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http://dx.doi.org/10.5012/bkcs.2013.34.5.1388

Synthesis and Characterization of New Macroporous SnO2 Foams  

Choi, Moon-Hyung (Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University)
Paek, Seung-Min (Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University)
Publication Information
Bulletin of the Korean Chemical Society / v.34, no.5, 2013 , pp. 1388-1390 More about this Journal
Abstract
Macroporous $SnO_2$ foam was successfully synthesized via a simple soft-chemical route by hybridization between alkylamine and tin(IV) oxide. According to X-ray diffraction (XRD) analysis, the as-prepared $SnO_2$ foam had a highly ordered lamella structure along the crystallographic c-axis, which transformed to a rutile phase after thermal treatment at $300^{\circ}C$. X-ray absorption spectroscopy (XAS) at the Sn K-edge revealed that $SnO_2$ particles in the hybrid material maintained their nanosized structure after hybridization with alkylamine. Scanning electron microscope (SEM) images clearly showed that the as-prepared $SnO_2$ foam had a macroporous structure. This synthetic route can be extended to the development of open frameworks with good electrochemical properties in battery applications.
Keywords
X-ray absorption spectroscopy; Layered material; Hybrid;
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