/Summary/Keyword: nano open

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Novel Fabrication of Platinum Counter Electrode in Dye-sensitized Solar Cells Using Nano-second Pulsed Laser Sintering

  • Lee, Jin Ah;Yoo, Kicheon;Kim, Woong;Ko, Min Jae
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.234-234
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    • 2013
  • The counter electrodes in dye-sensitized solar cells (DSSCs) play roles in not only collecting electrons from external circuit but also reducing I3- to I- in electrolytes. Generally, conventional counter electrodes for DSSCs are prepared from the high temperature treatment of the H2PtCl6 precursor solution at $400^{\circ}C$ However, the more simplified fabrication process of counter electrodes is required for the commercialization of DSSCs. In this work, we developed novel fabrication process of counter electrodes using nano-second pulsed laser. DSSCs employing counter electrodes prepared by laser process showed conversion efficiency of 6.75% with short-circuit current of 12.73 mA/cm2, open-circuit voltage of 0.74 V and fill factor of 0.72. Closer investigating of photovoltaic properties will be reported.

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Methods to Improve Light Harvesting Efficiency in Dye-Sensitized Solar Cells

  • Park, Nam-Gyu
    • Journal of Electrochemical Science and Technology
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    • v.1 no.2
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    • pp.69-74
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    • 2010
  • Methodologies to improve photovoltaic performance of dye-sensitized solar cell (DSSC) are reviewed. DSSC is usually composed of a dye-adsorbed $TiO_2$ photoanode, a tri-iodide/iodide redox electrolyte and a Pt counter electrode. Among the photovoltaic parameters of short-circuit photocurrent density, open-circuit voltage and fill factor, short-circuit photocurrent density is the collective measure of light harvesting, charge separation and charge collection efficiencies. Internal quantum efficiency is known to reach almost 100%, which indicates that charge separation occurs without loss by recombination. Thus, light harvesting efficiency plays an important role in improvement of photocurrent. In this paper, technologies to improve light harvesting efficiency, including surface area improvement by nano-dispersion, size-dependent light scattering efficiency, bi-functional nano material, panchromatic absorption by selective positioning of three different dyes and transparent conductive oxide (TCO)-less DSSC, are introduced.

Synthesis and Characterization of New Macroporous SnO2 Foams

  • Choi, Moon-Hyung;Paek, Seung-Min
    • Bulletin of the Korean Chemical Society
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    • v.34 no.5
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    • pp.1388-1390
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    • 2013
  • Macroporous $SnO_2$ foam was successfully synthesized via a simple soft-chemical route by hybridization between alkylamine and tin(IV) oxide. According to X-ray diffraction (XRD) analysis, the as-prepared $SnO_2$ foam had a highly ordered lamella structure along the crystallographic c-axis, which transformed to a rutile phase after thermal treatment at $300^{\circ}C$. X-ray absorption spectroscopy (XAS) at the Sn K-edge revealed that $SnO_2$ particles in the hybrid material maintained their nanosized structure after hybridization with alkylamine. Scanning electron microscope (SEM) images clearly showed that the as-prepared $SnO_2$ foam had a macroporous structure. This synthetic route can be extended to the development of open frameworks with good electrochemical properties in battery applications.

Design of Fuzzy PI Controller for Piezo Actuator of Nano Stage (나노 스테이지용 압전 구동기의 퍼지 PI 제어기 설계)

  • Cho, Seong-Yeon;Chung, Chung-Choo
    • Proceedings of the KIEE Conference
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    • 2003.11c
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    • pp.629-632
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    • 2003
  • Piezo actuators are mainly used in precision position control system because of their high position resolution. Although there have been many approaches in open loop control of this, those method turn out to be not effective in precision control due to hysteresis and creep. To overcome the problems, closed loop PI control method is used in commercial products. However, it is very difficult to obtain fast response with conventional PI control although piezo actuator has fast response. In this paper, we propose a fuzzy PI control method with the proposed fuzzy PI controller, we obtains faster settling response over the conventional PI controller. We verify the effectiveness of the proposed method with experimental results.

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Micromorph Schottky Silicon Solar Cells

  • Kim, Joon-Dong;Han, Chang-Soo;Yun, Ju-Hyung;Yi, Jun-Sin;Park, Yun-Chang
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.130-130
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    • 2010
  • Thin Si films were grown by a plasma-enhanced chemical vapor deposition (PECVD, SNTEK, Korea) system. Two different deposition condition were applied and formed a fully amorphous Si (a-Si) film and a micromorph mixing of microcrystalline Si (mc-Si) and a-Si film. Under one sun illumination, the micromorph device provided the enhanced open circuit voltage and fill factor values. It presents the fabrication of the micromorph Si film and the a-Si film by modulating a deposition condition. The performances of the Si thin film Schottky solar cells are discussed.

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Biodisc Regeneration Using Annulus Fibrosus Cell with Hyaluronic Acid Impregnated Small Intestinal Submucosa Sponge (히알루론산이 함유된 SIS 스폰지와 섬유륜세포를 이용한 디스크재생)

  • Hong, Hee-Kyung;Lee, Seon-Kyoung;Song, Yi-Seul;Kim, Dae-Sung;Eom, Shin;Kim, Hyoung-Eun;Lee, Dong-Won;Khang, Gil-Son
    • Polymer(Korea)
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    • v.34 no.3
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    • pp.282-288
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    • 2010
  • The porcine small intestinal submucosa (SIS) has been widely used as a biomaterial without immuno rejection responses and hyalunonic acid (HA) can be used as biocompatible materials to regenerate tissue. We developed the SIS sponge and HA loaded SIS sponges (SIS/HA) for the possibility of the application of the tissue engineering using annulus fibrosus (AF). SEM observation shows that SIS and SIS/HA sponges have interconnected and open pores. We demonstrated the presence of HA in SIS/HA sponge from C-O functional group observed by the FTIR analysis. In conclusion, we suggest that SIS/HA sponge may be useful to tissue engineering using AF cell. This may be due to the enhanced biocompatibility and higher water retention capacity of HA.

Effect of open-core screw dislocation on axial conductivity in semiconductor crystals

  • Taira, Hisao;Sato, Motohiro
    • Advances in nano research
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    • v.1 no.3
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    • pp.171-182
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    • 2013
  • The alternating current (AC) conductivity in semiconductor crystals with an open-core screw dislocation is studied in the current work. The screw dislocation in crystalline media results in an effective potential field which affects the electronic transport properties of the system. Therefore, from a technological view point, it is interesting to investigate properties of AC conductivity at frequencies of a few terahertz. To quantify the screw-induced potential effect, we calculated the AC conductivity of dislocated crystals using the Kubo formula. The conductivity showed peaks within the terahertz frequency region, where the amplitude of the AC conductivity was large enough to be measured in experiments. The measurable conductivity peaks did not arise in dislocation-free crystals threaded by a magnetic flux tube. These results imply different conductivity mechanisms in crystals with a screw dislocation than those threaded by a magnetic flux tube, despite the apparent similarity in their electronic eigenstates.

Investigating nonlinear forced vibration behavior of multi-phase nanocomposite annular sector plates using Jacobi elliptic functions

  • Mirjavadi, Seyed Sajad;Forsat, Masoud;Barati, Mohammad Reza;Hamouda, A.M.S.
    • Steel and Composite Structures
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    • v.36 no.1
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    • pp.87-101
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    • 2020
  • A multi-scale epoxy/CNT/fiberglass annular sector plate is studied in this paper in the view of determining nonlinear forced vibration characteristics. A 3D Mori-Tanaka model is employed for evaluating multi-scale material properties. Thus, all of glass fibers are assumed to have uni-direction alignment and CNTs have random diffusion. The geometry of annular sector plate can be described based on the open angle and the value of inner/outer radius. In order to solve governing equations and derive exact forced vibration curves for the multi-scale annular sector, Jacobi elliptic functions are used. Obtained results demonstrate the significance of CNT distribution, geometric nonlinearity, applied force, fiberglass volume, open angle and fiber directions on forced vibration characteristics of multi-scale annular sector plates.

A Novel Flowerlike Nanostructured CeO2 for Sustainable Energies

  • Li, Hong;Chen, Liquan
    • Journal of the Korean Ceramic Society
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    • v.47 no.1
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    • pp.66-70
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    • 2010
  • This article presents a brief review of our recent studies on flowerlike nanostructured $CeO_2$ materials. These materials are monodispersed microspheres with peony appearance, open mesoporous structure, large specific surface area and nano-crystalline feature. The applications of this type of novel material to SOFC, ethanol steam reforming and CO oxidation are introduced.

Electrically conductive nano adhesive bonding: Futuristic approach for satellites and electromagnetic interference shielding

  • Ganesh, M. Gokul;Lavenya, K.;Kirubashini, K.A.;Ajeesh, G.;Bhowmik, Shantanu;Epaarachchi, Jayantha Ananda;Yuan, Xiaowen
    • Advances in aircraft and spacecraft science
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    • v.4 no.6
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    • pp.729-744
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    • 2017
  • This investigation highlights rationale of electrically conductive nano adhesives for its essential application for Electromagnetic Interference (EMI) Shielding in satellites and Lightning Strike Protection in aircrafts. Carbon Nano Fibres (CNF) were functionalized by electroless process using Tollen's reagent and by Plasma Enhanced Chemical Vapour Deposition (PECVD) process by depositing silver on CNF. Different weight percentage of CNF and silver coated CNF were reinforced into the epoxy resin hardener system. Scanning Electron Microscopy (SEM) micrographs clearly show the presence of CNF in the epoxy matrix, thus giving enough evidence to show that dispersion is uniform. Transmission Electron Microscopy (TEM) studies reveal that there is uniform deposition of silver on CNF resulting in significant improvement in interfacial adhesion with epoxy matrix. There is a considerable increase in thermal stability of the conductive nano adhesive demonstrated by Differential Scanning Calorimetry (DSC) and Thermogravimetric Analysis (TGA). Four probe conductivity meters clearly shows a substantial increase in the electrical conductivity of silver coated CNF-epoxy composite compared to non-coated CNF-epoxy composite. Tensile test results clearly show that there is a significant increase in the tensile strength of silver coated CNF-composites compared to non-coated CNF-epoxy composites. Consequently, this technology is highly desirable for satellites and EMI Shielding and will open a new dimension in space research.